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US4579872A Expired / Lapsed US ⏱️ 0.0 years remaining

Uniform minimization of plastic foam cell size

Assignee: Dow Chemical Co
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Filing: 1985-05-06
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Granted: 1986-04-01
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Expires: 2005-05-06
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Abstract

Abstract Expandable beads and the like of thermoplastic organic polymer material, advantageously lightly-crosslinked in preparation, which are imbibed with halocarbon and/or light hydrocarbon (including mixed) blowing agents are advantageously tempered to provide excellent quality, uniformly fine-celled expanded cellular products therefrom by a quick quench from imbibition temperature to below 10 or so ° C. within one minute.

Inventors

  • 👤 David R. Johnson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:34
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/16; C08J9/18; C08J9/04; C08J9/12; C08J9/14; C08J2325/00; Y; Y10; Y10S; Y10S521/00; Y10S521/91

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 267 words
In the making of expandable bead and the like or equivalent physical forms of intermediate, blowing agent-containing masses of thermoplastic organic polymer material suitable for conversion to fine celled plastic foam product upon subjection of such expandable thermoplastic material to heat at a temperature at least equal to the glass transition temperature of the polymerizate therein but below its decomposition temperature, wherein (i) the involved blowing agent is a volatile normally-gaseous or readily-vaporizable substance selected from the group consisting of: at least monochlorinated or mono-fluorinated but incompletely-halogenated lower hydrocarbon halo-alkanes of C 1 to C 3 content; C 1 to C 3 chlorofluorocarbons; C 1 to C 5 aliphatic hydrocarbons; and mixtures thereof, with (ii) the expandable particle containing from about 5 to about 35 weight percent blowing agent impregnated in said thermoplastic organic polymer material; the step of improvement consisting essentially of: (iii) a quick-quench tempering treatment for the imbibed physical form of said thermoplastic material containing said impregnated blowing agent which involves rapidly cooling said bead or the like form in a quench media after completion of blowing agent imbibation at a temperature as indicated of at least about 65° C. to a rapidly-diminished chill temperature of said beads as a result of the said quench of less than about 10° C., wihtin not more than a minute whereupon and whereby the said expandable beads or the like are adapted to be converted upon expansion into foam body product characterized in having a density of from about 0.25 to about 10 pounds per cubic foot and having cells of about 0.02 to about 0.08 millimeter.
Claim 2
Dependent Claim 267 words
In the making of expandable bead and the like or equivalent physical forms of intermediate, blowing agent-containing masses of thermoplastic organic polymer material suitable for conversion to fine celled plastic foam product upon subjection of such expandable thermoplastic material to heat at a temperature at least equal to the glass transition temperature of the polymerizate therein but below its decomposition temperature, wherein (i) the involved blowing agent is a volatile normally-gaseous or readily-vaporizable substance selected from the group consisting of: at least monochlorinated or mono-fluorinated but incompletely-halogenated lower hydrocarbon halo-alkanes of C 1 to C 3 content; C 1 to C 3 chlorofluorocarbons; C 1 to C 5 aliphatic hydrocarbons; and mixtures thereof, with (ii) the expandable particle containing from about 5 to about 35 weight percent blowing agent impregnated in said thermoplastic organic polymer material; the step of improvement consisting essentially of: (iii) a quick-quench tempering treatment for the imbibed physical form of said thermoplastic material containing said impregnated blowing agent which involves rapidly cooling said bead or the like form in a quench media after completion of blowing agent imbibation at a temperature as indicated of at least about 65° C. to a rapidly-diminished chill temperature of said beads as a result of the said quench of less than about 10° C., wihtin not more than a minute whereupon and whereby the said expandable beads or the like are adapted to be converted upon expansion into foam body product characterized in having a density of from about 0.25 to about 10 pounds per cubic foot and having cells of about 0.02 to about 0.08 millimeter.
Claim 3
Dependent Claim 38 words
The process of claim 1 when said rapidly-diminished chill temperature attained in said beads as a result of said tempering treatment (iv) does not exceed about 5° C. and is accomplished within not more than about 30 seconds.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein said thermoplastic organic polymer material is a lightly crosslinked copolymer which is crosslinked to the equivalent of 0.04 weight percent divinylbenzene.
Claim 5
Dependent Claim 19 words
The process of claim 3 wherein said thermoplastic organic polymer material is a lightly-crosslinked copolymer of a styrene monomer.
Claim 6
Dependent Claim 16 words
The process of claim 3 wherein said thermoplastic organic polymer material is a lightly-crosslinked polystyrene material.
Claim 7
Dependent Claim 33 words
The process of claim 3 wherein said thermoplastic organic polymer material is a lightly-crosslinked polystyrene material and said involved blowing agent to be imbibed by said polystyrene material is a mixture of chlorofluorocarbons.
Claim 8
Dependent Claim 21 words
The process of claim 1, with said blowing agent is a mixture of chlorofluorocarbons being a combination of trichloro-monofluoro-methane and dichlorodifluoro-ethane.
Claim 9
Dependent Claim 16 words
The process of claim 1 wherein said quench media of Step (iii) is aqueous in nature.
Claim 10
Dependent Claim 17 words
The process of claim 8, with ice water being the said aqueous quench media of Step (ii).

References Cited (Backward Citations)

US3960784A Cited
US4226942A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-31 1989-09-30 1990-04-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-31 1993-09-30 1994-04-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-31 1997-09-30 1998-04-01 $7700.00 Window Closed / Lapsed

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