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US4546170A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester resins useful for forming containers having improved gas barrier properties

Assignee: Eastman Chemical Co
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Filing: 1984-12-26
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Granted: 1985-10-08
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Expires: 2004-12-26
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Abstract

Abstract The present invention provides polyester resins useful for forming containers having improved resistance to gas permeability. The polyester resin comprises the reaction product of a diol containing up to about 8 carbon atoms and a diacid component which comprises terephthalic acid and oxydiacetic acid. The oxydiacetic acid is present in a concentration of about 5 to 50 mole percent, based upon the total amount of diacid. The polyester resin has an inherent viscosity of about 0.4 to 1.5. A preferred polyester is that derived from ethylene glycol, terephthalic acid, and about 10 to 40 mole percent oxydiacetic acid. The polyesters which are provided by the present invention may be formed into containers in the form of sheet, film, molded articles, such as bottles, and other such structures.

Inventors

  • 👤 Robert B. Barbee
  • 👤 Burns Davis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:17
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 5 to 50 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.4 to 1.5.
Claim 2
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 5 to 50 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.4 to 1.5.
Claim 3
Dependent Claim 18 words
A polyester resin of claim 1 wherein said diol comprises ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or a mixture thereof.
Claim 4
Dependent Claim 12 words
A polyester resin of claim 1 wherein said diol comprises ethylene glycol.
Claim 5
Dependent Claim 11 words
A polyester resin of claim 1 wherein said diol comprises 1,4-butanediol.
Claim 6
Dependent Claim 11 words
A polyester resin of claim 1 wherein said diol comprises 1,4-cyclohexanedimethanol.
Claim 7
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 7.5 to 45 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.5 to 1.2.
Claim 8
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 7.5 to 45 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.5 to 1.2.
Claim 9
Dependent Claim 18 words
A polyester resin of claim 6 wherein said diol comprises ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or a mixture thereof.
Claim 10
Dependent Claim 12 words
A polyester resin of claim 6 wherein said diol comprises ethylene glycol.
Claim 11
Dependent Claim 11 words
A polyester resin of claim 6 wherein said diol comprises 1,4-butanediol.
Claim 12
Dependent Claim 11 words
A polyester resin of claim 6 wherein said diol comprises 1,4-cyclohexanedimethanol.
Claim 13
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 10 to 40 mole percent, based upon the total amount of diacid, and. wherein said polyester resin has an inherent viscosity of about 0.4 to 1.2.
Claim 14
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 10 to 40 mole percent, based upon the total amount of diacid, and. wherein said polyester resin has an inherent viscosity of about 0.4 to 1.2.
Claim 15
Dependent Claim 18 words
A polyester resin of claim 11 wherein said diol comprises ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or a mixture thereof.
Claim 16
Dependent Claim 12 words
A polyester resin of claim 11 wherein said diol comprises ethylene glycol.
Claim 17
Dependent Claim 11 words
A polyester resin of claim 11 wherein said diol comprises 1,4-butanediol.
Claim 18
Dependent Claim 11 words
A polyester resin of claim 11 wherein said diol comprises 1,4-cyclohexanedimethanol.
Claim 19
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 10 to 40 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.55 to 1.
Claim 20
Dependent Claim 68 words
A polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) oxydiacetic acid, wherein said oxydiacetic acid is present in an amount of about 10 to 40 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.55 to 1.
Claim 21
Dependent Claim 18 words
A polyester resin of claim 16 wherein said diol comprises ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or a mixture thereof.
Claim 22
Dependent Claim 12 words
A polyester resin of claim 16 wherein said diol comprises ethylene glycol.
Claim 23
Dependent Claim 11 words
A polyester resin of claim 16 wherein said diol comprises 1,4-butanediol.
Claim 24
Dependent Claim 11 words
A polyester resin of claim 16 wherein said diol comprises 1,4-cyclohexanedimethanol.

References Cited (Backward Citations)

US4403090A Cited
US4436895A Cited
US4446303A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-10-07 1989-04-08 1989-10-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-10-07 1993-04-08 1993-10-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-10-07 1997-04-08 1997-10-08 $7700.00 Window Closed / Lapsed

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