Patent US4579571A successfully refreshed from Google Patents.
US4579571A
Expired / Lapsed
US
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Method for fabricating optical fiber preforms
Assignee: Polaroid Corp
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Filing: 1984-10-09
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Granted: 1986-04-01
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Expires: 2004-10-09
Abstract
Abstract A method for fabricating preforms for drawing into single mode optical fibers having core and cladding doped with different amounts fluorine. A pure fused silica start rod is first coated with a layer of soot which is then dehydrated, doped with a first level of fluorine, and then consolidated. This structure, which is an intermediate preform, is then drawn down until its area weighted average index of refraction is such that it would perform as a core in a fiber. If not, it is recoated and drawn down further until it will behave as a core upon further reduction in size. The intermediate preform is then recoated with another layer doped with a higher concentration of fluorine so that it will act as a cladding layer over the first fluorinated layer whose index is higher because of a lower concentration of fluorine. This final structure serves as a preform from which the desired fiber can be drawn.
Inventors
- 👤 John W. Hicks, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:07
CPC Classifications
C; C03; C03B; C03B37/00; C03B37/01; C03B37/012; C03B37/014; C03B37/01446; C03B37/0146; C03B37/01466; C03B2201/00; C03B2201/06; C03B2201/08; C03B2201/12; C03B2203/00; C03B2203/10; C03B2203/22; C03B2203/24; Y; Y10; Y10S; Y10S65/00; Y10S65/15; Y10S65/16
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
352 words
A method of fabricating a glass preform from which optical fibers can be drawn comprising the steps of: depositing on a starting rod a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; reducing the cross-sectional area of said intermediate preform and adding additional solid fluorine-containing layers according to the sequence above as required until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or layers subsequently added to said intermediate preform, is a predetermined value such that said intermediate preform upon further drawing under a predetermined draw down ratio will act as an optical fiber core when surrounded by a cladding having an index of refraction which in combination with said average index will sustain waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform.
Claim 2
Independent Claim
352 words
A method of fabricating a glass preform from which optical fibers can be drawn comprising the steps of: depositing on a starting rod a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; reducing the cross-sectional area of said intermediate preform and adding additional solid fluorine-containing layers according to the sequence above as required until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or layers subsequently added to said intermediate preform, is a predetermined value such that said intermediate preform upon further drawing under a predetermined draw down ratio will act as an optical fiber core when surrounded by a cladding having an index of refraction which in combination with said average index will sustain waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform.
Claim 3
Dependent Claim
25 words
The method of claim 1 wherein both of said dehydrating steps comprise the step of heating said coatings of soot in a chlorine containing atmosphere.
Claim 4
Dependent Claim
29 words
The method of claim 2 wherein said heating is sufficient to raise and maintain said soot coatings at a temperature within the range between 1,000° C. and 1,200° C.
Claim 5
Dependent Claim
25 words
The method of claim 1 wherein said consolidation steps comprise the step of sintering said fluorinated coatings of soot from one end to the other.
Claim 6
Dependent Claim
42 words
The method of claim 1 wherein said first fluorine level and said cross-sectional reduction in area of said intermediate preform is such that said predetermined value for said area weighted average index of refraction is within the range between 1.4454 and 1.4446.
Claim 7
Dependent Claim
37 words
The method of claim 5 wherein said lower concentration of fluorine is such that said other solid layer has an index of refraction that is lower than said average index of refraction by between 0.0035 and 0.0069.
Claim 8
Dependent Claim
71 words
The method of claim 1 further including, just prior to said area reduction step, determining if said intermediate preform average index of refraction is said predetermined value and, if not, dividing said intermediate preform into a plurality of segments and proceeding with said method, treating each of said segments as an intermediate preform until each of said segments has an area weighted average index of refraction which satisfies said predetermined value.
Claim 9
Dependent Claim
13 words
The method of claim 1 wherein said start rod comprises pure silicon dioxide.
Claim 10
Independent Claim
340 words
A method of fabricating a glass preform from which optical fibers can be drawn comprising the steps of: depositing on a starting rod of silicon dioxide a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; drawing down said intermediate preform and repeating the first five steps if necessary starting with said intermediate preform until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or subsequent layers, added to said intermediate preform is a predetermined value such that said intermediate preform upon further drawing will act as an optical fiber core if surrounded by a cladding having the necessary index of refraction to promote waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform.
Claim 11
Independent Claim
340 words
A method of fabricating a glass preform from which optical fibers can be drawn comprising the steps of: depositing on a starting rod of silicon dioxide a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; drawing down said intermediate preform and repeating the first five steps if necessary starting with said intermediate preform until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or subsequent layers, added to said intermediate preform is a predetermined value such that said intermediate preform upon further drawing will act as an optical fiber core if surrounded by a cladding having the necessary index of refraction to promote waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform.
Claim 12
Independent Claim
362 words
A method of fabricating a single mode optical fiber comprising the steps of: depositing on a starting rod a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; reducing the cross-sectional area of said intermediate preform and adding additional solid fluorine-containing layers according to the sequence above as required until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or layers subsequently added to said intermediate preform, is a predetermined value such that said intermediate preform upon further drawing under a predetermined draw down ratio will act as an optical fiber core when surrounded by a cladding having an index of refraction which in combination with said average index will sustain waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure, of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform to form said preform; and drawing down said preform into a single mode optical fiber.
Claim 13
Independent Claim
362 words
A method of fabricating a single mode optical fiber comprising the steps of: depositing on a starting rod a coating of porous glass soot of homogeneous composition and low water content; dehydrating said coating of soot to reduce its water content; fluorinating said coating of soot with a given concentration and partial pressure of fluorine while at an elevated temperature to remove water remaining after said dehydration step and to fill the pores of said soot with fluorine; consolidating said fluorinated soot on said starting rod to form an intermediate preform with a solid glass layer doped with a predetermined percentage of fluorine; reducing the cross-sectional area of said intermediate preform and adding additional solid fluorine-containing layers according to the sequence above as required until the area weighted average index of refraction of said starting rod material to said fluorine doped layer, or layers subsequently added to said intermediate preform, is a predetermined value such that said intermediate preform upon further drawing under a predetermined draw down ratio will act as an optical fiber core when surrounded by a cladding having an index of refraction which in combination with said average index will sustain waveguiding action; depositing on said intermediate preform at least one other coating of porous glass soot of homogeneous composition and low water content; dehydrating said other coating of soot to reduce its water content; fluorinating said other coating of soot with a given concentration, lower than said first concentration, and partial pressure, of fluorine while at an elevated temperature sufficient to remove any water remaining after dehydrating said other soot coating and to fill the pores of said other soot coating with a level of fluorine which, after consolidation of said final soot, results in a solid fluorinated layer having an index of refraction lower than that of said solid fluorinated layer of said intermediate preform; and consolidating said final soot on said intermediate preform to form over said intermediate preform a solid glass layer whose index of refraction is lower than the area weighted average index of refraction of said intermediate preform to form said preform; and drawing down said preform into a single mode optical fiber.
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