Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same

Claim 2

A product of reaction made by reacting phosphorus pentoxide, a vicinal diol, of the formula R(OH) 2 wherein R is a hydrocarbyl group containing 8 to 30 carbon atoms, a boron compound selected from the group consisting of boric oxide, a metaborate or boron compounds having the formula (R.sup.1 O).sub.x B(OH).sub.y wherein R 1 is a C 1 to C 6 alkyl group and x and y are each 0 to 3, their sum being 3, and a hydrocarbylamine having one of the following formulae: ##STR5## wherein R 2 is a C 2 to C 30 hydrocarbyl group, R 3 and R 4 are hydrogen or a C 1 to C 20 hydrocarbyl group, R 5 is a C 12 to C 20 hydrocarbyl group, R 7 is a C 1 to C 4 alkylene group and each of R 6 , R 8 and R 9 is selected from hydrogen or a C 1 to C 20 hydrocarbyl group.

Claim 3

The product of claim 1 wherein the hydrocarbyl group is an alkyl, aryl, aralkyl or cycloalkyl group.

Claim 4

The product of claim 1 wherein the diol is 1,2-decanediol, 1,2-dodecandeiol, 1,2-tetradecanediol, 1,2-pentadecanediol, 1,2-hexadecanediol, 1,2-heptadecanediol, 1,2-octadecanediol, 1,2-eicosanediol, 1,2-triacontanediol, mixed C 15 to C 18 alkanediols or mixtures of any of these.

Claim 5

The product of claim 1 wherein the boron compound is boric acid, mono-, di- or trimethyl borate; mono-, di- or triethyl borate; mono-, di- or tripropyl borate; mono-, di- or tributyl borate; mono-, di-, or tripentyl borate; or mono-, di- or trihexyl borate.

Claim 6

The product of claim 4 wherein the boron compound is boric acid.

Claim 7

The product of claim 1 wherein the hydrocarbylamine is hexylamine, octylamine, decylamine, tetradecylamine, octadecylamine, eicoxylamine, triacontylamine, the secondary and tertiary counterparts thereof, oleylamine, cocoamine, tallowamine, soyamine, t-butylamine, N-dodecyl-1,2-ethylenediamine, N-oleyl-1,2-ethylenediamine, N-coco-1,2-ethylenediamine, N-soyl-1,2-ethylenediamine, N-tallowyl-1,2-ethylenediamine, N-dodecyl-1,3-propylenediamine, N-oleyl-1,3-propylenediamine, N-coco-1,3-propylenediamine, N-soyl-1,3-propylenediamine or N-tallowyl-1,3-propylenediamine.

Claim 8

The product of claim 1 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is oleylamine.

Claim 9

The product of claim 1 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is a mixed C 12 to C 14 t-alkylamine.

Claim 10

The product of claim 1 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is N-oleyl-1,3-propylenediamine.

Claim 11

A lubricant composition comprising a major proportion of a lubricant and between about 0.1 and about 10% by weight of the total composition of a product of reaction made by reacting phosphorus pentoxide, a vicinal diol, of the formula (R(OH).sub.2 wherein R is a hydrocarbyl group containing 8 to 30 carbon atoms, a boron compound selected from the group consisting of boric oxide, a metaborate or a boron compound having the formula (R.sup.1 O).sub.x B(OH).sub.y wherein R 1 is a C 1 to C 6 alkyl group and x and y are each 0 to 3, their sum being 3, and a hydrocarbylamine having one of the following formulae: ##STR6## wherein R 2 is a C 2 to C 30 hydrocarbyl group, R 3 and R 4 are hydrogen or a C 1 to C 20 hydrocarbyl group, R 5 is a C 12 to C 20 hydrocarbyl group, R 7 is a C 1 to C 4 alkylene group and each of R 6 , R 8 and R 9 is selected from hydrogen or a C 1 to C 20 hydrocarbyl group.

Claim 12

A lubricant composition comprising a major proportion of a lubricant and between about 0.1 and about 10% by weight of the total composition of a product of reaction made by reacting phosphorus pentoxide, a vicinal diol, of the formula (R(OH).sub.2 wherein R is a hydrocarbyl group containing 8 to 30 carbon atoms, a boron compound selected from the group consisting of boric oxide, a metaborate or a boron compound having the formula (R.sup.1 O).sub.x B(OH).sub.y wherein R 1 is a C 1 to C 6 alkyl group and x and y are each 0 to 3, their sum being 3, and a hydrocarbylamine having one of the following formulae: ##STR6## wherein R 2 is a C 2 to C 30 hydrocarbyl group, R 3 and R 4 are hydrogen or a C 1 to C 20 hydrocarbyl group, R 5 is a C 12 to C 20 hydrocarbyl group, R 7 is a C 1 to C 4 alkylene group and each of R 6 , R 8 and R 9 is selected from hydrogen or a C 1 to C 20 hydrocarbyl group.

Claim 13

The composition of claim 10 wherein the hydrocarbyl group is an alkyl, aryl, aralkyl or cycloalkyl group.

Claim 14

The composition of claim 10 wherein the diol is 1,2-decanediol, 1,2-dodecandeiol, 1,2-tetradecanediol, 1,2-pentadecanediol, 1,2-hexadecanediol, 1,2-heptadecanediol, 1,2-octadecanediol, 1,2-eicosanediol, 1,2-triacontanediol, mixed C 15 to C 18 alkanediols or mixtures of any of these.

Claim 15

The composition of claim 10 wherein the boron compound is boric acid, mono-, di- or trimethyl borate; mono-, di- or triethyl borate; mono-, di- or tripropyl borate; mono, di- or tributyl borate; mono-, di-, or tripentyl borate; or mono-, di- or trihexyl borate.

Claim 16

The composition of claim 7 wherein the boron compound is boric acid.

Claim 17

The composition of claim 10 wherein hydrocarbylamine is hexylamine, octylamine, decylamine, tetradecylamine, octadecylamine, eicoxylamine, triacontylamine, the secondary and tertiary counterparts thereof, oleylamine, cocoamine, tallowamine, soyamine, t-butylamine, N-dodecyl-1,2-ethylenediamine, N-oleyl-1,2-ethylenediamine, N-coco-1,2-ethylenediamine, N-soyl-1,2-ethylenediamine, N-tallowyl-1,2-ethylenediamine, N-dodecyl-1,3-propylenediamine, N-oleyl-1,3-propylenediamine, N-coco-1,3-propylenediamine, N-soyl-1,3-propylenediamine or N-tallowyl-1,3-propylenediamine.

Claim 18

The composition of claim 10 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is oleylamine.

Claim 19

The composition of claim 10 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is a mixed C 12 to C 14 t-alkylamine.

Claim 20

The composition of claim 10 wherein the diol is 1,2-mixed pentadecanediol-octadecanediol, the phosphorus oxide is phosphorus pentoxide, the boron compound is boric acid and the hydrocarbylamine is N-oleyl-1,3-propylenediamine.

Claim 21

The composition of claim 10 wherein the lubricant is (1) a mineral oil, (2) a synthetic oil or a mixture of synthetic oils, (3) a mixture of (1) and (2) or (4) a grease of (1), (2) or (3).

Claim 22

The composition of claim 19 wherein the lubricant is a mineral oil.

Claim 23

The composition of claim 19 wherein the lubricant is a synthetic oil or mixture of synthetic oils.

Claim 24

The composition of claim 19 wherein the lubricant is a grease.

Claim 25

The composition of claim 10 additionally containing one or more of a member selected from the group consisting of a polymeric dispersant, metallic phenate, a metallic sulfonate, a zinc dithiophosphate and a polymeric viscosity index improver.