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Foam and process for producing same

Assignee: Asahi Kasei Corp
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Filing: 1985-04-10
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Granted: 1986-02-11
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Expires: 2005-04-10
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Abstract

Abstract A novel foam composed of closed cells having a specific tensile strength of 150 kg/cm 2 or more, a compression recovery of 80% or more and a heat shrinkage of 50% or less, a variation in thickness of foam of less than 50%, a corrugation value of less than 100% and a surface smoothness of less than 2 mm, an average cell diameter of 0.05-3 mm, said foam having a foam density of 0.007-0.10 g/cm 3 , a variation in thickness of cell wall film of ±30% or less and a variation factor of cell diameter of 70% or less, obtained by foaming a composition consisting essentially of 100 parts by weight of a substantially non-crosslinked polyethylene having a density of 0.935 g/cm 3 or more and a melting point of 117° C. or more, 0.05-10 parts by weight of a foaming decelerant having the capability of prolonging the foaming time by at least one second as compared with the absence of the foaming decelerant, as measured by a glass tube blowing test method, and 0.001-5 parts by weight of a nucleating agent. The resulting foam has excellent mechanical properties and heat-resistance and has a good appearance.

Inventors

  • 👤 Kouroku Hoshi
  • 👤 Shoji Noro

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 13:50
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/12; C08J9/14; C08J9/0061; C08J9/0014; C08J9/0023; C08J9/0028; C08K; C08K5/00; C08K5/04; C08K5/06; C08K5/16; C08K5/17; C08L; C08L23/00; C08L23/02; C08L23/04; C08J2323/00; C08J2323/02; C08J2471/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 351 words
A foam composed of closed cells having a specific tensile strength of 150 kg/cm 2 or more, a compression recovery of 80% or more and a heat shrinkage of 50% or less, a variation in thickness of foam of less than 50%, a corrugation value of less than 100% and a surface smoothness of less than 2 mm, an average cell diameter of 0.05-3 mm, said foam having a foam density of 0.007-0.10 g/cm 3 , a variation in thickness of cell wall film of ±30% or less and a variation of cell diameter of 70% or less, obtained by foaming a composition consisting essentially of 100 parts by weight of a substantially non-crosslinked crystalline polyethylene having a density of 0.935 g/cm 3 or more and a melting point of 117° C. or more, 0.05-10 parts by weight of a foaming decelerant having the capability of prolonging the foaming time by at least one second as compared with the absence of the foaming decelerant, as measured by a glass tube blowing test method, wherein said foaming decelerant is a compound represented by a formula selected from at least one of the general formula: (H).sub.x --N[(R.sub.1 -O).sub.n A].sub.3-x I. wherein R 1 is an alkylene group having 1-5 carbon atoms, A is a hydrogen atom or an acyl group, n is an integer of 1-10, and x is 0 or an integer of 1-2; HO(R.sub.2 O).sub.m H II. wherein R 2 's may be identical with or different from one another and represent divalent hydrocarbon groups having 1-6 carbon atoms and m is an integer of 1 or more; and ##STR11## wherein R 5 is hydrogen or a substituent represented by ##STR12## wherein R 9 and R 10 represent hydrogen or hydrocarbon groups having 1-23 carbon atoms; R 11 is a hydrocarbon group having 1-6 carbon atoms, and l is 0 or an integer of 1-6, R 6 and R 7 are hydrogen or hydrocarbon groups having 1-23 carbon atoms; and R 8 is hydrogen or a hydrocarbon group having 1-6 carbon atoms, and 0.001-5 parts by weight of a nucleating agent.
Claim 2
Dependent Claim 351 words
A foam composed of closed cells having a specific tensile strength of 150 kg/cm 2 or more, a compression recovery of 80% or more and a heat shrinkage of 50% or less, a variation in thickness of foam of less than 50%, a corrugation value of less than 100% and a surface smoothness of less than 2 mm, an average cell diameter of 0.05-3 mm, said foam having a foam density of 0.007-0.10 g/cm 3 , a variation in thickness of cell wall film of ±30% or less and a variation of cell diameter of 70% or less, obtained by foaming a composition consisting essentially of 100 parts by weight of a substantially non-crosslinked crystalline polyethylene having a density of 0.935 g/cm 3 or more and a melting point of 117° C. or more, 0.05-10 parts by weight of a foaming decelerant having the capability of prolonging the foaming time by at least one second as compared with the absence of the foaming decelerant, as measured by a glass tube blowing test method, wherein said foaming decelerant is a compound represented by a formula selected from at least one of the general formula: (H).sub.x --N[(R.sub.1 -O).sub.n A].sub.3-x I. wherein R 1 is an alkylene group having 1-5 carbon atoms, A is a hydrogen atom or an acyl group, n is an integer of 1-10, and x is 0 or an integer of 1-2; HO(R.sub.2 O).sub.m H II. wherein R 2 's may be identical with or different from one another and represent divalent hydrocarbon groups having 1-6 carbon atoms and m is an integer of 1 or more; and ##STR11## wherein R 5 is hydrogen or a substituent represented by ##STR12## wherein R 9 and R 10 represent hydrogen or hydrocarbon groups having 1-23 carbon atoms; R 11 is a hydrocarbon group having 1-6 carbon atoms, and l is 0 or an integer of 1-6, R 6 and R 7 are hydrogen or hydrocarbon groups having 1-23 carbon atoms; and R 8 is hydrogen or a hydrocarbon group having 1-6 carbon atoms, and 0.001-5 parts by weight of a nucleating agent.
Claim 3
Dependent Claim 57 words
A foam according to claim 1, wherein said decelerant is selected from II and is represented by the formula: HO(R.sub.3 O).sub.a (R.sub.4 O).sub.b (R.sub.3 O).sub.c H wherein R 3 and R 4 are different from each other and represent divalent hydrocarbon groups having 1-6 carbon atoms, and a, b and c are integers of 1 or more.
Claim 4
Dependent Claim 36 words
A foam according to claim 1, wherein said polyethylene has a melt index of 0.02-40 g/10 minutes as measured at 190° C. under a load of 21,600 g and a swelling value of 20-50 g/20 cm.
Claim 5
Dependent Claim 58 words
A foam according to claim 1, wherein said foaming decelerant is a compound represented by the following general formula: (H).sub.x --N[(R.sub.1 --O).sub.n A].sub.3-x wherein R 1 is an alkylene group having 1-5 carbon atoms, A is a hydrogen atom or an acyl group, n is an integer of 1-10, and x is 0 or an integer of 1-2.
Claim 6
Dependent Claim 53 words
A foam according to claim 1, wherein said foaming decelerant is a compound represented by the following general formula: HO(R.sub.2 O).sub.m H wherein R 2 's may be identical with or different from one another, and represent divalent hydrocarbon groups having 1-6 carbon atoms and m is an integer of 1 or more.
Claim 7
Dependent Claim 52 words
A foam according to claim 5, wherein said decelerant is represented by the formula: HO(R.sub.3 O).sub.a (R.sub.4 O).sub.b (R.sub.3 O).sub.c H wherein R 3 and R 4 are different from each other and represent divalent hydrocarbon groups having 1-6 carbon atoms, and a, b and c are integers of 1 or more.
Claim 8
Dependent Claim 24 words
A foam according to claim 6, wherein R 3 in the general formula is --CH 2 CH 2 -- and R 4 is ##STR13##
Claim 9
Dependent Claim 91 words
A foam according to claim 1, wherein said foaming decelerant is a compound represented by the general formula: ##STR14## wherein R 5 is hydrogen or a substituent represented by ##STR15## wherein R 9 and R 10 represent hydrogen or hydrocarbon groups having 1-23 carbon atoms; R 11 is a hydrocarbon group having 1-6 carbon atoms, and l is 0 or an integer of 1-6, R 6 and R 7 are hydrogen or hydrocarbon groups having 1-23 carbon atoms; and R 8 is hydrogen or a hydrocarbon group having 1-6 carbon atoms.

References Cited (Backward Citations)

US2956960A Cited
US3102865A Cited
US4214054A Cited
US4343913A Cited
US4275168A Cited
EP0036562A2 Cited
EP0036560A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-10 1989-08-12 1990-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-10 1993-08-12 1994-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-10 1997-08-12 1998-02-11 $7700.00 Window Closed / Lapsed

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