Alkoxylated amine-phosphite reaction product and lubricant and fuel containing same

Claim 2

A product of reaction made by reacting (1) an alkoxylated amine of the formula ##STR4## wherein R is a C 6 to C 30 hydrocarbyl group, R 1 is hydrogen or a C 1 to C 6 hydrocarbyl group, and x and y are integers of from 0 to 10, at least one of which is not 0 with (2) a phosphite of the formula ##STR5## wherein R 2 is a C 1 to C 6 hydrocarbyl group, said reacting being carried out at a temperature between about 80° C. and about 200° C. and in reactant proportions such that from about 5 percent to about 100 percent of the amine hydroxy groups are reacted with said phosphite.

Claim 3

The product of claim 1 wherein the C 6 to C 30 hydrocarbyl group is alkyl, aryl, alkenyl, alkaryl, aralkyl or cycloalkyl.

Claim 4

The product of claim 1, wherein R 1 is an alkyl group.

Claim 5

The product of claim 1 wherein R 2 is an alkyl group.

Claim 6

The product of claim 1 wherein the alkoxylated amine is 2-hydroxylethylhexylamine, 2-hydroxyethyloctylamine, 2-hydroxyethyldodecylamine, 2-hydroxyethyltetradecylamine, 2-hydroxyethylpentadecylamine, 2-hydroxyethyleicosylamine, 2-hydroxyethyltriacontylamine, 2-hydroxyethyloleylamine, 2-hydroxyethyltallowamine, 2-hydroxyethylsoyamine, bis(2-hydroxyethyl)hexylamine, bis(2-hydroxyethyl)octylamine, bis(2-hydroxyethyl)dodecylamine, bis(2-hydroxyethyl)tetradecylamine, bis(2-hydroxyethyl)pentadecylamine, bis(2-hydroxyethyl)eicosylamine, bis(2-hydroxyethyl)triacontylamine, bis(2-hydroxyethyl)oleylamine, bis(2-hydroxyethyl)tallowamine, bis(2-hydroxyethyl)soyamine, 2-hydroxylpropylhexylamine, 2-hydroxypropyloctylamine, 2-hydroxypropyldodecylamine, 2-hydroxypropyltetradecylamine, 2-hydroxypropylpentadecylamine, 2-hydroxypropyleicosylamine, 2-hydroxypropyltriacontylamine, 2-hydroxypropyloleylamine, 2-hydroxypropyltallowamine, 2-hydroxypropylsoyamine, bis(2-hydroxypropyl)hexylamine, bis(2-hydroxypropyl)octylamine, bis(2-hydroxypropyl)dodecylamine, bis(2-hydroxypropyl)tetradecylamine, bis(2-hydroxypropyl)pentadecylamine, bis(2-hydroxypropyl)eicosylamine, bis(2-hydroxypropyl)triacontylamine, bis(2-hydroxypropyl)oleylamine, bis(2-hydroxypropyl)tallowamine, bis(2-hydroxypropyl)soyamine or mixtures thereof.

Claim 7

The product of claim 1 wherein the phosphite is dimethyl phosphite, diethyl phosphite, dipropyl phosphite, dibutyl phosphite, diamyl phosphite, dihexyl phosphite or mixtures thereof.

Claim 8

The product of claim 1 wherein the alkoxylated amine is bis(2-hydroxyethyl)oleylamine and the phosphite is dimethyl phosphite.

Claim 9

The product of claim 1 wherein the alkoxylated amine is bis(2-hydroxyethyl)cocoamine and the phosphite is dimethyl phosphite.

Claim 10

The product of claim 1 wherein the alkoxylated amine is bis(2-hydroxyethyl)soyamine and the phosphite is dimethyl phosphite.

Claim 11

A lubricant composition comprising a major proportion of a lubricant selected from the group consisting of (1) mineral oil, (2) synthetic oil, (3) mixtures of synthetic oils; (4) mixtures of mineral oil and synthetic oil; and (5) grease from (1), (2), (3) or (4), and a friction reducing amount of a product made by reacting (1) an alkoxylated amine of the formula ##STR6## wherein R is a C 6 to C 30 hydrocarbyl group, R 1 is hydrogen or a C 1 to C 6 hydrocarbyl group, and x and y are integers of from 0 to 10, at least one of which is not 0 with (2) a phosphite of the formula ##STR7## wherein R is a C 1 to C 6 hydrocarbyl group said reacting being carried out at a temperature between about 80° C. and about 200° C. and in reactant proportions such that from about 5 percent to about 100 percent of the amine hydroxy groups are reacted with said phosphite.

Claim 12

A lubricant composition comprising a major proportion of a lubricant selected from the group consisting of (1) mineral oil, (2) synthetic oil, (3) mixtures of synthetic oils; (4) mixtures of mineral oil and synthetic oil; and (5) grease from (1), (2), (3) or (4), and a friction reducing amount of a product made by reacting (1) an alkoxylated amine of the formula ##STR6## wherein R is a C 6 to C 30 hydrocarbyl group, R 1 is hydrogen or a C 1 to C 6 hydrocarbyl group, and x and y are integers of from 0 to 10, at least one of which is not 0 with (2) a phosphite of the formula ##STR7## wherein R is a C 1 to C 6 hydrocarbyl group said reacting being carried out at a temperature between about 80° C. and about 200° C. and in reactant proportions such that from about 5 percent to about 100 percent of the amine hydroxy groups are reacted with said phosphite.

Claim 13

The composition of claim 10 wherein the C 6 to C 30 hydrocarbyl group is alkyl, aryl, alkeryl, alkaryl, aralkyl or cycloalkyl.

Claim 14

The composition of claim 10 wherein R 1 is an alkyl group.

Claim 15

The composition of claim 10 wherein R 2 is an alkyl group.

Claim 16

The composition of claim 10 wherein the alkoxylated amine is 2-hydroxylethylhexylamine, 2-hydroxyethyloctylamine, 2-hydroxyethyldodecylamine, 2-hydroxyethyltetradecylamine, 2-hydroxyethylpentadecylamine, 2-hydroxyethyleicosylamine, 2-hydroxyethyltriacontylamine, 2-hydroxyethyloleylamine, 2-hydroxyethyltallowamine, 2-hydroxyethylsoyamine, bis(2-hydroxyethyl)hexylamine, bis(2-hydroxyethyl)octylamine, bis(2-hydroxyethyl)dodecylamine, bis(2-hydroxyethyl)tetradecylamine, bis(2-hydroxyethyl)pentadecylamine, bis(2-hydroxyethyl)eicosylamine, bis(2-hydroxyethyl)triacontylamine, bis(2-hydroxyethyl)oleylamine, bis(2-hydroxyethyl)tallowamine, bis(2-hydroxyethyl)soyamine, 2-hydroxylpropylhexylamine, 2-hydroxypropyloctylamine, 2-hydroxypropyldodecylamine, 2-hydroxypropyltetradecylamine, 2-hydroxypropylpentadecylamine, 2-hydroxypropyleicosylamine, 2-hydroxypropyltriacontylamine, 2-hydroxypropyloleylamine, 2-hydroxypropyltallowamine, 2-hydroxypropylsoyamine, bis(2-hydroxypropyl)hexylamine, bis(2-hydroxypropyl)octylamine, bis(2-hydroxypropyl)dodecylamine, bis(2-hydroxypropyl)tetradecylamine, bis(2-hydroxypropyl)pentadecylamine, bis(2-hydroxypropyl)eicosylamine, bis(2-hydroxypropyl)triacontylamine, bis(2-hydroxypropyl)oleylamine, bis(2-hydroxypropyl)tallowamine, bis(2-hydroxypropyl)soyamine or mixtures thereof.

Claim 17

The composition of claim 10 wherein the phosphite is dimethyl phosphite, diethyl phosphite, dipropyl phosphite, dibutyl phosphite, diamyl phosphite, dihexyl phosphite or mixtures thereof.

Claim 18

The composition of claim 10 wherein the alkoxylated amine is bis(2-hydroxyethyl)oleylamine and the phosphite is dimethyl phosphite.

Claim 19

The composition of claim 10 wherein the alkoxylated amine is bis(2-hydroxyethyl)cocamine and the phosphite is dimethyl phosphite.

Claim 20

The composition of claim 10 wherein the alkoxylated amine is bis(2-hydroxyethyl)soyamine and the phosphite is dimethyl phosphite.

Claim 21

The composition of claim 10 wherein the lubricant is (1) a mineral oil, (2) a synthetic oil or mixtures of synthetic oils, (3) a mixture of (1) and (2) and (4) a grease from (1), (2) or (3).

Claim 22

The composition of claim 19 wherein the lubricant is a mineral oil.

Claim 23

The composition of claim 19 wherein the lubricant is a synthetic oil or mixtures of synthetic oils.

Claim 24

The composition of claim 19 wherein the lubricant is the mixture of (3).

Claim 25

The composition of claim 19 wherein the lubricant is said grease.

Claim 26

The composition of claim 10 wherein said liquid fuel is a liquid hydrocarbon or a liquid alcohol.