Patent US4568785A successfully refreshed from Google Patents.
US4568785A
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Preparative process for methane conversion agents
Assignee: Atlantic Richfield Co
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Filing: 1984-04-16
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Granted: 1986-02-04
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Expires: 2004-04-16
Abstract
Abstract An improved support for a contact agent, useful for converting methane to higher hydrocarbon products by contacting a gas comprising methane with a contact agent at a selected temperature, is formed by sintering the surface of the support.
Inventors
- 👤 John A. Jaecker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:57
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/08; B01J23/14; B01J23/16; B01J23/18; B01J23/32; B01J23/34; C; C07; C07C; C07C2/00; C07C2/76; C07C2/82; C07C2/84; C07C2521/00; C07C2521/06; C07C2521/08; C07C2521/10; C07C2523/00; C07C2523/02; C07C2523/04; C07C2523/08; C07C2523/14; C07C2523/16; C07C2523/18; C07C2523/32; C07C2523/34; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/943
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
131 words
In an improved method for converting a gas comprising methane to higher hydrocarbons which comprises contacting said gas with a contact agent comprising: (a) at least one metal, the oxide of which is reduced and produces higher hydrocarbons and water when contacted with methane at a selected temperature in the range of about 500° to about 1000° C.; and (b) a support associated with said oxide, at conditions to convert said gas to said higher hydrocarbons and water and to reduce said metal oxide, the improvement which comprises employing said contact agent wherein the surface of at least a portion of said support has been sintered at an elevated temperature equal to at least about 0.33 of the normal melting temperature of the material of said support prior to said contacting.
Claim 2
Dependent Claim
131 words
In an improved method for converting a gas comprising methane to higher hydrocarbons which comprises contacting said gas with a contact agent comprising: (a) at least one metal, the oxide of which is reduced and produces higher hydrocarbons and water when contacted with methane at a selected temperature in the range of about 500° to about 1000° C.; and (b) a support associated with said oxide, at conditions to convert said gas to said higher hydrocarbons and water and to reduce said metal oxide, the improvement which comprises employing said contact agent wherein the surface of at least a portion of said support has been sintered at an elevated temperature equal to at least about 0.33 of the normal melting temperature of the material of said support prior to said contacting.
Claim 3
Dependent Claim
23 words
The method of claim 1 wherein said support is selected from a group consisting of magnesia, silica, alumina, titania, zirconia, and mixtures thereof.
Claim 4
Dependent Claim
23 words
The method of claim 2 wherein said support comprises magnesia and is sintered at a temperature of about 1690° and about 5070° F.
Claim 5
Dependent Claim
23 words
The method of claim 2 wherein said support comprises silica and is sintered at a temperature of about 1040° and about 3110° F.
Claim 6
Dependent Claim
26 words
The method of claim 1 wherein said reducible oxide is selected from the group consisting of manganese, tin, indium, germanium, antimony, lead, bismuth, and mixtures thereof.
Claim 7
Dependent Claim
29 words
The method of claim 1 wherein said agent comprises additionally a promoting amount of at least one promoter selected from the group consisting of alkali metals and compounds thereof.
Claim 8
Dependent Claim
23 words
The method of claim 1 wherein the surface area of said support ranges from about 30 to about 90 square meters per gram.
Claim 9
Dependent Claim
19 words
The method of claim 1 wherein said support is sintered before said reducible oxide is admixed with said support.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-02-03 | 1989-08-05 | 1990-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-02-03 | 1993-08-05 | 1994-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-02-03 | 1997-08-05 | 1998-02-04 | $7700.00 | Window Closed / Lapsed |