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US4259454A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable organic resin compositions and foaming method

Assignee: General Electric Co
•
Filing: 1980-06-09
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Granted: 1981-03-31
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Expires: 2000-06-09
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Abstract

Abstract Curable organic resin compositions, such as epoxy resins, are provided, based on the use of dialkyl hydroxy arylsulfonium salts in combination with certain orgainc oxidants such as iodosoaromatic esters, or the use of certain amines or transition metals in combination with organic peroxides. The curable compositions can provide flexible or rigid organic resin foam when used with a volatile organic solvent as a result of exothermic heat of cure.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 20:07
CPC Classifications
C; C08; C08G; C08G85/00; C08G59/00; C08G59/18; C08G59/68; C08G59/687; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C08G77/00; C08G77/04; C08G77/06; C08G77/08; C08J; C08J9/00; C08J9/04; C08J9/12; C08J9/14; C08J9/142; C08L; C08L61/00

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 192 words
A foaming method which comprises, (1) agitating an exothermically curable composition comprising (C) cationically polymerizable organic material (D) an effective amount of a curing agent consisting essentially of a dialkylhydroxyarylsulfonium salt of the formula, R(R.sup.1).sub.a S].sup.+ [Y].sup.-, and an organic oxidant selected from an iodosoaromatic compound, a hydroquinone, and an organic peroxide having a decomposition accelerator selected from an organic amine and compound of a transition metal, and (E) 1% to 30% by weight of (C), (D) and (E) of a volatile inert organic solvent, and (2) thereafter allowing the ingredients of the resulting mixtures to react resulting in the production of exothermic heat and the simultaneous evaporation of the organic solvent and the cure of the cationically polymerizable organic resin, where R is a C.sub.(6-20) aromatic radical having from 1 to 3 nuclearly bonded hydroxy radicals, R 1 can be the same or different C.sub.(1-8) alkyl radical or an alkylene radical capable of forming a cycloaliphatic or heterocyclic ring, Y is a nonnucleophilic anion, a is an integer equal to 0 or 2, and when R 1 is alkyl, a is 2, and when R 1 is alkylene, a is 1.
Claim 2
Dependent Claim 192 words
A foaming method which comprises, (1) agitating an exothermically curable composition comprising (C) cationically polymerizable organic material (D) an effective amount of a curing agent consisting essentially of a dialkylhydroxyarylsulfonium salt of the formula, R(R.sup.1).sub.a S].sup.+ [Y].sup.-, and an organic oxidant selected from an iodosoaromatic compound, a hydroquinone, and an organic peroxide having a decomposition accelerator selected from an organic amine and compound of a transition metal, and (E) 1% to 30% by weight of (C), (D) and (E) of a volatile inert organic solvent, and (2) thereafter allowing the ingredients of the resulting mixtures to react resulting in the production of exothermic heat and the simultaneous evaporation of the organic solvent and the cure of the cationically polymerizable organic resin, where R is a C.sub.(6-20) aromatic radical having from 1 to 3 nuclearly bonded hydroxy radicals, R 1 can be the same or different C.sub.(1-8) alkyl radical or an alkylene radical capable of forming a cycloaliphatic or heterocyclic ring, Y is a nonnucleophilic anion, a is an integer equal to 0 or 2, and when R 1 is alkyl, a is 2, and when R 1 is alkylene, a is 1.
Claim 3
Dependent Claim 14 words
A method in accordance with claim 1, where the volatile organic solvent is acetone.
Claim 4
Dependent Claim 17 words
A method in accordance with claim 1, where the cationically polymerizable organic material is an epoxy resin.
Claim 5
Dependent Claim 15 words
A method in accordance with claim 1, where the iodoso aromatic compound is iodosobenzene diacetate.

References Cited (Backward Citations)

US3412046A Cited
US4058400A Cited
US4058401A Cited
US4069054A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-30 1984-09-29 1985-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-30 1988-09-29 1989-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-30 1992-09-29 1993-03-31 $7700.00 Window Closed / Lapsed

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