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US4548613A
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Yellow disperse dyestuff mixtures and dyeing process
Assignee: CNA Holdings LLC
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Filing: 1984-05-18
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Granted: 1985-10-22
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Expires: 2004-05-18
Abstract
Abstract C.I. Disperse Yellow 54 and 64 are important yellow dyestuffs of the quinophthalone type used in coloring synthetic fibers, particularly polyamide, polyester, acrylic and acetate fibers at boiling temperature conditions. Yellow azo dyestuffs of the hydroxypyridone type, e.g., C.I. Disperse Yellow 114, 180 227 and 230 have found widespread application in the high-temperature dyeing of such synthetic fibers. It has now been found that improved tinctorial results on these synthetic fiber materials can be obtained by applying a dyeing composition derived from these yellow coloring means and comprising a mixture of 70-90 parts by weight of one or more dyestuffs of the C.I. 54 and 64 type with 5 to 30 parts by weight of an azo dyestuff of the hydroxypyridone type. These improved dyestuff compositions exhibit superior leveling, high tinctorial strength or color build-up, high dyebath exhaustion and deep shade dyeing over the individual components. In addition, the dyestuff compositions of the invention are not phototropic.
Inventors
- 👤 Albert Bode
- 👤 Thomas V. Chambers
- 👤 Manfred Hahnke
- 👤 Wolfgang Kretzschmar
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 19:05
CPC Classifications
C; C09; C09B; C09B67/00; C09B67/0071; C09B67/008; C09B67/0033; C09B67/0041; D; D06; D06P; D06P1/00; D06P1/16; Y; Y10; Y10S; Y10S534/00; Y10S534/01; Y10S8/00; Y10S8/92; Y10S8/921; Y10S8/922; Y10S8/924
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
172 words
A dyestuff composition comprising a mixture of: (1) 70-95 parts by weight of at least one yellow disperse dyestuff, designated as a Formula I type dyestuff, having the formula: ##STR42## where R 1 is hydrogen or bromine; (2) 5-13 parts by weight of at least one yellow disperse dyestuff, designated as Formula II type dyestuff, having the formula: ##STR43## where: n=0, 1, 2, 3, 4 or 5; R 2 is hydrogen when n=0 or is a substituent independently selected from halogen, cyano, nitro, trifluoromethyl, an alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, aliphatic carboxylate, aromatic sulfonate, aliphatic keto, aromatic keto, unsubstituted carboxyamide, aliphatic carboxyamide, unsubstituted sulfonamide, aliphatic sulfonamide, aliphatic sulfone or aromatic sulfone, when n=an integer of from 1 to 5; and R 3 is hydrogen, alkyl of 1 to 6 carbons, alkyl of 1 to 6 carbons containing ethereal oxygen,, benzyl or phenethyl, wherein said parts by weight are calculated on 100 parts by weight of Formula I type and Formula II type dyestuff.
Claim 2
Dependent Claim
172 words
A dyestuff composition comprising a mixture of: (1) 70-95 parts by weight of at least one yellow disperse dyestuff, designated as a Formula I type dyestuff, having the formula: ##STR42## where R 1 is hydrogen or bromine; (2) 5-13 parts by weight of at least one yellow disperse dyestuff, designated as Formula II type dyestuff, having the formula: ##STR43## where: n=0, 1, 2, 3, 4 or 5; R 2 is hydrogen when n=0 or is a substituent independently selected from halogen, cyano, nitro, trifluoromethyl, an alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, aliphatic carboxylate, aromatic sulfonate, aliphatic keto, aromatic keto, unsubstituted carboxyamide, aliphatic carboxyamide, unsubstituted sulfonamide, aliphatic sulfonamide, aliphatic sulfone or aromatic sulfone, when n=an integer of from 1 to 5; and R 3 is hydrogen, alkyl of 1 to 6 carbons, alkyl of 1 to 6 carbons containing ethereal oxygen,, benzyl or phenethyl, wherein said parts by weight are calculated on 100 parts by weight of Formula I type and Formula II type dyestuff.
Claim 3
Dependent Claim
63 words
A dyestuff composition in accordance with claim 1, wherein the Formula II type dyestuff has the following formula: ##STR44## where n=0, 1, 2, 4 or 5; R 3 is defined as in claim 1; R 4 is hydrogen when n=0 or is a substituent independently selected from methyl, ethyl, chlorine, nitro, cyano, methoxy and ethoxy when n=an integer of from 1 to 5.
Claim 4
Dependent Claim
64 words
A dyestuff composition according to claim 2, wherein said Formula II type dyestuff has the following formula: ##STR45## where n=0 or 1; R 3 is defined as in claim 1; R 4 is defined as in claim 2; and R 5 is amino, alkylamino of 1 to 4 carbons, dialkylamino of 1 to 4 carbons per each alkyl, methyl, ethyl, phenyl or substituted phenoxy.
Claim 5
Dependent Claim
59 words
A dyestuff composition according to claim 2, wherein said Formula II type dyestuff has the formula: ##STR46## where n=0 or 1; R 3 is defined as in claim 1; R 4 is defined as in claim 2; and R 6 is alkyl of 1 to 4 carbons, or alkyl of 1 to 4 carbons containing ethereal oxygen or phenyl-sulfo.
Claim 6
Dependent Claim
67 words
A dyestuff composition according to claim 2, wherein said Formula II type dyestuff has the formula: ##STR47## where n=0 or 1; R 3 is defined as in claim 1; R 4 is defined as in claim 2; and R 7 is alkyl of 1 to 4 carbons, alkoxy of 1 to 4 carbons, amino, alkylamino, or phenyl or phenyl substituted by alkyl of 1 to 4 carbons.
Claim 7
Dependent Claim
47 words
A dyestuff composition according to claim 2, wherein said Formula II type dyestuff has the formula: ##STR48## where n=0 or 1; R 4 is defined as in claim 2; and R 8 is hydrogen, methoxy, methyl, chlorine or nitro; and R 9 is hydrogen, methyl or ethyl.
Claim 8
Dependent Claim
29 words
A dyestuff composition according to claim 2, wherein said Formula II type dyestuff has the formula: ##STR49## where R 10 is hydrogen or alkyl of 1 to 4 carbons.
Claim 9
Dependent Claim
47 words
A dyestuff composition according to claim 1, 2, 3, 4, 5, 6 or 7 containing at least one other disperse dyestuff and wherein said at least one other disperse dyestuff has a structural formula different from the structure of said Formula I and Formula II type dyestuffs.
Claim 10
Dependent Claim
66 words
A dyestuff composition according to claims 1, 2, 3, 4, 5, 6 or 7, wherein said dyestuff designated as Formula I type is present in an amount of from 80-90 parts by weight, and said dyestuff designated as Formula II type is present in an amount of 10-20 parts by weight, calculated on 100 parts by weight of Formula I type and Formula II type dyestuffs.
Claim 11
Dependent Claim
15 words
A process for dyeing a fiber using a dyestuff composition in accordance with claim 1.
Claim 12
Dependent Claim
21 words
A process according to claim 10, wherein said fiber is selected from the group consisting of polyester, polyamide, and cellulose acetate.
Claim 13
Dependent Claim
30 words
A process according to claim 10, wherein said polyester fiber is a copolymer with another monomer selected from the group consisting of polyethylene glycol, isophthalic acid or polymerizable phosphorus compounds.
Claim 14
Dependent Claim
18 words
A process according to claim 10, wherein said dyeing operation is an exhaust method at high temperature conditions.
Claim 15
Dependent Claim
25 words
A process according to claim 10, wherein said dyeing operation is an exhaust method at boiling temperature of the aqueous dyeing medium under atmospheric pressure.
Claim 16
Dependent Claim
19 words
A process according to claim 10, wherein the dyeing operation is carried out in the presence of a carrier.
Claim 17
Dependent Claim
38 words
A process according to claim 10, wherein said dyeing composition is used in combination with at least one other disperse dyestuff having a structure different from that of said Formula I type and Formula II type disperse dyestuffs.
Claim 18
Dependent Claim
19 words
A fiber having therewith a dyestuff composition in accordance with claims 1, 2, 3, 4, 5, 6 or 7.
Claim 19
Dependent Claim
21 words
A fiber according to claim 17, wherein said fiber is selected from the group consisting of polyester, polyamide and cellulose acetate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-10-21 | 1989-04-22 | 1989-10-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-10-21 | 1993-04-22 | 1993-10-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-10-21 | 1997-04-22 | 1997-10-22 | $7700.00 | Window Closed / Lapsed |