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US4542178A
Expired / Lapsed
US
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Plasticizer-containing polyvinyl alcohol granules
Assignee: Clariant Produkte Deutschland GmbH
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Filing: 1983-12-02
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Granted: 1985-09-17
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Expires: 2003-12-02
Abstract
Abstract For the thermoplastic processing of polyvinyl alcohol, the processing temperature must be below the decomposition temperature of the polyvinyl alcohol; this is attained by incorporating plasticizers. For preparing a plasticizer-containing granular polyvinyl alcohol wherein the plasticizer is homogeneously distributed, there is used as starting material a granular polyvinyl alcohol consisting substantially of particles having a definite diameter. The plasticizer is incorporated in the presence of a small amount of water insufficient to dissolve the polyvinyl alcohol, and the temperature is adjusted in a definite manner during the mixing operation. Simultaneous presence of fine particles of a high molecular weight organic compound soluble or dispersible in water is advantageous. The plasticizer-containing granular polyvinyl alcohol is suitable for the manufacture of any shaped articles, especially films and sheets.
Inventors
- 👤 Wolfgang Zimmermann
- 👤 Albrecht Harreus
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 09:41
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/18; C08J3/12; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08J2329/00; C08J2329/02; C08J2329/04
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
91 words
A plasticizer-containing, pourable and tack-free granular polyvinyl alcohol composition comprising polyvinyl alcohol, at least 90% of the plasticized polyvinyl alcohol granules being from 0.8 to 4 mm in diameter; a plasticizer homogeneously distributed therein, the plasticizer being present in an amount of 10 to 30% by weight relative to the unplasticized polyvinyl alcohol granules; and further containing, distributed homogeneously therein, a fine particle high molecular weight organic compound, in an amount of 2 to 12% by weight relative to the unplasticized polyvinyl alcohol granules, which is soluble or dispersible in water.
Claim 2
Dependent Claim
91 words
A plasticizer-containing, pourable and tack-free granular polyvinyl alcohol composition comprising polyvinyl alcohol, at least 90% of the plasticized polyvinyl alcohol granules being from 0.8 to 4 mm in diameter; a plasticizer homogeneously distributed therein, the plasticizer being present in an amount of 10 to 30% by weight relative to the unplasticized polyvinyl alcohol granules; and further containing, distributed homogeneously therein, a fine particle high molecular weight organic compound, in an amount of 2 to 12% by weight relative to the unplasticized polyvinyl alcohol granules, which is soluble or dispersible in water.
Claim 3
Dependent Claim
25 words
The composition of claim 1, wherein the high molecular weight organic compound is a starch, starch derivative, cellulose, cellulose derivative, casein, gelatin or vinyl polymer.
Claim 4
Dependent Claim
15 words
The composition of claim 2, wherein the cellulose derivative is methyl cellulose or carboxyhydroxy cellulose.
Claim 5
Dependent Claim
15 words
The composition of claim 2, wherein the vinyl polymer is polyvinyl ester or polyvinyl acetal.
Claim 6
Dependent Claim
42 words
The composition of claim 2, wherein the vinyl polymer is a copolymer of vinyl acetate with ethylene, maleic acid diesters, fumaric diesters, acrylic acid diesters, methacrylic acid esters or acrylonitrile, the alcohol portion of the esters having 2 to 8 carbon atoms.
Claim 7
Dependent Claim
26 words
The composition of claim 1, wherein the high molecular weight compound is in the form of powder particles having diameters of from 10 to 300 micrometers.
Claim 8
Dependent Claim
21 words
The composition of claim 6 wherein the diameters of the high molecular weight compound particles are from 20 to 200 micrometers.
Claim 9
Dependent Claim
34 words
The composition of claim 1, wherein the high molecular weight compound is in the form of an aqueous dispersion in which the particle diameter of the disperse compound is from 0.1 to 10 micrometers.
Claim 10
Dependent Claim
15 words
The composition of claim 8, wherein the particle diameter is from 0.2 to 8 mircometers.
Claim 11
Dependent Claim
55 words
The composition of claim 1, further including up to 3% by weight of an auxiliary comprising a heat stabilizer, a dyestuff and a lubricant selected from the group consisting of stearic acid, wax, polyethylene glycol having a molecular weight of from 400 to 20,000, silicic acid and an alkaline earth stearate, or a combination thereof.
Claim 12
Dependent Claim
27 words
The composition of claim 10, wherein the auxiliary or auxiliaries are present in amounts of from 0.4 to 1.0% by weight relative to the polyvinyl alcohol granules.
Claim 13
Dependent Claim
19 words
The composition of claim 1, wherein the plasticizer is an aliphatic polyol having a boiling point above 250° C.
Claim 14
Dependent Claim
15 words
The composition of claim 12, wherein the plasticizer is ethyleneglycol, glycerol, trimethylolpropane, neopentylglycol or sorbitol.
Claim 15
Dependent Claim
27 words
The composition of claim 1, wherein the plasticizer is glycerol and further including a high molecular weight compound which comprises a polyvinylacetate which is dispersible in water.
Claim 16
Dependent Claim
27 words
The composition of claim 1, wherein at least 70 weight % of the polyvinyl alcohol granules consist of particles having a diameter of 1 to 3.5 mm.
Claim 17
Dependent Claim
25 words
The composition of claim 15, wherein at least 90% of the polyvinyl alcohol granules consist of particles having a diameter of 1 to 3.5 mm.
Claim 18
Dependent Claim
86 words
The composition of claim 1, wherein the fine particle high molecular weight organic compound has a particle diameter size of from 0.1 to 300 μm and a polymerization degree (average weight) of from 300 to 5000; and the composition further contains auxiliaries, in an amount from 0.04 to 1% by weight, including a heat stabilizer, a dyestuff and a lubricant selected from the group consisting of stearic acid, wax, polyethyleneglycol having a molecular weight of from 400 to 20,000, silicic acid and an alkaline earth stearate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-16 | 1989-03-18 | 1989-09-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-16 | 1993-03-18 | 1993-09-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-16 | 1997-03-18 | 1997-09-17 | $7700.00 | Window Closed / Lapsed |