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US4555561A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyurethane resin composition

Assignee: Sunstar Suisse SA
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Filing: 1984-08-24
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Granted: 1985-11-26
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Expires: 2004-08-24
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Abstract

Abstract A polyurethane resin composition, which comprises (A) a urethane prepolymer composition containing 0.5 to 15.0% by weight of an active isocyanate group which is prepared by reacting a polyoxyalkylene ether polyol and/or polyester polyol and an excess amount of a polyisocaylante compound, and (B) as an adhesion-promoting agent 0.05 to 5.0% by weight of a reaction product of an amine compound containing at least one alkoxysilyl group of the formula: <IMAGE> wherein R1 and R2 are the same or different and are each a alkyl having 1 to 4 carbon atoms, and n is 0, 1 or 2, and an excess amount of a carbonyl compound. Said polyurethane resin composition has excellent adhesion properties and can show also excellent adhesiveness to metals which are hardly adhered with the conventional compositions and is useful as an adhesive, sealant and coating agent in various technical fields.

Inventors

  • 👤 Masaru Sugimori
  • 👤 Koichiro Sanji

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:31
CPC Classifications
C; C09; C09J; C09J175/00; C09J175/04; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 225 words
A polyurethane resin composition comprising (A) a urethane prepolymer composition containing 0.5 to 15.0% by weight based on said prepolymer composition of an active isocyanate group, said prepolymer composition prepared by reacting (1) a polyoxyalkylene ether polyol and/or polyester polyol and (2) a stoichiometric excess of a polyisocyanate compound and (B) 0.05 to 5.0% by weight based on the polyurethane resin composition of a reaction product of (1) an amine compound having a primary and/or secondary amino group and containing at least one alkoxysilyl group of the formula: ##STR5## wherein R 1 and R 2 are the same or different and are each alkyl having 1 to 4 carbon atoms and n is 0, 1 or 2, and (2) a stoichiometrically equivalent or excess amount of a carbonyl compound selected from the group consisting of an aldehyde, a cyclic ketone, an aliphatic ketone, and a β-dicarbonyl compound of the formula: R.sup.4 --CO--CH.sub.2 --CO--R.sup.5 wherein R 4 and R 5 are the same or different and each are an alkyl having 1 to 16 carbon atoms, an aryl having 6 to 12 carbon atoms, or an alkoxy having 1 to 4 carbon atoms, said reaction product containing enamine or ketimine groups formed by a dehydration condensation reaction of the carbonyl group of said carbonyl compound with the primary and/or secondary amino group of said amine compound.
Claim 2
Dependent Claim 225 words
A polyurethane resin composition comprising (A) a urethane prepolymer composition containing 0.5 to 15.0% by weight based on said prepolymer composition of an active isocyanate group, said prepolymer composition prepared by reacting (1) a polyoxyalkylene ether polyol and/or polyester polyol and (2) a stoichiometric excess of a polyisocyanate compound and (B) 0.05 to 5.0% by weight based on the polyurethane resin composition of a reaction product of (1) an amine compound having a primary and/or secondary amino group and containing at least one alkoxysilyl group of the formula: ##STR5## wherein R 1 and R 2 are the same or different and are each alkyl having 1 to 4 carbon atoms and n is 0, 1 or 2, and (2) a stoichiometrically equivalent or excess amount of a carbonyl compound selected from the group consisting of an aldehyde, a cyclic ketone, an aliphatic ketone, and a β-dicarbonyl compound of the formula: R.sup.4 --CO--CH.sub.2 --CO--R.sup.5 wherein R 4 and R 5 are the same or different and each are an alkyl having 1 to 16 carbon atoms, an aryl having 6 to 12 carbon atoms, or an alkoxy having 1 to 4 carbon atoms, said reaction product containing enamine or ketimine groups formed by a dehydration condensation reaction of the carbonyl group of said carbonyl compound with the primary and/or secondary amino group of said amine compound.
Claim 3
Dependent Claim 76 words
The composition according to claim 1, wherein the amine compound containing an alkoxysilyl group is a compound of the formula: ##STR6## wherein R 1 and R 2 are the same or different and are each a alkyl having 1 to 4 carbon atoms, R 3 is a divalent hydrocarbon group having 1 to 4 carbon atoms, Z is hydrogen atom, or an aminoalkyl having 1 to 4 carbon atoms, and m is 0, 1 or 2.
Claim 4
Dependent Claim 117 words
The composition according to claim 1, wherein the amine compound containing an alkoxysilyl group is a compound prepared by reacting an aminoalkylalkoxysilane of the formula: ##STR7## wherein R 1 and R 2 are the same or different and are each a alkyl having 1 to 4 carbon atoms, R 3 is a divalent hydrocarbon group having 1 to 4 carbon atoms, Z is hydrogen atom, or an aminoalkyl having 1 to 4 carbon atoms, and m is 0, 1 or 2, and less than equimolar amount of an epoxyalkylalkoxysilane compound of the formula: ##STR8## wherein R 1 , R 2 , R 3 and m are as defined above, and G is a glycidoxy or epoxycyclohexyl group.
Claim 5
Dependent Claim 60 words
The composition according to claim 1, wherein the carbonyl compound is a β-dicarbonyl compound of the formula: R.sup.4 --CO--CH.sub.2 --CO--R.sup.5 (III) wherein R 4 and R 5 are the same or different and are each an alkyl having 1 to 16 carbon atoms, an aryl having 6 to 12 carbon atoms, or an alkoxy having 1 to 4 carbon atoms.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-25 1989-05-27 1989-11-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-25 1993-05-27 1993-11-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-25 1997-05-27 1997-11-26 $7700.00 Window Closed / Lapsed

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