US4563263A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Selectively permeable film and ion sensor
Assignee: Terumo Corp
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Filing: 1982-01-15
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Granted: 1986-01-07
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Expires: 2002-01-15
Abstract
Abstract A selectively permeable film directly applied to coat the surface of an electroconductive element, said electively permeable film comprising a polymer which is derived from at least one aromatic compound selected from the group of nitrogen-containing aromatic compounds or from the group of hydroxy aromatic compounds. The nitrogen-containing aromatic compounds are aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline, tyramine, N-(o-hydroxybenzyl)-aniline and pyrrole. The film coated on the electrode surfaces permits selective passage of ions and the electrode can be used as an ions sensor for measuring the concentration of ions in solutions.
Inventors
- 👤 Noboru Oyama
- 👤 Hiroaki Matsuda
- 👤 Eishun Tsuchida
- 👤 Yukio Ohnuki
- 👤 Takeshi Shimomura
- 👤 Norihiko Ushizawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 14:40
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; G01N27/333; G01N27/3335
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
158 words
A system for measuring the concentration of hydrogen ions in a test solution by electrode potential response or current response, comprising: a hydrogen ion sensor adapted to contact said test solution; and means coupled to said hydrogen ion sensor for measuring the electrical potential difference between said hydrogen ion sensor while contacting said test solution and a reference potential; said hydrogen ion sensor consisting essentially of an electroconductive element having applied to a surface thereof a polymer film derived from at least one aromatic compound selected from the group consisting of nitrogen-containing aromatic compounds selected from the group consisting of aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline, tyramine, N-(o-hydroxybenzyl)aniline, and pyrrole and a hydroxy aromatic compound selected from compounds having the formula ##STR3## wherein Ar is an aromatic ring, R is selected from the group consisting of alkyl, aryl, alkylcarbonyl, arylcarbonyl hydroxyalkyl, carboxyl, aldehyde, and hydroxyl, and l is zero or the valency number of the Ar group.
Claim 2
Independent Claim
158 words
A system for measuring the concentration of hydrogen ions in a test solution by electrode potential response or current response, comprising: a hydrogen ion sensor adapted to contact said test solution; and means coupled to said hydrogen ion sensor for measuring the electrical potential difference between said hydrogen ion sensor while contacting said test solution and a reference potential; said hydrogen ion sensor consisting essentially of an electroconductive element having applied to a surface thereof a polymer film derived from at least one aromatic compound selected from the group consisting of nitrogen-containing aromatic compounds selected from the group consisting of aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline, tyramine, N-(o-hydroxybenzyl)aniline, and pyrrole and a hydroxy aromatic compound selected from compounds having the formula ##STR3## wherein Ar is an aromatic ring, R is selected from the group consisting of alkyl, aryl, alkylcarbonyl, arylcarbonyl hydroxyalkyl, carboxyl, aldehyde, and hydroxyl, and l is zero or the valency number of the Ar group.
Claim 3
Dependent Claim
23 words
The system of claim 1, wherein the polymer film is a film polymerized by electrochemical oxidation on the surface of the electroconductive element.
Claim 4
Dependent Claim
28 words
The system of claim 1, wherein the polymer film is a film obtained by applying to the surface of the electroconductive element a solution of the synthesized polymer.
Claim 5
Dependent Claim
16 words
The system of claim 1, wherein the polymer film is derived from said nitrogen-containing aromatic compound.
Claim 6
Dependent Claim
14 words
The system of claim 1, wherein said hydrogen ion sensor is a pH sensor.
Claim 7
Dependent Claim
16 words
The system of claim 1, wherein the polymer film is derived from said hydroxy aromatic compound.
Claim 8
Dependent Claim
62 words
The system of claim 1, wherein the hydroxy aromatic compound is at least one member selected from the group consisting of phenol, dimethyl phenol, hydroxypyridine, o- and m-benzyl alcohols, o-, m- and p-hydroxybenzaldehydes, o-, m- and p-hydroxyacetophenones, o-, m- and p-hydroxypropiophenones, o-, m- and p-benzophenols, o-, m- and p-hydroxybenzophenones, o-, m- and p-carboxyphenols, diphenyl phenol, 2-methyl-8-hydroquinoline, 5-hydroxy-1,4-naphthoquinone, 4-(p-hydroxyphenyl)-2-butanone, 1,5-dihydroxy-1,2,3,4-tetrahydronaphthalene and bis-phenol A.
Claim 9
Independent Claim
109 words
A system for measuring the concentration of hydrogen ions in a test solution by electrode potential response or current response, comprising: a hydrogen ion sensor adapted to contact said test solution; and means coupled to said hydrogen ion sensor for measuring the electrical potential difference between said hydrogen ion sensor while contacting said test solution and a reference potential; said hydrogen ion sensor comprising an electroconductive element having applied to a surface thereof a polymer film derived from at least one aromatic compound selected from the group consisting of nitrogen-containing aromatic compounds selected from the group consisting of aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline tyramine, N-(o-hydroxybenzyl)aniline, and pyrrole.
Claim 10
Independent Claim
109 words
A system for measuring the concentration of hydrogen ions in a test solution by electrode potential response or current response, comprising: a hydrogen ion sensor adapted to contact said test solution; and means coupled to said hydrogen ion sensor for measuring the electrical potential difference between said hydrogen ion sensor while contacting said test solution and a reference potential; said hydrogen ion sensor comprising an electroconductive element having applied to a surface thereof a polymer film derived from at least one aromatic compound selected from the group consisting of nitrogen-containing aromatic compounds selected from the group consisting of aniline, 2-aminobenzotrifluoride, 2-aminopyridine, 2,3-diaminopyridine, 4,4'-diaminodiphenyl ether, 4,4'-methylenedianiline tyramine, N-(o-hydroxybenzyl)aniline, and pyrrole.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-01-06 | 1989-07-08 | 1990-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-06 | 1993-07-08 | 1994-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-06 | 1997-07-08 | 1998-01-07 | $7700.00 | Window Closed / Lapsed |