Benzo[de]pyrano[3,2-g]isoquinoline derivatives useful as dyestuffs

Claim 1

A coumarin of the formula ##STR211## in which A is >N--R wherein R is hydrogen, alkyl of from 1 to 18 carbon atoms, or alkyl of from 1 to 18 carbon atoms mono-, di- or trisubstituted by fluorine, chlorine or bromine, or mono- or disubstituted by alkoxy of from 1 to 4 carbon atoms, dialkylamino of from 2 to 8 carbon atoms, sulfodialkylamide of from 2 to 8 carbon atoms or cyano, the di- or tri-substituents being the same or not all the same; or is a moiety selected from the group consisting of cyclopentyl, cyclohexyl, cycloheptyl, phenyl, naphthyl, pyridyl, pyrimidyl, benzoxazolyl, benzothiozolyl and benzimidazolyl, or said moiety mono-, di- or trisubstituted at one or more nuclear carbon atoms by fluorine, chlorine or bromine, or mono- or disubstituted at one or more nuclear carbon atoms by alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, hydroxyl, cyano, sulfonamide or sulfodialkyl-amide of from 2 to 8 carbon atoms, the di- or tri-substituents being the same or not all the same; X is oxygen or >N--R' wherein R' is a moiety selected from the group consisting of hydrogen, alkylcarbonyl of from 2 to 19 carbon atoms, alkoxycarbonyl of from 2 to 5 carbon atoms, alkylcarbamoyl of from 2 to 5 carbon atoms and alkylsulfonyl of from 1 to 4 carbon atoms, or said moiety mono-, di- or trisubstituted in the alkyl or alkoxy group by fluorine, chlorine or bromine, or mono- or disubstituted in the alkyl or alkoxy group by alkoxy of from 1 to 4 carbon atoms or cyano, the di- or tri-substituents being the same or not at all the same; or is phenyl, phenylcarbonyl, phenycarbamoyl or phenysulfonyl, or phenyl, phenylcarbonyl, phenylcarbanoyl or phenylsulfonyl mono-, di- or trisubstituted in the phenyl moiety by fluorine, chlorine, bromine, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, nitro, or cyano, the di- or tri-substituents being the same or not all the same; Y is hydrogen, cyano, or alkyl carboxylate of from 2 to 5 carbon atoms, phenyl, phenylsulfonyl or phenylcarboxylate, or phenyl, phenylsulfonyl or phenylcarboxylate mono-, di- or trisubstituted in the phenyl group by fluorine, chlorine or bromine, alkyl of from 1 to 4 carbon atoms or alkoxy of from 1 to 4 carbon atoms, or mono- or disubstituted in the phenyl group by nitro, amino, monoalkyl or dialkylamino wherein said alkyl is of from 1 to 4 carbon atoms, or monosubstituted in the phenyl group by methylenedioxy or benzoxazolyl, the di- or tri-substituents being the same or not at all the same, or is a moiety selected from the group consisting of thienyl, benzothienyl, furyl, benzofuryl, triazolyl, imidazolyl, benzimidazolyl, thiazolyl, benzothiazolyl, oxazolyl, benzoxazolyl, thiadiazolyl, oxadiazolyl or pyridyl, or said moiety mono-, di- or trisubstituted at one or more nuclear carbon atoms by fluorine, chlorine, bromine, alkyl of from 1 to 4 carbon atoms or alkoxy of from 1 to 4 carbon atoms, or mono- or disubstituted at one or more nuclear carbon atoms by nitro, phenyl, alkylphenyl wherein said alkyl is of from 1 to 4 carbon atoms, alkoxyphenyl wherein said alkoxy is of from 1 to 4 carbon atoms, or cyano, or monosubstituted at a nuclear carbon atom by methylenedioxy or alkylcarboxylate of from 2 to 5 carbon atoms, the di- or trisubstituents being the same or not all the same; and Z is hydrogen, cyano or alkylcarboxylate of from 2 to 5 carbon atoms.