Photoconductive film and electrophotographic photosensitive member using said film comprising silylated azo pigment

Claim 2

Photoconductive film which comprises a photoconductive pigment obtained by silylation of an azo series pigment having at least one hydroxy group.

Claim 3

Photoconductive film of claim 1 wherein the said azo series of pigment is a pigment having a coupler component having at least one phenolic hydroxy group.

Claim 4

Photoconductive film of claim 2 wherein the coupler component having a phenolic hydroxy group is hydroxynaphthoic acid amide type of coupler component, hydroxynaphthalic acid imide type of coupler component, or a aminonaphthol type of coupler component.

Claim 5

Photoconductive film of claim 4 wherein the hydroxynaphthoic acid amide type of coupler component is expressed by the following general formula: ##STR5## wherein R 1 represents hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted aryl group, or substituted or unsubstituted aralkyl group and R 2 represents alkyl group, aryl group, aralkyl group or heterocycle group that may be substituted, respectively; X represents atomic group required to form aromatic hydrocarbon ring or heterocyclic ring in condensation with benzene ring.

Claim 6

Photoconductive film of claim 3 wherein the hydroxynaphthalic acid imide type of coupler component is expressed by the following general formula (2) or (3): ##STR6## wherein R 3 is alkyl group, aryl group, or aralkyl group that may be substituted, respectively.

Claim 7

Photoconductive film of claim 3 wherein the said aminonaphthol type of coupler component is expressed by the following general formula (4): ##STR7## wherein R 4 is alkyl group, aryl group or aralkyl group that may be substituted, respectively.

Claim 8

Photoconductive film of claim 1 wherein the said azo series of pigment is disazo series of pigment or trisazo series of pigment.

Claim 9

Electrophotographic photosensitive member which comprises a conductive substrate and a photosensitive layer containing photoconductive an azo series pigment obtained by silylation of pigment having at least one hydroxy group.

Claim 10

Electrophotographic photosensitive member which comprises a conductive substrate and a photosensitive layer containing photoconductive an azo series pigment obtained by silylation of pigment having at least one hydroxy group.

Claim 11

Electrophotographic photosensitive member of claim 8 wherein the azo series of pigment is a pigment with coupler component having at least one phenolic hydroxy group.

Claim 12

Electrophotographic photosensitive member of claim 9 wherein the azo series of pigment is disazo series of pigment or trisazo series of pigment.

Claim 13

Electrophotographic photosensitive member of claim 8 wherein the silylation is effected by at least one type of compound selected from the group consisting of a silylation agent and a halomethyl silylation agent.

Claim 14

Electrophotographic photosensitive member which comprises a conductive substrate, a charge generation layer containing photoconcuctive an azo series pigment obtained by silylation of pigment having at least one hydroxy group, and a charge transfer layer.

Claim 15

Electrophotographic photosensitive member which comprises a conductive substrate, a charge generation layer containing photoconcuctive an azo series pigment obtained by silylation of pigment having at least one hydroxy group, and a charge transfer layer.

Claim 16

Electrophotographic photosensitive member of claim 12 wherein the azo series of pigment is a pigment having coupler component having at least one phenolic hydroxy group.

Claim 17

Electrophotographic photosensitive member of claim 12 the azo series of pigment is disazo series of pigment or trisazo series of pigment.

Claim 18

Electrophotographic photosensitive member of claim 12, wherein the silylation is effected by at least one type of compound selected from the group consisting of a silylation agent and a halomethyl silylation agent.

Claim 19

Electrophotographic photosensitive member of claim 12 wherein the charge transfer layer is laminated on the said charge generation layer.

Claim 20

Electrophotographic photosensitive member of claim 12 wherein the charge transfer layer contains a charge transfer material and a binder.

Claim 21

Electrophotographic photosensitive member of claim 17 wherein the charge transfer material is an electron transfer material or positive hole transfer material.

Claim 22

Electrophotographic photosensitive member of claim 18 wherein the positive hole transfer material is at least one type of compound selected from group consisting of polycyclic aromatic compounds, carbazoles, hydrazones, pyrazolines, oxazoles, thiazoles, triaryl methanes, polyaryl alkanes, triphenyl amines, poly-N-vinylcarbazoles, polyvinyl pyrenes, polyvinyl anthracenes, polyvinyl acridines, poly-9-vinylphenyl anthracenes, pyrene-formaldehyde resins and N-ethylcarbazole-formaldehyde resins.

Claim 23

Electrophotographic photosensitive member of claim 18 wherein the said positive hole transfer material is hydrazones.