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US4540651A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic photosensitive member

Assignee: Konica Minolta Inc
•
Filing: 1983-11-07
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Granted: 1985-09-10
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Expires: 2003-11-07
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Abstract

Abstract There is disclosed an electrophotographic photosensitive member comprising a photosensitive layer comprising a combination of a carrier generating layer and a carrier transporting layer provided on an electroconductive support, the carrier generating layer containing a bisazo compound and the carrier transporting layer containing a styryl compound and/or an amine derivative, a hydrazone compound or a carbazole derivative. The electrophotographic photosensitive member according to the present invention has a high sensitivity and can form constantly good visible images.

Inventors

  • 👤 Yoshihide Fujimaki
  • 👤 Yoshiaki Takei
  • 👤 Hiroyuki Nomori

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:09
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0675; G03G5/0679; G03G5/0683; G03G5/0685; G03G5/0601; G03G5/0612; G03G5/0614; G03G5/06142; G03G5/06147; G03G5/0616; G03G5/0622; G03G5/0624; G03G5/0627; G03G5/0629; G03G5/0635; G03G5/0637; G03G5/0666; G03G5/0668; G03G5/067

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 576 words
An electrophotographic photosensitive member comprising a photosensitive layer comprising a combination of a carrier generating phase and a carrier transporting phase provided on an electroconductive support, said carrier generating phase containing a bisazo compound represented by the formula [I] shown below and said carrier transporting phase containing a carrier transporting material selected from the group consisting of at least one of styryl compounds represented by the formula [II] shown below, amine derivatives represented by the formula [III], hydrazone compounds represented by the formula [IV], [V] and [VI] and carbazole derivatives represented by the formula [VII]: ##STR21## wherein each of Ar 1 , Ar 2 and Ar 3 represents a divalent carbocyclic aromatic residue or a divalent heterocyclic aromatic residue; each of R 1 , R 2 , R 3 and R 4 represents an electron attracting group or a hydrogen atom, provided that 1 or 2 of R 1 to R 4 are electron attracting groups and the case where R 1 and R 2 or R 3 and R 4 are electron attracting groups at the same time is excluded; A is a group represented by the following formula: ##STR22## wherein X is a hydroxyl group, ##STR23## where each of R 6 and R 7 is a hydrogen atom, an alkyl group and R 8 is an alkyl group or an aryl group; Y is a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a carboxyl group, a sulfo group, a carbamoyl group or a sulfamoyl group; Z is a group of atoms necessary for forming a carbocyclic aromatic ring or a heterocyclic aromatic ring; R 5 is a hydrogen atom, an amino group, a carbamoyl group, a carboxyl group or its ester group; A' is an aryl group; n is an integer of 1 to 3; and m is an integer of 0 to 4, ##STR24## wherein each of R 9 and R 10 represents an alkyl group or phenyl group; R 11 represents a phenyl group, naphthyl group, anthryl group, fluorenyl group or heterocyclic group; each of R 12 to R 15 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an amino group, ##STR25## wherein each of Ar 4 and Ar 5 represents a phenyl group; and Ar 6 represents a phenyl group, naphthyl group, anthryl group, fluorenyl group or heterocyclic group, ##STR26## wherein each of R 16 to R 17 represents a hydrogen atom or a halogen atom; each of R 18 and R 19 represents an aryl group; and Ar 7 represents an arylene group, ##STR27## wherein R 20 represents an aryl group or a heterocyclic group; R 21 represents a hydrogen atom, an alkyl group or an aryl group; X 1 represents a hydrogen atom, a halogen atom, an alkyl group, an amino group or an alkoxyl group; and p represents an integer of 0 or 1, ##STR28## wherein R 22 represents an aryl group or a heterocyclic group; R 23 represents a hydrogen atom or an alkyl group; X 2 represents a hydrogen atom, a halogen atom, an alkyl group, an amino group, an alkoxy group or a cyano group; and q represents an integer of 0 or 1, ##STR29## wherein R 24 represents an aryl group; R 25 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amino group or a hydroxyl group; and R 26 represents an aryl group or a heterocyclic group.
Claim 2
Dependent Claim 576 words
An electrophotographic photosensitive member comprising a photosensitive layer comprising a combination of a carrier generating phase and a carrier transporting phase provided on an electroconductive support, said carrier generating phase containing a bisazo compound represented by the formula [I] shown below and said carrier transporting phase containing a carrier transporting material selected from the group consisting of at least one of styryl compounds represented by the formula [II] shown below, amine derivatives represented by the formula [III], hydrazone compounds represented by the formula [IV], [V] and [VI] and carbazole derivatives represented by the formula [VII]: ##STR21## wherein each of Ar 1 , Ar 2 and Ar 3 represents a divalent carbocyclic aromatic residue or a divalent heterocyclic aromatic residue; each of R 1 , R 2 , R 3 and R 4 represents an electron attracting group or a hydrogen atom, provided that 1 or 2 of R 1 to R 4 are electron attracting groups and the case where R 1 and R 2 or R 3 and R 4 are electron attracting groups at the same time is excluded; A is a group represented by the following formula: ##STR22## wherein X is a hydroxyl group, ##STR23## where each of R 6 and R 7 is a hydrogen atom, an alkyl group and R 8 is an alkyl group or an aryl group; Y is a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a carboxyl group, a sulfo group, a carbamoyl group or a sulfamoyl group; Z is a group of atoms necessary for forming a carbocyclic aromatic ring or a heterocyclic aromatic ring; R 5 is a hydrogen atom, an amino group, a carbamoyl group, a carboxyl group or its ester group; A' is an aryl group; n is an integer of 1 to 3; and m is an integer of 0 to 4, ##STR24## wherein each of R 9 and R 10 represents an alkyl group or phenyl group; R 11 represents a phenyl group, naphthyl group, anthryl group, fluorenyl group or heterocyclic group; each of R 12 to R 15 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an amino group, ##STR25## wherein each of Ar 4 and Ar 5 represents a phenyl group; and Ar 6 represents a phenyl group, naphthyl group, anthryl group, fluorenyl group or heterocyclic group, ##STR26## wherein each of R 16 to R 17 represents a hydrogen atom or a halogen atom; each of R 18 and R 19 represents an aryl group; and Ar 7 represents an arylene group, ##STR27## wherein R 20 represents an aryl group or a heterocyclic group; R 21 represents a hydrogen atom, an alkyl group or an aryl group; X 1 represents a hydrogen atom, a halogen atom, an alkyl group, an amino group or an alkoxyl group; and p represents an integer of 0 or 1, ##STR28## wherein R 22 represents an aryl group or a heterocyclic group; R 23 represents a hydrogen atom or an alkyl group; X 2 represents a hydrogen atom, a halogen atom, an alkyl group, an amino group, an alkoxy group or a cyano group; and q represents an integer of 0 or 1, ##STR29## wherein R 24 represents an aryl group; R 25 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amino group or a hydroxyl group; and R 26 represents an aryl group or a heterocyclic group.
Claim 3
Dependent Claim 37 words
The electrophotographic photosensitive member of claim 1, wherein said photosensitive layer comprises a carrier generating phase as a layer containing said bisazo compound and a carrier transporting phase as a separate layer containing said carrier transporting material.
Claim 4
Dependent Claim 64 words
The electrophotographic photosensitive member of claim 2, wherein the bisazo compound is selected from the compounds of the formulae [Ia-1] to [Ia-4] shown below: ##STR30## wherein Ar 1 , Ar 2 , Ar 3 and A are the same as defined in Formula [I], and R 1 ', R 2 ', R 3 ' and R 4 ' each represents an electron attracting group.
Claim 5
Dependent Claim 25 words
The electrophotographic photosensitive member of claim 3, wherein R 1 ', R 2 ', R 3 ' and R 4 ' are a cyano group.
Claim 6
Dependent Claim 49 words
The electrophotographic photosensitive member of claim 4, wherein the bisazo compound is selected from the compounds of the formulae [Ib-1] to [Ib-4] shown below: ##STR31## wherein A is the same as defined in Formula [I], each of Ar 8 , Ar 9 and Ar 10 represents a phenyl group.
Claim 7
Dependent Claim 40 words
The electrophotographic photosensitive member of claim 5, wherein each of Ar 8 , Ar 9 and Ar 10 represents a phenyl group, an alkyl substituted phenyl group, an alkoxy group, a halogen atom, a hydroxyl group or a cyano group.
Claim 8
Dependent Claim 17 words
The electrophotographic photosensitive member of claim 2, wherein the carrier generating layer further comprises a binder resin.
Claim 9
Dependent Claim 20 words
The electrophotographic photosensitive member of claim 2, wherein the carrier generating layer has a thickness of 0.005 to 20 microns.
Claim 10
Dependent Claim 17 words
The electrophotographic photosensitive member of claim 7, wherein the carrier transporting layer further comprises a binder resin.
Claim 11
Dependent Claim 20 words
The electrophotographic photosensitive member of claim 8, wherein the carrier transporting layer has a thickness of 2 to 100 microns.
Claim 12
Dependent Claim 21 words
The electrophotographic photosensitive member of claim 2, wherein further comprising an intermediate layer between the photosensitive layer and the electroconductive support.
Claim 13
Dependent Claim 30 words
The electrophotographic photosensitive member of claim 2, wherein the photosensitive layer is provided in the order of the carrier generating layer and the carrier transporting layer on the electroconductive support.
Claim 14
Dependent Claim 30 words
The electrophotographic photosensitive member of claim 2, wherein the photosensitive layer is provided in the order of the carrier transporting layer and the carrier generating layer on the electroconductive support.
Claim 15
Dependent Claim 45 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-1] and said carrier transporting layer contains at least one of styryl compounds represented by the formula [II] and amine derivatives represented by the formula [III].
Claim 16
Dependent Claim 33 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-1] and said carrier transporting layer contains hydrazone compounds represented by the formula [IV].
Claim 17
Dependent Claim 35 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-1] and said carrier transporting layer contains hydrazone compounds represented by the formula [V] or [VI].
Claim 18
Dependent Claim 33 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-1] and said carrier transporting layer contains carbazol derivatives represented by the formula [VII].
Claim 19
Dependent Claim 45 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-2] and said carrier transporting layer contains styryl compounds represented by at least one of the formula [II] and amine derivatives represented by the formula [III].
Claim 20
Dependent Claim 33 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-2] and said carrier transporting layer contains hydrazone compounds represented by the formula [IV].
Claim 21
Dependent Claim 35 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-2] and said carrier transporting layer contains hydrazone compounds represented by the formula [V] or [VI].
Claim 22
Dependent Claim 33 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-2] and said carrier transporting layer contains carbazol derivatives represented by the formula [VII].
Claim 23
Dependent Claim 47 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-3] or [Ia-4] and said carrier transporting layer contains at least one of styryl compounds represented by the formula [II] and amine derivatives represented by the formula [III].
Claim 24
Dependent Claim 35 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-3] or [Ia-4] and said carrier transporting layer contains hydrazone compounds represented by the formula [IV].
Claim 25
Dependent Claim 37 words
The electrophotographic photosensitive member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-3] or [Ia-4] and said carrier transporting layer contains hydrazone compounds represented by the formula [V] or [VI].
Claim 26
Dependent Claim 35 words
The electrophotographic photosensitve member of claim 2, wherein said carrier generating layer contains bisazo compounds represented by the formula [Ia-3] or [Ia-4] and said carrier transporting layer contains carbazol derivatives represented by the formula [VII].
Claim 27
Dependent Claim 23 words
The electrophotographic photosensitive member of claim 2, wherein said bisazo compound is ##STR32## and said carrier transporting material is the styryl compound ##STR33##
Claim 28
Dependent Claim 23 words
The electrophotographic photosensitive member of claim 2, wherein said bisazo compound is ##STR34## and said carrier transporting material is the hydrazone compound ##STR35##
Claim 29
Dependent Claim 23 words
The electrophotographic photosensitive member of claim 2, wherein said bisazo compound is ##STR36## and said carrier transporting material is the hydrazone compound ##STR37##
Claim 30
Dependent Claim 23 words
The electrophotographic photosensitive member of claim 2, wherein said bisazo compound is ##STR38## and said carrier transporting material is the hydrazone compound ##STR39##
Claim 31
Dependent Claim 23 words
The electrophotographic photosensitive member of claim 2, wherein said bisazo compound is ##STR40## and said carrier transporting material is the carbazole compound ##STR41##
Claim 32
Dependent Claim 35 words
The electrophotographic photosensitive member of claim 2, wherein said electron attracting group R 1 , R 2 , R 3 and R 4 in said bisazo compound is CN, Cl, Br, or NO 2 .

References Cited (Backward Citations)

US4427753A Cited
US4399207A Cited
US4450218A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-09-09 1989-03-11 1989-09-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-09-09 1993-03-11 1993-09-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-09-09 1997-03-11 1997-09-10 $7700.00 Window Closed / Lapsed

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