US4259454A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Curable organic resin compositions and foaming method
Assignee: General Electric Co
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Filing: 1980-06-09
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Granted: 1981-03-31
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Expires: 2000-06-09
Abstract
Abstract Curable organic resin compositions, such as epoxy resins, are provided, based on the use of dialkyl hydroxy arylsulfonium salts in combination with certain orgainc oxidants such as iodosoaromatic esters, or the use of certain amines or transition metals in combination with organic peroxides. The curable compositions can provide flexible or rigid organic resin foam when used with a volatile organic solvent as a result of exothermic heat of cure.
Inventors
- 👤 James V. Crivello
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:07
CPC Classifications
C; C08; C08G; C08G85/00; C08G59/00; C08G59/18; C08G59/68; C08G59/687; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C08G77/00; C08G77/04; C08G77/06; C08G77/08; C08J; C08J9/00; C08J9/04; C08J9/12; C08J9/14; C08J9/142; C08L; C08L61/00
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
192 words
A foaming method which comprises, (1) agitating an exothermically curable composition comprising (C) cationically polymerizable organic material (D) an effective amount of a curing agent consisting essentially of a dialkylhydroxyarylsulfonium salt of the formula, R(R.sup.1).sub.a S].sup.+ [Y].sup.-, and an organic oxidant selected from an iodosoaromatic compound, a hydroquinone, and an organic peroxide having a decomposition accelerator selected from an organic amine and compound of a transition metal, and (E) 1% to 30% by weight of (C), (D) and (E) of a volatile inert organic solvent, and (2) thereafter allowing the ingredients of the resulting mixtures to react resulting in the production of exothermic heat and the simultaneous evaporation of the organic solvent and the cure of the cationically polymerizable organic resin, where R is a C.sub.(6-20) aromatic radical having from 1 to 3 nuclearly bonded hydroxy radicals, R 1 can be the same or different C.sub.(1-8) alkyl radical or an alkylene radical capable of forming a cycloaliphatic or heterocyclic ring, Y is a nonnucleophilic anion, a is an integer equal to 0 or 2, and when R 1 is alkyl, a is 2, and when R 1 is alkylene, a is 1.
Claim 2
Dependent Claim
192 words
A foaming method which comprises, (1) agitating an exothermically curable composition comprising (C) cationically polymerizable organic material (D) an effective amount of a curing agent consisting essentially of a dialkylhydroxyarylsulfonium salt of the formula, R(R.sup.1).sub.a S].sup.+ [Y].sup.-, and an organic oxidant selected from an iodosoaromatic compound, a hydroquinone, and an organic peroxide having a decomposition accelerator selected from an organic amine and compound of a transition metal, and (E) 1% to 30% by weight of (C), (D) and (E) of a volatile inert organic solvent, and (2) thereafter allowing the ingredients of the resulting mixtures to react resulting in the production of exothermic heat and the simultaneous evaporation of the organic solvent and the cure of the cationically polymerizable organic resin, where R is a C.sub.(6-20) aromatic radical having from 1 to 3 nuclearly bonded hydroxy radicals, R 1 can be the same or different C.sub.(1-8) alkyl radical or an alkylene radical capable of forming a cycloaliphatic or heterocyclic ring, Y is a nonnucleophilic anion, a is an integer equal to 0 or 2, and when R 1 is alkyl, a is 2, and when R 1 is alkylene, a is 1.
Claim 3
Dependent Claim
14 words
A method in accordance with claim 1, where the volatile organic solvent is acetone.
Claim 4
Dependent Claim
17 words
A method in accordance with claim 1, where the cationically polymerizable organic material is an epoxy resin.
Claim 5
Dependent Claim
15 words
A method in accordance with claim 1, where the iodoso aromatic compound is iodosobenzene diacetate.
References Cited (Backward Citations)
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