US4576994A
Expired / Lapsed
US
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Process for the preparation of a polypropylene molding composition
Assignee: Hoechst AG
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Filing: 1984-08-31
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Granted: 1986-03-18
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Expires: 2004-08-31
Abstract
Abstract A polypropylene molding composition with a good hardness and good impact strength at low temperatures is formed by two-stage polymerization of propylene and ethylene in liquid propylene in the presence of a special supported catalyst.
Inventors
- 👤 Bernhard Dorrer
- 👤 Helmut Strametz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 08:31
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083; C08L23/14; C08L23/142; C08L2205/00; C08L2205/02; C08L2308/00
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
269 words
A process for the preparation of a polypropylene molding composition consisting of 65 to 95% by weight of a polypropylene and 35 to 5% by weight of an ethylene propylene copolymer by continuous polymerization in two stages in liquid propylene, which comprises preparing a crystalline polypropylene or a polypropylene modified by small amounts of another 1-olefin in the first state at a temperature between about 40° C. and about 85° C. and a pressure higher than the pressure of the second stage and a residence time of 40 to 90 minutes and preparing an ethylene/propylene copolymer in the second stage at a temperature between about 40° C. and about 85° C. and under a pressure of 23 to 64 atmospheres and a residence time of 10 to 90 minutes in the presence of 10 to 55 mole % of ethylene, based on the ethylene/propylene mixture present, a mixed catalyst which has been formed by bringing into contact (A) the reaction product of (a1) a reaction product of a magnesium halide with an electron donor and/or a cyclopolyene and (a21) a compound formed by reduction of titanium tetrachloride by means of an organometallic compound of main groups I to III of the periodic table or (a22) titanium tetrachloride with (B) a halogen-free organoaluminum compound and (C) a compound from the group comprising cyclopolyenes and aromatic carboxylic acid esters, wherein the mixed catalyst being used in both stages is composed of about 0.001 to 1 mole/liter of liquid of component (A) about 0.01 to 40 moles/liter of liquid of component (B) and 0.003 to 12 moles/liter of liquid of component (C).
Claim 2
Dependent Claim
269 words
A process for the preparation of a polypropylene molding composition consisting of 65 to 95% by weight of a polypropylene and 35 to 5% by weight of an ethylene propylene copolymer by continuous polymerization in two stages in liquid propylene, which comprises preparing a crystalline polypropylene or a polypropylene modified by small amounts of another 1-olefin in the first state at a temperature between about 40° C. and about 85° C. and a pressure higher than the pressure of the second stage and a residence time of 40 to 90 minutes and preparing an ethylene/propylene copolymer in the second stage at a temperature between about 40° C. and about 85° C. and under a pressure of 23 to 64 atmospheres and a residence time of 10 to 90 minutes in the presence of 10 to 55 mole % of ethylene, based on the ethylene/propylene mixture present, a mixed catalyst which has been formed by bringing into contact (A) the reaction product of (a1) a reaction product of a magnesium halide with an electron donor and/or a cyclopolyene and (a21) a compound formed by reduction of titanium tetrachloride by means of an organometallic compound of main groups I to III of the periodic table or (a22) titanium tetrachloride with (B) a halogen-free organoaluminum compound and (C) a compound from the group comprising cyclopolyenes and aromatic carboxylic acid esters, wherein the mixed catalyst being used in both stages is composed of about 0.001 to 1 mole/liter of liquid of component (A) about 0.01 to 40 moles/liter of liquid of component (B) and 0.003 to 12 moles/liter of liquid of component (C).
Claim 3
Dependent Claim
87 words
The process as claimed in claim 1, wherein said mixed catalyst which has been formed by bringing into contact (A) the reaction product of (a1) a reaction product of a magnesium halide with an electron donor and/or a cyclopolyene and (a21) a compound formed by reduction of titanium tetrachloride by means of an organometallic compound of main groups I to III of the periodic table, with (B) a halogen-free organoaluminum compound and (C) a compound from the group comprising cyclopolyenes and aromatic carboxylic acid esters, is used.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-03-17 | 1989-09-16 | 1990-03-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-03-17 | 1993-09-16 | 1994-03-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-03-17 | 1997-09-16 | 1998-03-18 | $7700.00 | Window Closed / Lapsed |