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US4564561A
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Fluorine-containing polymer compositions and their preparation
Assignee: EIDP Inc
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Filing: 1985-03-27
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Granted: 1986-01-14
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Expires: 2005-03-27
Abstract
Abstract Mixtures of (1) a polymer of at least one polyfluoroalkyl acrylate or methacrylate and (2) a copolymer of (a) at least one polyfluoroalkyl acrylate or methacrylate, (b) at least one 3-chloro- (or 3-bromo-) 2-hydroxypropyl acrylate or methacrylate, (c) at least one alkyl acrylate or methacrylate and (d) at least one polyoxyethylene acrylate or methacrylate. Mixtures are prepared by first polymerizing (1) and then (2) (a)-(d). Mixtures are useful as oil- and water-repellents, particularly for rainwear.
Inventors
- 👤 Albert L. Lore
- 👤 Stuart Raynolds
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:55
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/04; C08L33/14; C08L33/16; C08L2205/00; C08L2205/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
211 words
Fluorine-containing polymeric compositions consisting essentially of mixtures of (1) an addition polymer of at least one monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2, and (2) an addition copolymer of (a) at least one monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2, (b) at least one monomer having the formula XCH.sub.2 CH(OH)CH.sub.2 OC(O)C(R.sup.1)=CH.sub.2, (c) at least one monomer having the formula R.sup.2 OC(O)C(R.sup.3)=CH.sub.2, and (d) at least one monomer having the formula H(OCH.sub.2 CH.sub.2).sub.n OC(O)C(R.sup.4)=CH.sub.2 wherein R, R 1 , R 3 , and R 4 are the same or different H or CH 3 ; R 2 is alkyl containing 2 to 18 carbons; X is Cl or Br; k is an integer from 2 to 18; m is an integer from 1 to 15; and n is an integer from 5 to 50; based upon the total weight of the polymeric composition, the fluorinated monomer or mixture of fluorinated monomers constituting 20 to 80 percent by weight of the composition; the chlorine- or bromine-containing monomer constituting between 5 and 35 percent by weight of the composition; the alkyl acrylate or methacrylate constituting between 5 and 55 weight percent of the composition and the oxyethylated acrylate or methacylate constituting between 0.1 and 3 weight percent thereof.
Claim 2
Dependent Claim
211 words
Fluorine-containing polymeric compositions consisting essentially of mixtures of (1) an addition polymer of at least one monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2, and (2) an addition copolymer of (a) at least one monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2, (b) at least one monomer having the formula XCH.sub.2 CH(OH)CH.sub.2 OC(O)C(R.sup.1)=CH.sub.2, (c) at least one monomer having the formula R.sup.2 OC(O)C(R.sup.3)=CH.sub.2, and (d) at least one monomer having the formula H(OCH.sub.2 CH.sub.2).sub.n OC(O)C(R.sup.4)=CH.sub.2 wherein R, R 1 , R 3 , and R 4 are the same or different H or CH 3 ; R 2 is alkyl containing 2 to 18 carbons; X is Cl or Br; k is an integer from 2 to 18; m is an integer from 1 to 15; and n is an integer from 5 to 50; based upon the total weight of the polymeric composition, the fluorinated monomer or mixture of fluorinated monomers constituting 20 to 80 percent by weight of the composition; the chlorine- or bromine-containing monomer constituting between 5 and 35 percent by weight of the composition; the alkyl acrylate or methacrylate constituting between 5 and 55 weight percent of the composition and the oxyethylated acrylate or methacylate constituting between 0.1 and 3 weight percent thereof.
Claim 3
Dependent Claim
30 words
The composition of claim 1 wherein the polymeric units (1) and (2)(a) consists of copolymeric units in which 80-90% by weight of the perfluoroalkyl radicals contain 6 to 12 carbons.
Claim 4
Dependent Claim
21 words
The composition of claim 2 wherein the average of the chain lengths in the perfluoroalkyl radicals is 6 to 8 carbons.
Claim 5
Dependent Claim
11 words
The composition of claim 1 wherein R is CH 3 .
Claim 6
Dependent Claim
9 words
The composition of claim 4 wherein m is 2.
Claim 7
Dependent Claim
32 words
The composition of claim 5 wherein the polymeric units (1) and (2)(a) consists of copolymeric units in which 80 to 90% by weight of the perfluoroalkyl radicals contain 6 to 12 carbons.
Claim 8
Dependent Claim
21 words
The composition of claim 6 wherein the average of the chain lengths in the perfluoroalkyl radicals is 6 to 8 carbons.
Claim 9
Dependent Claim
26 words
The composition of claim 7 wherein k is 2, 4, 6, 8, 10 and 12 in an approximate weight ratio fo 2/35/30/18/8/3 in said copolymeric units.
Claim 10
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 1 to substrates.
Claim 11
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 2 to substrates.
Claim 12
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 3 to substrates.
Claim 13
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 4 to substrates.
Claim 14
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 5 to substrates.
Claim 15
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 6 to substrates.
Claim 16
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 7 to substrates.
Claim 17
Dependent Claim
27 words
A process for imparting oil and water repellency to fibrous and filamentary substrates which comprises applying an aqueous dispersion of the compositions of claim 8 to substrates.
Claim 18
Dependent Claim
28 words
A fibrous or filamentary substrate which contains a coating of the composition of claim 1 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 19
Dependent Claim
28 words
A fibrous or filamentary substrate which contains a coating of the composition of claim 2 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 20
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 3 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 21
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 4 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 22
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 5 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 23
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 6 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 24
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 7 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 25
Dependent Claim
29 words
A fibrous or filamentary nylon substrate which contains a coating of the composition of claim 8 in an amount sufficient to impart oil and water repellency to said substrate.
Claim 26
Dependent Claim
113 words
A process for manufacturing the composition of claim 1 which consists essentially of (1) subjecting to addition polymerization at least one fluorine-containing monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2, then (2) subjecting to addition polymerization a mixture of (a) at least one fluorine-containing monomer having the formula CF.sub.3 CF.sub.2 (CF.sub.2).sub.k C.sub.m H.sub.2m OC(O)C(R)=CH.sub.2 (b) at least one monomer having the formula XCH.sub.2 CH(OH)CH.sub.2 OC(O)C(R.sup.1)=CH.sub.2, (c) at least one monomer having the formula R.sup.2 OC(O)C(R.sup.3)=CH.sub.2, and (d) at least one monomer having the formula H(OCH.sub.2 CH.sub.2).sub.n OC(O)C(R.sup.4)=CH.sub.2, the amount of fluorine-containing monomer used in step (1) being between 60 and 90 weight percent of the total thereof used in the process.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-01-13 | 1989-07-15 | 1990-01-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-13 | 1993-07-15 | 1994-01-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-13 | 1997-07-15 | 1998-01-14 | $7700.00 | Window Closed / Lapsed |