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US4549004A
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Fluoroalkyloxyalkyl containing organopolysiloxanes
Assignee: Wacker Chemie AG
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Filing: 1984-10-02
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Granted: 1985-10-22
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Expires: 2004-10-02
Abstract
Abstract This invention relates to fluoroalkyloxyalkyl diorganopolysiloxanes having the general formula ##STR1## where R 1 represents fluoroalkyloxyalkyl groups of the general formula --(CH.sub.2).sub.a --O--C.sub.b F.sub.2b H in which the hydrogen atom is in the beta position to the ether oxygen, a is 2, 3 or 4; b is an integer having a value of from 1 to 6; R 2 represents an alkyl group having from 1 to 8 carbon atoms whose terminal units may also contain an amino or a thiol group, or an alkenyl group having 2 or 3 carbon atoms, or an aryl group having from 6 to 8 carbon atoms or hydrogen; R 3 represents the group having the formula --(CH.sub.2).sub.c --C.sub.d F.sub.(2d-e+1) Hal.sub.e, in which Hal represents a terminal chlorine, bromine or iodine atom, c is 2, 3 or 4; d is an integer having a value of from 1 to 18; e is 0 or 1; R 4 , R 5 and R 6 are the same as R 2 ; X and Y are the same or different and represent condensable terminal groups or trialkylsiloxy groups in which the alkyl groups have from 1 to 6 carbon atoms; m has a value of from 0.05 to 0.9; n has a value of from 0 to 0.6; and p has a value of from 0.1 to 0.8 with the proviso that the sum of m+n+p=1.
Inventors
- 👤 Gunter von Au
- 👤 Ernst Innertsberger
- 👤 Jakob Schmidlkofer
- 👤 Wolfgang Kaiser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:09
CPC Classifications
C; C10; C10M; C10M107/00; C10M107/50; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/24; C10M2207/00; C10M2207/10; C10M2207/12; C10M2207/125; C10M2207/129; C10M2229/00; C10M2229/04; C10M2229/05; C10M2229/051; C10M2229/052; C10M2229/053; C10N; C10N2010/00; C10N2010/02
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
252 words
A lubricant containing a diorganopolysiloxane of the formula ##STR3## where R 1 represents fluoroalkyloxyalkyl groups of the formula --(CH.sub.2).sub.a --O--C.sub.b F.sub.2b H in which the hydrogen atom is in the beta position relative to the ether oxygen: a is 2, 3 or 4; b is an integer of from 1 to 6; R 2 is selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; R 3 represents the group --(CH.sub.2).sub.c --C.sub.d F.sub.(2d-e+1) Hal.sub.e, where Hal represents a terminal halogen group selected from the class consisting of chlorine, bromine and iodine; c is 2, 3 or 4; d is an integer having a value of from 1 to 18; e is 0 or 1; R 4 , R 5 and R 6 are each selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; X and Y are each selected from the group consisting of condensable terminal groups and trialkylsiloxy groups in which the alkyl groups have from 1 to 6 carbon atoms; m has a value of from 0.05 to 0.9; n has a value of from 0 to 0.6; and p has a value of from 0.1 to 0.8; with the proviso that the sum of m+n+p =1.
Claim 2
Dependent Claim
252 words
A lubricant containing a diorganopolysiloxane of the formula ##STR3## where R 1 represents fluoroalkyloxyalkyl groups of the formula --(CH.sub.2).sub.a --O--C.sub.b F.sub.2b H in which the hydrogen atom is in the beta position relative to the ether oxygen: a is 2, 3 or 4; b is an integer of from 1 to 6; R 2 is selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; R 3 represents the group --(CH.sub.2).sub.c --C.sub.d F.sub.(2d-e+1) Hal.sub.e, where Hal represents a terminal halogen group selected from the class consisting of chlorine, bromine and iodine; c is 2, 3 or 4; d is an integer having a value of from 1 to 18; e is 0 or 1; R 4 , R 5 and R 6 are each selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; X and Y are each selected from the group consisting of condensable terminal groups and trialkylsiloxy groups in which the alkyl groups have from 1 to 6 carbon atoms; m has a value of from 0.05 to 0.9; n has a value of from 0 to 0.6; and p has a value of from 0.1 to 0.8; with the proviso that the sum of m+n+p =1.
Claim 3
Dependent Claim
37 words
The lubricant of claim 1, wherein R 2 is an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
Claim 4
Dependent Claim
46 words
The lubricant of claim 2, wherein R 4 , R 5 and R 6 are each selected from an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
Claim 5
Dependent Claim
51 words
The lubricant of claim 1, wherein R 2 is hydrogen and R 4 , R 5 and R 6 are each selected from an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
Claim 6
Dependent Claim
251 words
An antifoam containing a diorganopolysiloxane of the formula ##STR4## where R 1 represents fluoroalkyloxyalkyl groups of the formula --(CH.sub.2).sub.a --O--C.sub.d F.sub.2b H in which the hydrogen atom is in the beta position relative to the ether oxygen; a is 2, 3 or 4; b is an integer of from 1 to 6; R 2 is selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; R 3 represents the group --(CH.sub.2).sub.c --C.sub.d F.sub.(2d-e+1) Hal.sub.e, where Hal represents a terminal halogen group selected from the class consisting of chlorine, bromine and iodine; c is 2, 3 or 4; d is an integer having a value of from 1 to 18; e is 0 or 1; R 4 , R 5 and R 6 are each selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; X and Y are each selected from the group consisting of condensable terminal groups and trialkylsiloxy groups in which the alkyl groups have from 1 to 6 carbon atoms; m has a value of from 0.05 to 0.9, n has a value of from 0 to 0.6; and p has a value of from 0.1 to 0.8; with the proviso that the sum of m+n+p=1.
Claim 7
Dependent Claim
251 words
An antifoam containing a diorganopolysiloxane of the formula ##STR4## where R 1 represents fluoroalkyloxyalkyl groups of the formula --(CH.sub.2).sub.a --O--C.sub.d F.sub.2b H in which the hydrogen atom is in the beta position relative to the ether oxygen; a is 2, 3 or 4; b is an integer of from 1 to 6; R 2 is selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; R 3 represents the group --(CH.sub.2).sub.c --C.sub.d F.sub.(2d-e+1) Hal.sub.e, where Hal represents a terminal halogen group selected from the class consisting of chlorine, bromine and iodine; c is 2, 3 or 4; d is an integer having a value of from 1 to 18; e is 0 or 1; R 4 , R 5 and R 6 are each selected from the group consisting of an alkyl group having from 1 to 8 carbon atoms, an alkenyl group having 2 or 3 carbon atoms, an aryl group having 6 to 8 carbon atoms and hydrogen; X and Y are each selected from the group consisting of condensable terminal groups and trialkylsiloxy groups in which the alkyl groups have from 1 to 6 carbon atoms; m has a value of from 0.05 to 0.9, n has a value of from 0 to 0.6; and p has a value of from 0.1 to 0.8; with the proviso that the sum of m+n+p=1.
Claim 8
Dependent Claim
37 words
The antifoam of claim 5, wherein R 2 is an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
Claim 9
Dependent Claim
46 words
The antifoam of claim 6, wherein R 4 , R 5 and R 6 are each selected from an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
Claim 10
Dependent Claim
51 words
The antifoam of claim 5, wherein R 2 is hydrogen and R 4 , R 5 and R 6 are each selected from an alkyl group having from 1 to 8 carbon atoms and further contains terminal units selected from the group consisting of an amino group and a thiol group.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-10-21 | 1989-04-22 | 1989-10-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-10-21 | 1993-04-22 | 1993-10-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-10-21 | 1997-04-22 | 1997-10-22 | $7700.00 | Window Closed / Lapsed |