Heat-curable compositions comprising an epoxy resin, an amine and a sulfonium salt

Claim 2

A curable composition consisting essentially of (a) a polyepoxide, (b) at least one aromatic or aliphatic amine present in an amount effective to cure the polyepoxide under curing conditions, and (c) a catalytic amount of a trihydrocarbyl sulfonium salt comprising substituted or unsubstituted alkyl or aryl radicals.

Claim 3

The composition of claim 1 wherein the polyepoxide is a glycidyl polyether of a polyhydric phenol.

Claim 4

The composition of claim 2 wherein the polyhydric phenol is 2,2bis(4-hydroxyphenyl)propane.

Claim 5

The composition of claim 1 wherein the trihydrocarbyl sulfonium salt is a trialkyl sulfonium salt.

Claim 6

The composition of claim 4 wherein the trialkyl sulfonium salt is used in an amount from about 0.001% to about 10% by weight of the polyepoxide.

Claim 7

The composition of claim 1 wherein the trihydrocarbyl sulfonium salt is a mixture prepared by the condensation of 2,2'-thiodiethanol with tetrafluoroboric acid.

Claim 8

The composition of claim 1 wherein the trihydrocarbyl sulfonium salt is ethyl(2-hydroxyethyl)(2-(ethylthio)ethyl)sulfonium tetrafluoroborate.

Claim 9

The composition of claim 1 wherein the aromatic amine is 4,4'-methylenedianiline.

Claim 10

A composition consisting essentially of: (a) a polyepoxide, (b) an aromatic or aliphatic amine present in an amount of from about 0.5 to about 2.0 chemical equivalents based on the polyepoxide, and (c) a trihydrocarbyl sulfonium salt comprising substituted or unsubstituted alkyl or aryl radicals and present in an amount of about 0.001 to about 10 weight percent based on the weight of the polyepoxide.

Claim 11

A composition consisting essentially of: (a) a polyepoxide, (b) an aromatic or aliphatic amine present in an amount of from about 0.5 to about 2.0 chemical equivalents based on the polyepoxide, and (c) a trihydrocarbyl sulfonium salt comprising substituted or unsubstituted alkyl or aryl radicals and present in an amount of about 0.001 to about 10 weight percent based on the weight of the polyepoxide.

Claim 12

The composition of claim 9 wherein the amine is present in an amount of from about 0.5 to about 1.5 chemical equivalents based on the polyepoxide.

Claim 13

The composition of claim 9 wherein the amine is selected from the group consisting of methylenedianiline, metaphenylenediamine, 2,4-bis[p-aminobenzyl]aniline, diaminodiphenyl sulfone, 2,4-toluenediamine, 1,3-diamino-2,4-diethyl-6-methylbenzene, 4,4'-oxydianiline, methylenebis(ortho-chloroaniline), 2,6-diaminopyridine, 4-bromo-1,3-diaminobenzene, bis(4-aminocyclohexyl)methane, 1,8-diamino-p-menthane, 1,2-diaminocyclohexane and mixtures of these.

Claim 14

The composition of claim 9 in which the amine is present in an amount of from about 0.75 to about 1.25 equivalents of amine per equivalent of polyepoxy.

Claim 15

The composition of claim 9 which further contains at least one additive selected from the group consisting of a filler, reinforcement fibers, a pigment, a flame retardant, a plasticizer, a stabilizer, an extender, a thixotropic agent and an antioxidant.

Claim 16

The composition of claim 9 which further contains reinforcement fibers.

Claim 19

The method of claim 15 in which the amine curing agent is selected from the group consisting of methylenedianiline, metaphenylenediamine, 2,4-bis[p-aminobenzyl]aniline, diaminodiphenyl sulfone, 2,4-toluenediamine, 1,3-diamino-2,4-diethyl-6-methylbenzene, 4,4'-oxydianiline, methylenebis(ortho-chloroaniline), 2,6-diaminopyridine, 4-bromo-1,3-diaminobenzene, bis(4-aminocyclohexyl)methane, 1,8-diamino-p-menthane, 1,2-diaminocyclohexane and mixtures of these.

Claim 20

The method of claim 15 in which the trihydrocarbyl sulfonium salt is a mixture prepared by the condensation of 2,2-thiodiethanol with tetrafluoroboric acid.

Claim 21

The method of claim 16 in which the composition further contains reinforcement fibers.

Claim 22

The method of claim 16 in which the trihydrocarbyl sulfonium salt can be represented by the formula ##STR4## wherein R 1 , R 2 and R 3 are selected independently from substituted or unsubstituted alkyl and aryl radicals having 1 to about 18 carbon atoms and X is selected from the group consisting of BF 4 , PF 6 , AsF 6 , CF 3 SO 3 , FSO 3 , CH 3 SO 3 , 2,4,6-trinitrobenzenesulfonate and p-toluenesulfonate.