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Poly(ester-amide) hot-melt adhesive

Assignee: Union Camp Corp
•
Filing: 1985-08-02
•
Granted: 1986-02-11
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Expires: 2005-08-02
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Abstract

Abstract There is disclosed a group of poly(ester-amide) compositions which possess unexpectedly good low temperature adhesive properties with respect to vinyl based substrates. These poly(ester-amide) compositions are the reaction product of a polymeric fatty acid, with an organic diamine, dicarboxylic acid and an alkanolamine having the general formula: ##STR1## wherein R 2 represents alkylene of 2 to 8 carbons, and R 1 is selected from the group consisting of hydrogen and a monovalent moiety of the formula: R.sub.3 --CH.sub.2 --CH.sub.2 -- (II) wherein R 3 is selected from hydroxyl and amino groups. The term "alkylene of 2 to 8 carbons" as used throughout the specification and claims means a divalent moiety of the formula: ##STR2## wherein n is an integer of from 0 to 6. N-(2-hydroxyethyl)piperazine is a preferred compound of the alkanolamine group.

Inventors

  • 👤 Charles R. Frihart
  • 👤 Richard L. Veazey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:19
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 90 words
A poly(ester-amide) adhesive composition which comprises; the product of the polymerization of (a) from 30 to 95 equivalent percent of a polymeric fatty acid; and (b) from 5 to 70 equivalent percent of a dicarboxylic acid; and with a substantially equivalent amount of (c) from 10 to 95 equivalent percent of an organic diamine; and (d) from 5 to 90 equivalent percent of an alkanolamine of the formula: ##STR6## wherein R 2 represents alkylene of 2 to 8 carbons, and R 1 is a monovalent moiety of the formula: ##STR7##
Claim 2
Dependent Claim 90 words
A poly(ester-amide) adhesive composition which comprises; the product of the polymerization of (a) from 30 to 95 equivalent percent of a polymeric fatty acid; and (b) from 5 to 70 equivalent percent of a dicarboxylic acid; and with a substantially equivalent amount of (c) from 10 to 95 equivalent percent of an organic diamine; and (d) from 5 to 90 equivalent percent of an alkanolamine of the formula: ##STR6## wherein R 2 represents alkylene of 2 to 8 carbons, and R 1 is a monovalent moiety of the formula: ##STR7##
Claim 3
Dependent Claim 21 words
The composition of claim 1 wherein the dicarboxylic acid is a straight chain aliphatic diacid having at least 6 carbon atoms.
Claim 4
Dependent Claim 15 words
The composition of claim 2 wherein the diacid has from 6 to 12 carbon atoms.
Claim 5
Dependent Claim 19 words
The composition of claim 3 wherein the diacid is selected from the group consisting of azelaic and sebacic acids.
Claim 6
Dependent Claim 15 words
The composition of claim 1 wherein the organic diamine is a straight chain aliphatic diamine.
Claim 7
Dependent Claim 11 words
The composition of claim 5 wherein the diamine is ethylene diamine.
Claim 8
Dependent Claim 13 words
The composition of claim 1 wherein the organic diamine is a cycloaliphatic diamine.
Claim 9
Dependent Claim 10 words
The composition of claim 7 wherein the diamine is 4,4'-methylenebis(cyclohexylamine).

References Cited (Backward Citations)

US3377303A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-10 1989-08-12 1990-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-10 1993-08-12 1994-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-10 1997-08-12 1998-02-11 $7700.00 Window Closed / Lapsed

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