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US4308357A Expired / Lapsed US ⏱️ 0.0 years remaining

Block copolymerization process and product

Assignee: El Paso Products Co
•
Filing: 1980-10-20
•
Granted: 1981-12-29
•
Expires: 2000-10-20
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Abstract

Abstract A process for the preparation of ethylene-propylene block copolymers at high catalyst productivity rates resulting in polymer products having improved impact strength-polymerized ethylene content relationship.

Inventors

  • 👤 Malcolm J. Kaus
  • 👤 Birendra K. Patnaik

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 05:12
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 220 words
A block copolymerization process for the production of impact resistant ethylene-propylene block polymers at high productivity rates, which comprises I. in a first stage producing a propylene prepolymer in the presence of no more than about 5 vol % of inert diluents by polymerizing propylene at pressures sufficient to maintain propylene in liquid phase, at a residence time of about 30 minutes or below and at temperatures between about 115° F. and about 165° F. in the presence of a catalyst composition containing the components (a) an aluminum trialkyl or an aluminum trialkyl at least partially complexed with an electron donor compound, and (b) titanium tri- or tetrahalide supported on magnesium dihalide, or a complex of a titanium tri- or tetrahalide with an electron donor compound supported on magnesium dihalide, the components (a) and (b) being provided in a molar ratio of Al/Ti between about 10 and about 400; II. in a second stage contacting the prepolymer of the first stage with a monomer mixture of ethylene and propylene at a pressure sufficient to maintain propylene in liquid phase, at a temperature between about 115° F. and about 165° F., a residence time of between about 30 and about 450 minutes in the substantial absence of inert diluents, and III. separating the product of Step II from the unreacted monomer.
Claim 2
Dependent Claim 220 words
A block copolymerization process for the production of impact resistant ethylene-propylene block polymers at high productivity rates, which comprises I. in a first stage producing a propylene prepolymer in the presence of no more than about 5 vol % of inert diluents by polymerizing propylene at pressures sufficient to maintain propylene in liquid phase, at a residence time of about 30 minutes or below and at temperatures between about 115° F. and about 165° F. in the presence of a catalyst composition containing the components (a) an aluminum trialkyl or an aluminum trialkyl at least partially complexed with an electron donor compound, and (b) titanium tri- or tetrahalide supported on magnesium dihalide, or a complex of a titanium tri- or tetrahalide with an electron donor compound supported on magnesium dihalide, the components (a) and (b) being provided in a molar ratio of Al/Ti between about 10 and about 400; II. in a second stage contacting the prepolymer of the first stage with a monomer mixture of ethylene and propylene at a pressure sufficient to maintain propylene in liquid phase, at a temperature between about 115° F. and about 165° F., a residence time of between about 30 and about 450 minutes in the substantial absence of inert diluents, and III. separating the product of Step II from the unreacted monomer.
Claim 3
Dependent Claim 23 words
A process according to claim 1 wherein the residence time of the first step is maintained between about 5 and about 20 minutes.
Claim 4
Dependent Claim 31 words
A process according to claim 1, wherein the ethylene content of the monomer mixture of ethylene and propylene in the second stage is maintained between about 0.5 and about 6 mole%.
Claim 5
Dependent Claim 18 words
A process according to claim 3, wherein said content is between about 1 and about 4 mole %.
Claim 6
Dependent Claim 22 words
A process according to claim 1, wherein the polymerization temperature of either stage is between about 125° F. and about 155° F.
Claim 7
Dependent Claim 13 words
A process according to claim 1, wherein the propylene prepolymer is propylene homopolymer.
Claim 8
Dependent Claim 17 words
A process according to claim 1, wherein the propylene prepolymer is random copolymer of ethylene and propylene.
Claim 9
Dependent Claim 23 words
A process according to claim 1, wherein the aluminum trialkyl is one containing from 1 to 8 carbon atoms in the alkyl groups.
Claim 10
Dependent Claim 13 words
A process according to claim 1, wherein the aluminum trialkyl is triisobutyl aluminum.
Claim 11
Dependent Claim 28 words
A process according to claim 1, herein the electron donor compound of component (a) of the catalyst composition is an ester of a carboxylic acid or a diamine.
Claim 12
Dependent Claim 17 words
A process according to claim 10, wherein said electron donor is an ester of an aromatic acid.
Claim 13
Dependent Claim 11 words
A process according to claim 11, wherein the ester is methyl-p-toluate.
Claim 14
Dependent Claim 23 words
A process according to claim 1, wherein the molar ratio of trialkyl aluminum to electron donor ranges between about 1 and about 100.
Claim 15
Dependent Claim 17 words
A process acccording to claim 13, wherein the molar ratio is between about 2 and about 5.
Claim 16
Dependent Claim 28 words
The process of claim 1, wherein component (a) is prepared by prereacting the aluminum trialkyl with the electron donor for for less than one hour prior to polymerization.
Claim 17
Dependent Claim 18 words
The process of claim 1, wherein the titanium tri- or tetrahalide is a titanium trichloride of titanium tetrachloride.
Claim 18
Dependent Claim 12 words
The process of claim 1, wherein the magnesium dihalide is magnesium dichloride.
Claim 19
Dependent Claim 27 words
The process of claim 1, wherein the electron donor compound of component (b) is a polyamine or an ester of an inorganic or an organic oxygenated acid.
Claim 20
Dependent Claim 17 words
The process of claim 18, wherein said electron donor is an ester of an aromatic carboxylic acid.
Claim 21
Dependent Claim 10 words
The process of claim 19, wherein the ester is ethylbenzoate.
Claim 22
Dependent Claim 21 words
The process of claim 1, wherein the magnesium to electron donor molar ratio of component (b) is at least about 1.
Claim 23
Dependent Claim 16 words
The process of claim 21, wherein said molar ratio is between about 2 and about 10.
Claim 24
Dependent Claim 28 words
The process of claim 1, wherein the titanium content expressed as titanium metal ranges between about 0.1 and about 20 weight percent in the supported catalyst component (b).
Claim 25
Dependent Claim 18 words
The process of claim 23, wherein the titanium content is between about 1 and about 3 weight percent.

References Cited (Backward Citations)

US3378607A Cited
US3318976A Cited
US3514501A Cited
US3830787A Cited
US3953414A Cited
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US4149990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-28 1985-06-29 1985-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-28 1989-06-29 1989-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-28 1993-06-29 1993-12-29 $7700.00 Window Closed / Lapsed

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