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US4579999A Expired / Lapsed US ⏱️ 0.0 years remaining

Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle

Assignee: Mobil Oil AS
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Filing: 1985-05-14
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Granted: 1986-04-01
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Expires: 2005-05-14
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Abstract

Abstract A process for converting oxygenated feedstock, such as methanol, dimethyl ether or the like, to liquid hydrocarbons. In the primary catalyst stage the feedstock is contacted with zeolite catalyst to produce C2-C4 olefins and C5+ hydrocarbons. In a secondary catalytic stage with oligomerization catalyst comprising medium-pore shape selective acidic zeolite at increased pressure converts C3+ olefins to gasoline and/or distillate liquids. The improvement is a technique for recovering lower alkene for recycle to the primary catalytic stage.

Inventors

  • 👤 Ronald M. Gould
  • 👤 Samuel A. Tabak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:46
CPC Classifications
C; C10; C10G; C10G50/00; C07; C07C; C07C1/00; C07C1/20; C10G3/00; C10G3/42; C10G3/44; C10G3/48; C10G3/49; B; B01; B01J; B01J2208/00; B01J2208/00008; B01J2208/00017; B01J2208/00106; B01J2208/00265; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C10G2300/00; C10G2300/40; C10G2300/4081; C10G2400/00; C10G2400/02; C10G2400/20; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/582; Y02P20/584; Y02P30/00; Y02P30/20

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 166 words
A process for converting oxygenate feedstock comprising methanol, dimethyl ether or mixtures thereof to predominantly distillate range liquid hydrocarbons comprising the steps of contacting the feedstock with zeolite catalyst in a primary fluidized bed catalyst stage at elevated temperature and moderate pressure to convert feedstock to hydrocarbons comprising C 2 -C 4 olefins and C 5 + hydrocarbons; cooling and separating effluent from the primary stage to recover a liquid hydrocarbon stream and a light hydrocarbon vapor stream rich in C 2 -C 4 olefins; pressurizing and contacting the light olefinic hydrocarbon stream in a secondary catalytic stage with oligomerization catalyst comprising medium-pore shape selective acidic zeolite at substantially increased pressure and moderate temperature to convert at least a portion of olefins to a heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids; and injecting at least a portion of the olefinic gasoline recycle stream into the fluidized catalyst bed of the primary stage reactor at a separate point above the oxygenate feedstock.
Claim 2
Dependent Claim 166 words
A process for converting oxygenate feedstock comprising methanol, dimethyl ether or mixtures thereof to predominantly distillate range liquid hydrocarbons comprising the steps of contacting the feedstock with zeolite catalyst in a primary fluidized bed catalyst stage at elevated temperature and moderate pressure to convert feedstock to hydrocarbons comprising C 2 -C 4 olefins and C 5 + hydrocarbons; cooling and separating effluent from the primary stage to recover a liquid hydrocarbon stream and a light hydrocarbon vapor stream rich in C 2 -C 4 olefins; pressurizing and contacting the light olefinic hydrocarbon stream in a secondary catalytic stage with oligomerization catalyst comprising medium-pore shape selective acidic zeolite at substantially increased pressure and moderate temperature to convert at least a portion of olefins to a heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids; and injecting at least a portion of the olefinic gasoline recycle stream into the fluidized catalyst bed of the primary stage reactor at a separate point above the oxygenate feedstock.
Claim 3
Dependent Claim 38 words
The process of claim 1 wherein primary stage feedstock is converted over HZSM-5 catalyst to provide a light olefinic hydrocarbon vapor stream comprising a major amount of C 3 -C 4 olefins and a minor amount of ethene.
Claim 4
Dependent Claim 45 words
The process of claim 1 further comprising the step of fractionating gaseous effluent separated from primary stage effluent to recover a recycle gas stream containing at least 90% of ethene from the primary catalytic stage and an olefinic stream rich in C 3 + olefins.
Claim 5
Dependent Claim 46 words
The process of claim 1 wherein the primary and secondary stage catalyst comprises ZSM-5 type zeolite and olefinic gasoline is recycled to the primary stage at a rate of about 1 to 30 parts gasoline per 100 parts by weight of hydrocarbon equivalent in the feedstock.
Claim 6
Dependent Claim 30 words
The process of claim 1 wherein compressed light hydrocarbon gaseous stream is further fractionated by selectively absorbing C 3 + components in a C 5 + liquid hydrocarbon sorbent stream.
Claim 7
Dependent Claim 28 words
The process of claim 5 wherein a C 5 + fraction of the secondary stage liquid hydrocarbon product stream comprising olefinic gasoline is recycled as the sorbent stream.
Claim 8
Dependent Claim 162 words
A process for converting oxygenated feedstock to liquid hydrocarbons comprising the steps of contacting the feedstock with fluidized bed catalyst in a primary catalyst stage at elevated temperature and moderate pressure to convert feedstock to hydrocarbons comprising C 2 -C 4 alkenes and C 5 + hydrocarbons; cooling and separating effluent from the primary stage to recover a liquid hydrocarbon stream and a light hydrocarbon stream rich in C 2 -C 4 alkenes; compressing the light hydrocarbon stream to condense a liquid olefinic hydrocarbon stream rich in C 3 + alkenes and recovering an ethene-rich gaseous stream; further pressurizing and contacting the condensed liquid olefinic hydrocarbon stream in a secondary catalytic stage with oligomerization catalyst comprising medium-pore shape selective acidic zeolite at substantially increased pressure and moderate temperature to convert at least a portion of alkenes to a heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids; and recycling a lower alkene stream recycle to the primary catalytic stage.
Claim 9
Dependent Claim 162 words
A process for converting oxygenated feedstock to liquid hydrocarbons comprising the steps of contacting the feedstock with fluidized bed catalyst in a primary catalyst stage at elevated temperature and moderate pressure to convert feedstock to hydrocarbons comprising C 2 -C 4 alkenes and C 5 + hydrocarbons; cooling and separating effluent from the primary stage to recover a liquid hydrocarbon stream and a light hydrocarbon stream rich in C 2 -C 4 alkenes; compressing the light hydrocarbon stream to condense a liquid olefinic hydrocarbon stream rich in C 3 + alkenes and recovering an ethene-rich gaseous stream; further pressurizing and contacting the condensed liquid olefinic hydrocarbon stream in a secondary catalytic stage with oligomerization catalyst comprising medium-pore shape selective acidic zeolite at substantially increased pressure and moderate temperature to convert at least a portion of alkenes to a heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids; and recycling a lower alkene stream recycle to the primary catalytic stage.
Claim 10
Dependent Claim 40 words
The process of claim 7 where at least a portion of the alkene recycle stream is gasoline recovered from the secondary stage liquid effluent hydrocarbon stream, said gasoline containing at least 50 weight percent C 5 to C 9 olefins.
Claim 11
Dependent Claim 20 words
The process of claim 7 wherein the recycle comprises C 5 + hydrocarbons recovered between the primary and secondary stages.
Claim 12
Dependent Claim 30 words
The process of claim 8 wherein the alkene recycle stream is injected into the fluidized catalyst bed of the primary stage reactor at a point above the oxygenate feedstock charge.
Claim 13
Dependent Claim 23 words
The process of claim 7 wherein the alkene recycle stream is injected above a bed stratum corresponding to at least 99% oxygenate conversion.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-31 1989-09-30 1990-04-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-31 1993-09-30 1994-04-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-31 1997-09-30 1998-04-01 $7700.00 Window Closed / Lapsed

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