Patent US3544915A successfully refreshed from Google Patents.
Patent US4549134A successfully refreshed from Google Patents.
US4549134A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Moisture probe and technique
Assignee: Dow Chemical Co
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Filing: 1984-09-07
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Granted: 1985-10-22
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Expires: 2004-09-07
Abstract
Abstract A superior moisture probe and technique for assaying liquid and gas streams for moisture concentration in the parts per million (ppm) range, comprises an emf source connected across a pair of adjacent conductive probes separated by a sulfonated aliphatic fluorocarbon membrane, the combination being immersed in the fluid of interest, or in a sealed headspace associated therewith, the former being the preferred mode. With a D.C. emf, the resistance change of the probe, or a value proportional therewith is monitored, and from that value H 2 O concentration is deduced. With an A.C. emf, capacitance, A.C. resistance, and/or impedance of the described probe structure varies proportionately with the concentration of H 2 O in the membrane, and is monitored directly or indirectly to deduce H 2 O concentration. In the latter form of the invention, the conductive components of the probe are desirably clad by a corrosion resistant, impermeable polymeric coating, and in such form, the use of expensive noble metal components for the probe is less critical, and substitution with less expensive conductive materials is thus practical for certain applications.
Inventors
- 👤 Thomas M. Weiss
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 10:50
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/22; G01N27/223
Claims Analysis
Total Claims: 35
Claim 1
Independent Claim
155 words
Apparatus for sensitivity detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: a capacitance element comprising a pair of capacitor plates between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the capacitance element having the property to produce detectable capacitance change with changes in water concentration in air at least over the range of about 24,000 ppm to about 44 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first capacitor plate through the membrane to the second capacitor plate and thereby causing a change in the capacitance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting capacitance change of the capacitance element for purposes of determining the concentration of water in the fluid of interest.
Claim 2
Dependent Claim
155 words
Apparatus for sensitivity detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: a capacitance element comprising a pair of capacitor plates between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the capacitance element having the property to produce detectable capacitance change with changes in water concentration in air at least over the range of about 24,000 ppm to about 44 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first capacitor plate through the membrane to the second capacitor plate and thereby causing a change in the capacitance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting capacitance change of the capacitance element for purposes of determining the concentration of water in the fluid of interest.
Claim 3
Dependent Claim
152 words
Apparatus for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: a resistance element comprising a pair of terminals between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the resistance element having the property to produce detectable resistance change with changes in water concentration in air at least over the range of about 25,000 ppm to about 14 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first terminal through the membrane to the second terminal and thereby causing a change in the resistance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting resistance change of the resistance element for purposes of determining the concentration of water in the fluid of interest.
Claim 4
Dependent Claim
152 words
Apparatus for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: a resistance element comprising a pair of terminals between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the resistance element having the property to produce detectable resistance change with changes in water concentration in air at least over the range of about 25,000 ppm to about 14 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first terminal through the membrane to the second terminal and thereby causing a change in the resistance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting resistance change of the resistance element for purposes of determining the concentration of water in the fluid of interest.
Claim 5
Dependent Claim
12 words
The apparatus of claim 2, wherein the voltage is a D.C. voltage.
Claim 6
Dependent Claim
152 words
Apparatus for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: an impedance element comprising a pair of terminals between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the impedance element having the property to produce detectable impedance change with changes in water concentration in air at least over the range of about 23,000 ppm to about 15 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first terminal through the membrane to the second terminal and thereby causing a change in the impedance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting impedance change of the impedance element for purposes of determining the concentration of water in the fluid of interest.
Claim 7
Dependent Claim
152 words
Apparatus for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising in combination: an impedance element comprising a pair of terminals between which there is disposed a membrane; said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the impedance element having the property to produce detectable impedance change with changes in water concentration in air at least over the range of about 23,000 ppm to about 15 ppm; means for impressing a voltage below the voltage level required for electrolysis from the first terminal through the membrane to the second terminal and thereby causing a change in the impedance of the membrane dependant upon the water concentration in the fluid of interest; and means for detecting impedance change of the impedance element for purposes of determining the concentration of water in the fluid of interest.
Claim 8
Dependent Claim
13 words
The apparatus of claim 1, whereby the plates have non-metallic, corrosion resistant cladding.
Claim 9
Dependent Claim
13 words
The apparatus of claim 2, whereby the terminals have non-metallic, corrosion resistance cladding.
Claim 10
Dependent Claim
13 words
The apparatus of claim 4, whereby the terminals have non-metallic, corrosion resistant cladding.
Claim 11
Dependent Claim
18 words
The apparatus of claim 1, whereby the membrane has a thickness within the range of about 0.5-10 mils.
Claim 12
Dependent Claim
18 words
The apparatus of claim 2, whereby the membrane has a thickness within the range of about 0.5-10 mils.
Claim 13
Dependent Claim
18 words
The apparatus of claim 4, whereby the membrane has a thickness within the range of about 0.5-10 mils.
Claim 14
Dependent Claim
15 words
The apparatus of claim 1, whereby the membrane comprises a perfluorosulfonic acid substituted polytetrafluoroethylene material.
Claim 15
Dependent Claim
15 words
The apparatus of claim 2, whereby the membrane comprises a perfluorosulfonic acid substituted polytetrafluoroethylene material.
Claim 16
Dependent Claim
15 words
The apparatus of claim 4, whereby the membrane comprises a perfluorosulfonic acid substituted polytetrafluoroethylene material.
Claim 17
Independent Claim
156 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing a capacitance element comprising a pair of capacitor plates between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the capacitance element having the property to produce detectable capacitance change with respect to water concentration in air at least over the range of about 24,000 ppm to about 44 ppm; impressing a voltage below the voltage level required for electrolysis from the first capacitor plate to the second capacitor plate and thereby causing a change in the capacitance of the membrane dependent on the water concentration in the fluid of interest; and detecting capacitance change of the capacitance element for purposes of determining the concentration of water in the fluid of interest.
Claim 18
Independent Claim
156 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing a capacitance element comprising a pair of capacitor plates between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the capacitance element having the property to produce detectable capacitance change with respect to water concentration in air at least over the range of about 24,000 ppm to about 44 ppm; impressing a voltage below the voltage level required for electrolysis from the first capacitor plate to the second capacitor plate and thereby causing a change in the capacitance of the membrane dependent on the water concentration in the fluid of interest; and detecting capacitance change of the capacitance element for purposes of determining the concentration of water in the fluid of interest.
Claim 19
Independent Claim
157 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing a resistance element comprising a pair of terminals between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the resistance element having the property to produce detectable resistance change with respect to water concentration in air in the fluid of interest at least over the range of about 25,000 ppm to about 14 ppm; impressing a voltage below the level required for electrolysis from the first terminal to the second terminal and thereby causing a change in the resistance of the membrane dependent on the water concentration in the fluid of interest; and detecting resistance change of the resistance element for purposes of determining the concentration of water in the fluid of interest.
Claim 20
Independent Claim
157 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing a resistance element comprising a pair of terminals between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the resistance element having the property to produce detectable resistance change with respect to water concentration in air in the fluid of interest at least over the range of about 25,000 ppm to about 14 ppm; impressing a voltage below the level required for electrolysis from the first terminal to the second terminal and thereby causing a change in the resistance of the membrane dependent on the water concentration in the fluid of interest; and detecting resistance change of the resistance element for purposes of determining the concentration of water in the fluid of interest.
Claim 21
Independent Claim
152 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing an impedance element comprising a pair of terminals between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the impedance element having the property to produce detectable impedance change with respect to water concentration in air at least over the range of about 23,000 ppm to about 15 ppm; impressing a voltage below the level required for electrolysis from the first terminal to the second terminal and thereby causing a change in the impedance of the membrane dependent on the water concentration in the fluid of interest; and detecting impedance change in the impedance element for purposes of determining the concentration of water in the fluid of interest.
Claim 22
Independent Claim
152 words
A method for sensitively detecting, quantitatively, a range of concentrations, particularly trace concentrations of water in diverse fluids of interest, with utility for quantitating in the low ppm range, comprising the steps of: disposing an impedance element comprising a pair of terminals between which there is disposed a membrane in a fluid of interest, said membrane comprising a sulfonated aliphatic fluorocarbon polymer, the impedance element having the property to produce detectable impedance change with respect to water concentration in air at least over the range of about 23,000 ppm to about 15 ppm; impressing a voltage below the level required for electrolysis from the first terminal to the second terminal and thereby causing a change in the impedance of the membrane dependent on the water concentration in the fluid of interest; and detecting impedance change in the impedance element for purposes of determining the concentration of water in the fluid of interest.
Claim 23
Dependent Claim
16 words
The method of claim 16, wherein the voltage impressed on the membrane is a D.C. voltage.
Claim 24
Dependent Claim
18 words
The method of claim 14, further comprising the step of cladding the plates with a non-metallic, corrosion-resistant material.
Claim 25
Dependent Claim
18 words
The method of claim 15, further comprising the step of cladding the terminals with a non-metallic, corrosion-resistant material.
Claim 26
Dependent Claim
19 words
The method of claim 16, further comprising the step of cladding the terminals with a non-metallic, corrosion resistant material.
Claim 27
Dependent Claim
23 words
The method of claim 14, further comprising the step of using a membrane with a thickness in the range of about 0.5-10 mils.
Claim 28
Dependent Claim
23 words
The method of claim 15, further comprising the step of using a membrane with a thickness in the range of about 0.5-10 mils.
Claim 29
Dependent Claim
23 words
The method of claim 16, further comprising the step of using a membrane with a thickness in the range of about 0.5-10 mils.
Claim 30
Dependent Claim
19 words
The method of claim 14, further comprising the step of using a membrane comprising a perfluorosulfonic acid substituted polytetrafluoroethylene.
Claim 31
Dependent Claim
19 words
The method of claim 15, further comprising the step of using a membrane comprising a perfluorosulfonic acid substituted polytetrafluoroethylene.
Claim 32
Dependent Claim
19 words
The method of claim 16, further comprising the step of using a membrane comprising a perfluorosulfonic acid substituted polytetrafluoroethylene.
Claim 33
Dependent Claim
23 words
The method of claim 14, further comprising the step of disposing the membrane within a sealed headspace communicating with the fluid of interest.
Claim 34
Dependent Claim
23 words
The method of claim 15, further comprising the step of disposing the membrane within a sealed headspace communicating with the fluid of interest.
Claim 35
Dependent Claim
23 words
The method of claim 16, further comprising the step of disposing the membrane within a sealed headspace communicating with the fluid of interest.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-10-21 | 1989-04-22 | 1989-10-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-10-21 | 1993-04-22 | 1993-10-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-10-21 | 1997-04-22 | 1997-10-22 | $7700.00 | Window Closed / Lapsed |