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US4436895A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester containers having improved gas barrier properties

Assignee: Eastman Chemical Co
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Filing: 1983-04-13
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Granted: 1984-03-13
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Expires: 2003-04-13
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Abstract

Abstract The present invention provides containers having improved resistance to gas permeability. The containers are formed from a polyester resin which comprises the reaction product of a diol containing up to about 8 carbon atoms and a diacid component which comprises terephthalic acid and a second diacid selected from iminodiacetic acid, oxydiacetic acid, thiodiacetic acid, and mixtures thereof. The second diacid is present in a concentration of about 1 to 50 mole percent, based upon the total amount of diacid. The polyester resin has an inherent viscosity of about 0.5 to 1.5. A preferred polyester is that derived from ethylene glycol, terephthalic acid, and oxydiacetic acid. The containers which are provided by the present invention may be in the form of sheet, film, molded articles, such as bottles, and other such structures.

Inventors

  • 👤 Robert B. Barbee
  • 👤 Burns Davis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:35
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; C08G63/66; C08G63/668; C08G63/672; C08G63/685; C08G63/6854; C08G63/6856

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 84 words
A container formed from a polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) a second diacid selected from iminodiacetic acid, oxydiacetic acid, thiodiacetic acid, and mixtures thereof, wherein said second diacid is present in a concentration of about 1 to 50 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.
Claim 2
Dependent Claim 84 words
A container formed from a polyester resin comprising the reaction product of (A) a diol containing up to about 8 carbon atoms, and (B) a diacid component comprising (i) terephthalic acid and (ii) a second diacid selected from iminodiacetic acid, oxydiacetic acid, thiodiacetic acid, and mixtures thereof, wherein said second diacid is present in a concentration of about 1 to 50 mole percent, based upon the total amount of diacid, and wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.
Claim 3
Dependent Claim 17 words
The container of claim 1 wherein said diol comprises ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or a mixture thereof.
Claim 4
Dependent Claim 11 words
The container of claim 1 wherein said diol comprises ethylene glycol.
Claim 5
Dependent Claim 10 words
The container of claim 1 wherein said diol comprises 1,4-butanediol.
Claim 6
Dependent Claim 10 words
The container of claim 1 wherein said diol comprises 1,4-cyclohexanedimethanol.
Claim 7
Dependent Claim 12 words
The container of claim 1 wherein said second diacid comprises oxydiacetic acid.
Claim 8
Dependent Claim 21 words
The container of claim 1 wherein said second diacid is present in a concentration of about 5 to 40 mole percent.
Claim 9
Dependent Claim 31 words
The container of claim 1 wherein said container is a film formed from said polyester resin wherein said polyester resin comprises about 10 to 40 mole percent of said second diacid.
Claim 10
Dependent Claim 32 words
The container of claim 1 wherein said container is a molded container formed from said polyester resin wherein said polyester resin comprises about 10 to 20 mole percent of said second diacid.
Claim 11
Dependent Claim 58 words
A container formed from a polyester resin comprising the reaction product of (A) a diol component comprising ethylene glycol, and (B) a diacid component comprising (i) terephthalic acid and (ii) 1 to 50 mole percent, based on the total amount of diacid, of oxydiacetic acid, wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.
Claim 12
Dependent Claim 58 words
A container formed from a polyester resin comprising the reaction product of (A) a diol component comprising ethylene glycol, and (B) a diacid component comprising (i) terephthalic acid and (ii) 1 to 50 mole percent, based on the total amount of diacid, of oxydiacetic acid, wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.
Claim 13
Dependent Claim 57 words
A container former from a polyester resin comprising the reaction product of (A) a diol component comprising 1,4-butanediol, and (B) a diacid component comprising (i) terephthalic acid and (ii) 1 to 50 mole percent, based on the total amount of diacid, of oxydiacetic acid, wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.
Claim 14
Dependent Claim 57 words
A container former from a polyester resin comprising the reaction product of (A) a diol component comprising 1,4-butanediol, and (B) a diacid component comprising (i) terephthalic acid and (ii) 1 to 50 mole percent, based on the total amount of diacid, of oxydiacetic acid, wherein said polyester resin has an inherent viscosity of about 0.5 to 1.5.

References Cited (Backward Citations)

US3931114A Cited
US4076693A Cited
US4403090A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-13 1987-09-12 1988-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-13 1991-09-12 1992-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-13 1995-09-12 1996-03-13 $7700.00 Window Closed / Lapsed

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