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US4576980A
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Azetidinedione compounds as crosslinkers for electrodeposited coatings
Assignee: Dow Chemical Co
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Filing: 1984-10-15
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Granted: 1986-03-18
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Expires: 2004-10-15
Abstract
Abstract Novel coating compositions are disclosed which comprise aqueous dispersions of polyamine resins in the form of their acid salts along with azetidinedione crosslinking agents and other optional adjuvants. The compositions give rise to improved methods for the electrodeposition of heat-curable films on substrates. The compositions and methods find particular utility in the cathodic deposition of coatings and films on automotive parts and household appliances.
Inventors
- 👤 Shenghong A. Dai
- 👤 Philip W. Sherwood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 17:34
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/83; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C09; C09D; C09D5/00; C09D5/44; C09D5/4488; C09D5/4496; Y; Y10; Y10S; Y10S524/00; Y10S524/901
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
131 words
A coating composition in aqueous dispersion for forming a heat-curable film on a substrate said composition comprising 1. a polymer having amine groups selected from the group consisting of primary amines, secondary amines, and mixtures thereof said amine groups being in the form of their acid salts; and 2. a crosslinking agent having at least two azetidinedione groups of the formula ##STR16## wherein R and R 1 when taken separately are independently selected from the group consisting of hydrogen and hydrocarbyl, and when R and R 1 are taken together with the carbon atom to which they are joined represent a cycloalkane having 4 to 8 ring carbon atoms, inclusive, said azetidinedione crosslinking agent being present in at least an equivalent amount to react with substantially all of said amine groups.
Claim 2
Dependent Claim
131 words
A coating composition in aqueous dispersion for forming a heat-curable film on a substrate said composition comprising 1. a polymer having amine groups selected from the group consisting of primary amines, secondary amines, and mixtures thereof said amine groups being in the form of their acid salts; and 2. a crosslinking agent having at least two azetidinedione groups of the formula ##STR16## wherein R and R 1 when taken separately are independently selected from the group consisting of hydrogen and hydrocarbyl, and when R and R 1 are taken together with the carbon atom to which they are joined represent a cycloalkane having 4 to 8 ring carbon atoms, inclusive, said azetidinedione crosslinking agent being present in at least an equivalent amount to react with substantially all of said amine groups.
Claim 3
Dependent Claim
17 words
A coating composition according to claim 1 wherein said amine groups in said polymer are primary amines.
Claim 4
Dependent Claim
267 words
A coating composition according to claim 1 wherein said azetidinedione crosslinking agent has a formula selected from the group consisting of ##STR17## wherein R and R 1 when taken separately are independently selected from the group consisting of hydrogen and hydrocarbyl, and when R and R 1 are taken together with the carbon atom to which they are joined represent a cycloalkane having 4 to 8 ring carbon atoms, inclusive, X is selected from the group consisting of lower-alkylene, cycloalkylene, arylene, and divalent radicals having the formula ##STR18## wherein Z is selected from the group consisting of --CO--, --O--, --SO 2 --, and alkylene having 1 to 4 carbon atoms, inclusive, A represents the azetidinedione group ##STR19## wherein R and R 1 are defined as above, p represents an integer from 1 to 8, inclusive, or in the case of a mixture p has a mean value greater than 0 but less than 1, R 2 is the residue of a polyhydroxy compound having a molecular weight of from about 60 to about 3000, and a functionality m of from 2 to 6, R 3 is the residue of a polyhydroxy or polyamino compound having a molecular weight of from about 400 to about 8000 and a functionality m of from 2 to 6, Y represents --O-- when said R 3 is the residue of a polyhydroxy compound and --NH-- when said R 3 is the residue of a polyamino compound, f has an average value between 0 and 1, and D represents a branch unit when the functionality of said polyhydroxy or polyamino compound exceeds 2.
Claim 5
Dependent Claim
16 words
A coating composition according to claim 3 wherein said azetidinedione crosslinking agent has the formula (I).
Claim 6
Dependent Claim
16 words
A coating composition according to claim 3 wherein said azetidinedione crosslinking agent has the formula (II).
Claim 7
Dependent Claim
16 words
A coating composition according to claim 3 wherein said azetidinedione crosslinking agent has the formula (III).
Claim 8
Dependent Claim
16 words
A coating composition according to claim 3 wherein said azetidinedione crosslinking agent has the formula (IV).
Claim 9
Dependent Claim
16 words
A coating composition according to claim 3 wherein said azetidinedione crosslinking agent has the formula V.
Claim 10
Dependent Claim
16 words
A coating composition according to claim 1 wherein said azetidinedione crosslinking agent has the formula ##STR20##
Claim 11
Dependent Claim
26 words
A coating composition according to claim 9 wherein said polymer is a polyurethane having primary amine groups in the form of the lactic acid salts thereof.
Claim 12
Dependent Claim
27 words
A coating composition according to claim 9 wherein said polymer is a polyepoxy resin having primary amine groups in the form of the lactic acid salts thereof.
Claim 13
Dependent Claim
35 words
A coating composition according to claim 1 wherein said azetidinedione crosslinking agent has the formula ##STR21## wherein p has a mean value greater than 0 but less than 1 and B represents the group ##STR22##
Claim 14
Dependent Claim
26 words
A coating composition according to claim 12 wherein said polymer is a polyurethane having primary amine groups in the form of the lactic acid salts thereof.
Claim 15
Dependent Claim
27 words
A coating composition according to claim 12 wherein said polymer is a polyepoxy resin having primary amine groups in the form of the lactic acid salts thereof.
Claim 16
Dependent Claim
17 words
A substrate coated with a heat cured film derived from the composition in accordance with claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-03-17 | 1989-09-16 | 1990-03-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-03-17 | 1993-09-16 | 1994-03-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-03-17 | 1997-09-16 | 1998-03-18 | $7700.00 | Window Closed / Lapsed |