Patent US4550982A successfully refreshed from Google Patents.
US4550982A
Expired / Lapsed
US
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All-solid-state display including an organic electrochromic layer with ion donor/acceptor
Assignee: NEC Corp
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Filing: 1982-11-09
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Granted: 1985-11-05
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Expires: 2002-11-09
Abstract
Abstract Between a display electrode and a counter electrode, an all-solid-state organic electrochromic display device comprises a polymer layer comprising at least one organic electrochromic material and at lest one ionic material. The layer may be a polymer film of at least one polymer material in which film the electrochromic and the ionic materials are dispersed, a polymer electrochromic film comprising the electrochromic material in which film the ionic material is dispersed, a polymer ionic film comprising the ionic material in which film the electrochromic material is dispersed, or a polymer electrochromic and ionic film comprising the electrochromic and the ionic materials. Between the electrochromic layer and the counter electrode, the device may comprise a polymer redox layer which is similar in structure to the electrochromic layer and preferably comprises at least one ionic material. Between the electrochromic layer and either one of the display and the counter electrodes or the redox layer, the device may comprise a solid electrolyte layer which may either be a polymer ionic layer or an inorganic solid electrolyte layer. Preferably, the electrochromic, the redox, and/or the polymer ionic layer include conductive powder, at least one plasticizer, and/or reflective powder and, more preferably, are cross-linked. A conductive and/or reflective powder may be included in the inorganic solid electrolyte layer.
Inventors
- 👤 Yoshihiko Hirai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 19:40
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1514; G02F1/1516; G02F1/15165
Claims Analysis
Total Claims: 81
Claim 1
Independent Claim
48 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and an electrochromic layer between said transparent and said counter electrodes, wherein said electrochromic layer consists essentially of a polymer electrochromic film comprising at least one organic electrochromic material and at least one ionic material.
Claim 2
Dependent Claim
48 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and an electrochromic layer between said transparent and said counter electrodes, wherein said electrochromic layer consists essentially of a polymer electrochromic film comprising at least one organic electrochromic material and at least one ionic material.
Claim 3
Dependent Claim
57 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of macromolecules of at least one polymer material, with at least one organic electrochromic material and at least one ionic material dispersed in said film.
Claim 4
Dependent Claim
57 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of macromolecules of at least one polymer material, with at least one organic electrochromic material and at least one ionic material dispersed in said film.
Claim 5
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in claim 2, said polymer electrochromic film having a first and a second surface, wherein said transparent and said counter electrodes are in direct contact with said first and said second surfaces, respectively.
Claim 6
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 2, further comprising a solid electrolyte layer between said polymer electrochromic film and said transparent electrode.
Claim 7
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 2, further comprising a solid electrolyte layer between said polymer electrochromic film and said counter electrode.
Claim 8
Dependent Claim
23 words
An all-solid-state electrochromic display device as claimed in claim 5, further comprising a redox layer between said electrolyte layer and said counter electrode.
Claim 9
Dependent Claim
27 words
An all-solid-state electrochromic display device as claimed in claim 6, wherein said redox layer consists essentially of a polymer redox film comprising at least one redox material.
Claim 10
Dependent Claim
38 words
An all-solid-state electrochromic display device as claimed in claim 7, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material being dispersed in said polymer redox film.
Claim 11
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in claim 7, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material.
Claim 12
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in claim 7, wherein said polymer redox film further comprises at least one ionic material.
Claim 13
Dependent Claim
45 words
An all-solid-state electrochromic display device as claimed in claim 10, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material and said at least one ionic material being dispersed in said polymer redox film.
Claim 14
Dependent Claim
42 words
An all-solid-state electrochromic display device as claimed in claim 10, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material, said at least one ionic material being dispersed in said polymer redox film.
Claim 15
Dependent Claim
49 words
An all-solid-state electrochromic display device as claimed in claim 10, wherein said polymer redox film consists essentially of a polymer redox material and a polymer ionic material, said polymer redox material comprising said at least one redox material, said polymer ionic material comprising said at least one ionic material.
Claim 16
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in any one of claims 7 through 13, wherein said polymer redox film is cross-linked.
Claim 17
Dependent Claim
36 words
An all-solid-state electrochromic display device as claimed in claim 14, wherein said cross-linked polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 18
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in any one of claims 7 through 13, wherein said polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 19
Dependent Claim
43 words
An all-solid-state electrochromic display device as claimed in any one of claims 4 through 13, wherein said electrolyte layer is a dispersed film consisting essentially of macromolecules of at least one polymer material with at least one ionic material dispersed in said film.
Claim 20
Dependent Claim
30 words
An all-solid-state electrochromic display device as claimed in any one of claims 4 through 13, wherein said electrolyte layer is a polyelectrolyte film consisting essentially of a polymer ionic material.
Claim 21
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in any one of claims 4 through 13, wherein said electrolyte layer consists essentially of at least one inorganic solid electrolyte material.
Claim 22
Dependent Claim
56 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer electrochromic material comprising at least one organic electrochromic material, with at least one ionic material dispersed in said polymer electrochromic film.
Claim 23
Dependent Claim
56 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer electrochromic material comprising at least one organic electrochromic material, with at least one ionic material dispersed in said polymer electrochromic film.
Claim 24
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in claim 20, said polymer electrochromic film having a first and a second surface, wherein said transparent and said counter electrodes are in direct contact with said first and said second surfaces, respectively.
Claim 25
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 20, further comprising a solid electrolyte layer between said polymer electrochromic film and said transparent electrode.
Claim 26
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 20, further comprising a solid electrolyte layer between said polymer electrochromic film and said counter electrode.
Claim 27
Dependent Claim
23 words
An all-solid-state electrochromic display device as claimed in claim 23, further comprising a redox layer between said electrolyte layer and said counter electrode.
Claim 28
Dependent Claim
27 words
An all-solid-state electrochromic display device as claimed in claim 24, wherein said redox layer consists essentially of a polymer redox film comprising at least one redox material.
Claim 29
Dependent Claim
38 words
An all-solid-state electrochromic display device as claimed in claim 25, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material being dispersed in said polymer redox film.
Claim 30
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in claim 25, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one ionic material.
Claim 31
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in claim 25, wherein said polymer redox film further comprises at least one ionic material.
Claim 32
Dependent Claim
44 words
An all-solid-state electrochromic display device as claimed in claim 28, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material and said at least one ionic material dispersed in said polymer redox film.
Claim 33
Dependent Claim
43 words
An all-solid-state electrochromic display device as claimed in claim 28, wherein said polymer redox film consists essentially of a high polymer redox material comprising said at least one redox material, said at least one ionic material being dispersed in said polymer redox film.
Claim 34
Dependent Claim
49 words
An all-solid-state electrochromic display device as claimed in claim 28, wherein said polymer redox film consists essentially of a polymer redox material and a polymer ionic material, said polymer redox material comprising said at least one redox material, said polymer ionic material comprising said at least one ionic material.
Claim 35
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in any one of claims 25 through 31, wherein said polymer redox film is cross-linked.
Claim 36
Dependent Claim
36 words
An all-solid-state electrochromic display device as claimed in claim 32, wherein said cross-linked polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 37
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in any one of claims 25 through 31, wherein said polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 38
Dependent Claim
43 words
An all-solid-state electrochromic display device as claimed in any one of claims 22 through 31, wherein said electrolyte layer is a dispersed film consisting essentially of macromolecules of at least one polymer material with at least one ionic material dispersed in said film.
Claim 39
Dependent Claim
30 words
An all-solid-state electrochromic display device as claimed in any one of claims 22 through 31, wherein said electrolyte layer is a polyelectrolyte film consisting essentially of a polymer ionic material.
Claim 40
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in any one of claims 27 through 31, wherein said electrolyte layer consists essentially of at least one inorganic solid electrolyte material.
Claim 41
Dependent Claim
56 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer ionic material comprising at least one ionic material, with at least one organic electrochromic material dispersed in said polymer electrochromic film.
Claim 42
Dependent Claim
56 words
An all-solid-state electrochromic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer ionic material comprising at least one ionic material, with at least one organic electrochromic material dispersed in said polymer electrochromic film.
Claim 43
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in claim 38, said polymer electrochromic film having a first and a second surface, wherein said transparent and said counter electrodes are in direct contact with said first and said second surfaces, respectively.
Claim 44
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 38, further comprising a solid electrolyte layer between said polymer electrochromic film and said transparent electrode.
Claim 45
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 38, further comprising a solid electrolyte layer between said polymer electrochromic film and said counter electrode.
Claim 46
Dependent Claim
23 words
An all-solid-state electrochromic display device as claimed in claim 41, further comprising a redox layer between said electrolyte layer and said counter electrode.
Claim 47
Dependent Claim
27 words
An all-solid-state electrochromic display device as claimed in claim 42, wherein said redox layer consists essentially of a polymer redox film comprising at least one redox material.
Claim 48
Dependent Claim
38 words
An all-solid-state electrochromic display device as claimed in claim 43, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material being dispersed in said polymer redox film.
Claim 49
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in claim 43, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material.
Claim 50
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in claim 43, wherein said polymer redox film further comprises at least one ionic material.
Claim 51
Dependent Claim
45 words
An all-solid-state electrochromic display device as claimed in claim 46, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material and said at least one ionic material being dispersed in said polymer redox film.
Claim 52
Dependent Claim
42 words
An all-solid-state electrochromic display device as claimed in claim 46, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material, said at least one ionic material being dispersed in said polymer redox film.
Claim 53
Dependent Claim
50 words
An all-solid-state electrochromic display device as claimed in claim 46, wherein said polymer redox film consists essentially of a high polymer redox material and a polymer ionic material, said polymer redox material comprising said at least one redox material, said polymer ionic material comprising said at least one ionic material.
Claim 54
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in any one of claims 43 through 49, wherein said polymer redox film is cross-linked.
Claim 55
Dependent Claim
36 words
An all-solid-state electrochromic display device as claimed in claim 50, wherein said cross-linked polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 56
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in any one of claims 43 through 49, wherein said polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 57
Dependent Claim
43 words
An all-solid-state electrochromic display device as claimed in any one of claims 40 through 49, wherein said electrolyte layer is a dispersed film consisting essentially of macromolecules of at least one polymer material with at least one ionic material dispersed in said film.
Claim 58
Dependent Claim
30 words
An all-solid-state electrochromic display device as claimed in any one of claims 40 through 49, wherein said electrolyte layer is a polyelectrolyte film consisting essentially of a polymer ionic material.
Claim 59
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in any one of claims 40 through 49, wherein said electrolyte layer consists essentially of at least one inorganic solid electrolyte material.
Claim 60
Dependent Claim
56 words
An all-solid-state electrochrmic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer electrochromic material and a polymer ionic material, said polymer electrochromic material, said polymer ionic material comprising at least one ionic material.
Claim 61
Dependent Claim
56 words
An all-solid-state electrochrmic display device comprising a substantially transparent electrode, a counter electrode, and a polymer electrochromic film between said transparent and said counter electrodes, wherein said polymer electrochromic film consists essentially of a polymer electrochromic material and a polymer ionic material, said polymer electrochromic material, said polymer ionic material comprising at least one ionic material.
Claim 62
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in claim 56, said polymer electrochromic film having a first and a second surface, wherein said transparent and said counter electrodes are in direct contact with said first and said second surfaces, respectively.
Claim 63
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 56, further comprising a solid electrolyte layer between said polymer electrochromic film and said transparent electrode.
Claim 64
Dependent Claim
25 words
An all-solid-state electrochromic display device as claimed in claim 56, further comprising a solid electrolyte layer between said polymer electrochromic film and said counter electrode.
Claim 65
Dependent Claim
23 words
An all-solid-state electrochromic display device as claimed in claim 59, further comprising a redox layer between said electrolyte layer and said counter electrode.
Claim 66
Dependent Claim
27 words
An all-solid-state electrochromic display device as claimed in claim 60, wherein said redox layer consists essentially of a polymer redox film comprising at least one redox material.
Claim 67
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in claim 61, wherein said polymer redox film consists essentially of macromolecules of at least one high polymer material, said at least one redox material being dispersed in said high polymer redox film.
Claim 68
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in claim 61, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material.
Claim 69
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in claim 61, wherein said polymer redox film further comprises at least one ionic material.
Claim 70
Dependent Claim
45 words
An all-solid-state electrochromic display device as claimed in claim 64, wherein said polymer redox film consists essentially of macromolecules of at least one polymer material, said at least one redox material and said at least one ionic material being dispersed in said polymer redox film.
Claim 71
Dependent Claim
42 words
An all-solid-state electrochromic display device as claimed in claim 64, wherein said polymer redox film consists essentially of a polymer redox material comprising said at least one redox material, said at least one ionic material being dispersed in said polymer redox film.
Claim 72
Dependent Claim
50 words
An all-solid-state electrochromic display device as claimed in claim 64, wherein said polymer redox film consists essentially of a high polymer redox material and a polymer ionic material, said polymer redox material comprising said at least one redox material, said polymer ionic material comprising said at least one ionic material.
Claim 73
Dependent Claim
22 words
An all-solid-state electrochromic display device as claimed in any one of claims 61 through 67, wherein said polymer redox film is cross-linked.
Claim 74
Dependent Claim
36 words
An all-solid-state electrochromic display device as claimed in claim 68, wherein said cross-linked polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 75
Dependent Claim
40 words
An all-solid-state electrochromic display device as claimed in any one of claims 61 through 67, wherein said polymer redox film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 76
Dependent Claim
43 words
An all-solid-state electrochromic display device as claimed in any one of claims 58 through 67, wherein said electrolyte layer is a dispersed film consisting essentially of macromolecules of at least one polymer material with at least one ionic material dispersed in said film.
Claim 77
Dependent Claim
30 words
An all-solid-state electrochromic display device as claimed in any one of claims 58 through 67, wherein said electrolyte layer is a polyelectrolyte film consisting essentially of a polymer ionic material.
Claim 78
Dependent Claim
29 words
An all-solid-state electrochromic display device as claimed in any one of claims 58 through 67, wherein said electolyte layer consists essentially of at least one inorganic solid electrolyte material.
Claim 79
Dependent Claim
48 words
An all-solid-state electrochromic display device as claimed in any one of claims 2 through 13, any one of claims 20 through 31, any one of claims 38 through 49, or any one of claims 56 through 67, wherein said polymer electrochromic film is a cross-linked polymer electrochromic film.
Claim 80
Dependent Claim
36 words
An all-solid-state electrochromic display device as claimed in claim 74, wherein said cross-linked polymer electrochromic film comprises at least one additive selected from a group consisting of conductive powder, at least one plasticizer, and reflective powder.
Claim 81
Dependent Claim
62 words
An all-solid-state electrochromic display device as claimed in any one of claims 2 through 13, any one of claims 20 through 31, any one of claims 38 through 49, or any one of claims 56 through 67, wherein said polymer electrochromic film comprises at least one additive selected from the group consisting of conductive powder, at least one plasticizer, and reflective powder.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-04 | 1989-05-06 | 1989-11-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-04 | 1993-05-06 | 1993-11-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-04 | 1997-05-06 | 1997-11-05 | $7700.00 | Window Closed / Lapsed |