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US4542252A Expired / Lapsed US ⏱️ 0.0 years remaining

Multi-stage adiabatic process for methanol conversion to light olefins

Assignee: Mobil Oil AS
•
Filing: 1984-07-20
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Granted: 1985-09-17
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Expires: 2004-07-20
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Abstract

Abstract The operating performance of a multi-stage fixed bed adiabatic reactor system with interstage cooling designed for the exothermic conversion of methanol to light olefins is improved by cofeeding small quantities of light olefins with the methanol feed whereby a more controllable operation is achieved. Catalyst activity and cycle length also improves significantly. The light olefins can be produced in situ during dehydration.

Inventors

  • 👤 Kenneth R. Graziani
  • 👤 Ajit V. Sapre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:49
CPC Classifications
B; B01; B01J; B01J8/00; B01J8/02; B01J8/04; B01J8/0446; B01J8/0449; B01J8/0453; B01J8/0492; B01J8/0496; C; C07; C07C; C07C1/00; C07C1/20; B01J2208/00; B01J2208/00008; B01J2208/00017; B01J2208/00106; B01J2208/00168; B01J2208/00203; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 190 words
In a process for converting lower aliphatic alcohols into a predominantly olefinic hydrocarbon product by (a) contacting a feed comprising said aliphatic alcohol with a dehydration catalyst at elevated temperatures and exothermic reaction conditions effective to convert said alcohol to an ether-rich product, and (b) contacting the ether-rich product with at least a plurality of fixed beds of crystalline aluminosilicate zeolite in a sequential manner at elevated temperatures at substantially the same temperature increases across each of said fixed beds and under exothermic reaction conditions effective to convert said ether-rich product, at a predetermined conversion, to olefinic hydrocarbons, and cooling the reaction mixture effluent from each of said fixed beds, except the last, to reduce the temperature of said effluent by an amount substantially equal to the temperature increase across each fixed bed, the improvement comprising cofeeding with said ether-rich product about 0.5-3 percent by weight of a light olefin to the first of said fixed beds to stabilize the operation of said fixed beds whereby the shapes of the temperature profiles of the individual fixed beds are closer to each other allowing increased stable temperature rise in each stage.
Claim 2
Dependent Claim 190 words
In a process for converting lower aliphatic alcohols into a predominantly olefinic hydrocarbon product by (a) contacting a feed comprising said aliphatic alcohol with a dehydration catalyst at elevated temperatures and exothermic reaction conditions effective to convert said alcohol to an ether-rich product, and (b) contacting the ether-rich product with at least a plurality of fixed beds of crystalline aluminosilicate zeolite in a sequential manner at elevated temperatures at substantially the same temperature increases across each of said fixed beds and under exothermic reaction conditions effective to convert said ether-rich product, at a predetermined conversion, to olefinic hydrocarbons, and cooling the reaction mixture effluent from each of said fixed beds, except the last, to reduce the temperature of said effluent by an amount substantially equal to the temperature increase across each fixed bed, the improvement comprising cofeeding with said ether-rich product about 0.5-3 percent by weight of a light olefin to the first of said fixed beds to stabilize the operation of said fixed beds whereby the shapes of the temperature profiles of the individual fixed beds are closer to each other allowing increased stable temperature rise in each stage.
Claim 3
Dependent Claim 16 words
The improvement of claim 1 wherein said cofed light olefin comprises C 2 -C 4 olefins.
Claim 4
Dependent Claim 11 words
The improvement of claim 1 wherein said cofed olefin is propylene.
Claim 5
Dependent Claim 22 words
The improvement of claim 3 wherein the amount of cofed olefin is no greater than 1.5 weight percent of said ether-rich product.
Claim 6
Dependent Claim 17 words
The improvement of claim 4 wherein the amount of cofed olefin is about 0.7 percent by weight.
Claim 7
Dependent Claim 32 words
The improvement of claim 1 wherein said cofed light olefin is formed by cofeeding the corresponding alcohol of said light olefin with said aliphatic alcohol feed for contact over said dehydration catalyst.
Claim 8
Dependent Claim 24 words
The improvement of claim 6 wherein said cofed olefin is propylene, said propylene being produced by cofeeding isopropanol for contact with said dehydration catalyst.
Claim 9
Dependent Claim 18 words
The improvement of claim 1 wherein said crystalline aluminosilicate zeolite present in said fixed beds is ZSM-5 zeolite.
Claim 10
Dependent Claim 19 words
The improvement of claim 8 wherein the ZSM-5 zeolite has a crystal size of at least about 1 micron.
Claim 11
Dependent Claim 20 words
The improvement of claim 8 wherein amorphous silica is interdisposed within the interior of said crystalline structure of said zeolite.
Claim 12
Dependent Claim 19 words
The improvement of claim 1 wherein said crystalline aluminosilicate zeolite present in said fixed beds is erionite or ZSM-34.
Claim 13
Dependent Claim 12 words
The improvement of claim 1 wherein the dehydration catalyst is gamma alumina.
Claim 14
Dependent Claim 29 words
The imrovement of claim 1 wherein the exothermic reaction conditions in said fixed beds include a pressure of less than 100 psig and a space velocity of 0.1-5 WHSV.
Claim 15
Dependent Claim 39 words
The improvement of claim 1 wherein said lower aliphatic alcohol is methanol and wherein the feed for contacting with said dehydration catalyst is a methanol-water feed containing about 0 to about 70 wt.% water or an equivalent methanol-water feed.
Claim 16
Dependent Claim 17 words
The improvement of claim 1 wherein the predetermined conversion is between about 10 and about 90 percent.
Claim 17
Dependent Claim 24 words
The improvement of claim 1 wherein the temperature rise across each of the plurality of fixed beds is between about 18° and 45° F.
Claim 18
Dependent Claim 17 words
The improvement of claim 1 wherein the minimum number of fixed beds is from 2 to 10.
Claim 19
Dependent Claim 25 words
The improvement of claim 8 wherein the elevated temperatures in said fixed beds are in the range of from about 520° to about 750° F.
Claim 20
Dependent Claim 23 words
The improvement of claim 11 wherein the elevated temperatures in said fixed beds are in the range of about 600° to 900° F.

References Cited (Backward Citations)

US2596299A Cited
US2299197A Cited
US3433600A Cited
US4058576A Cited
US3931349A Cited
US4100219A Cited
US4025571A Cited
US4404414A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-09-16 1989-03-18 1989-09-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-09-16 1993-03-18 1993-09-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-09-16 1997-03-18 1997-09-17 $7700.00 Window Closed / Lapsed

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