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US4539282A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic photoconductive elements

Assignee: Tomoegawa Paper Manufacturing Co Ltd
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Filing: 1983-12-20
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Granted: 1985-09-03
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Expires: 2003-12-20
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Abstract

Abstract Electrophotographic photosensitive element using zinc oxide in a photosensitive layer thereof formed in conductive support are described. Zinc oxide is used in combination with polycarbonate binder and a compound of the specific type. The compound is represented by the formula ##STR1## in which R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, or an aryl group, R 5 and R 6 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, or an aryl group, R 7 , R 8 , R 9 and R 10 independently represent a hydrogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group or an amino group. Optionally, R 5 and R 6 may jointly form a saturated or unsaturated hydrocarbon ring having from 3 to 10 carbon atoms.

Inventors

  • 👤 Junichi Morimoto
  • 👤 Fumio Kawamura
  • 👤 Akira Watanabe
  • 👤 Yoshio Suzuki
  • 👤 Masamichi Kawamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 01:54
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0503; G03G5/051; G03G5/0517; G03G5/06; G03G5/0601; G03G5/0612; G03G5/0614; G03G5/06142; G03G5/06144

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 212 words
An electrophotographic photosensitive element which comprises a conductive support and at least a photosensitive layer formed on said conductive support, said photosensitive layer comprising sensitizing dye treated zinc oxide, a polycarbonate binder used in an amount ranging from 5 to 400 parts by weight per hundred parts by weight of said zinc oxide, and a compound of the general formula (I) used in an amount ranging from 5 to 500 parts by weight per hundred parts by weight of said zinc oxide, ##STR5## in which R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, or an aryl group, R 5 and R 6 independently represent a hydrogen atom, a substituted or unsubstitued alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, or an aryl group, R 7 , R 8 , R 9 and R 10 independently represent a hydrogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group or an amino group, and optionally R 5 and R 6 are able to jointly form a saturated or unsaturated hydrocarbon ring having from 3 to 10 carbon atoms.
Claim 2
Dependent Claim 212 words
An electrophotographic photosensitive element which comprises a conductive support and at least a photosensitive layer formed on said conductive support, said photosensitive layer comprising sensitizing dye treated zinc oxide, a polycarbonate binder used in an amount ranging from 5 to 400 parts by weight per hundred parts by weight of said zinc oxide, and a compound of the general formula (I) used in an amount ranging from 5 to 500 parts by weight per hundred parts by weight of said zinc oxide, ##STR5## in which R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, or an aryl group, R 5 and R 6 independently represent a hydrogen atom, a substituted or unsubstitued alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, or an aryl group, R 7 , R 8 , R 9 and R 10 independently represent a hydrogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group or an amino group, and optionally R 5 and R 6 are able to jointly form a saturated or unsaturated hydrocarbon ring having from 3 to 10 carbon atoms.
Claim 3
Dependent Claim 26 words
The electrophotographic photosensitive element according to claim 1, wherein said sensitizing dye is a member selected from the group consisting of xanthene dyes and triphenylmethane dyes.
Claim 4
Dependent Claim 36 words
The electrophotographic photosensitive element according to claim 2, wherein an amount of said sensitizing dye is in the range of 10 -3 to 5 parts by weight per 100 parts by weight of said zinc oxide.
Claim 5
Dependent Claim 22 words
The electrophotographic photosensitive element according to claim 1, further comprising an intermediate layer provided between said conductive support and said photosensitive layer.
Claim 6
Dependent Claim 22 words
The electrophotographic photosensitive element according to claim 6, wherein said intermediate layer is made of casein, polyvinyl pyrrolidone or water-soluble butyral resin.
Claim 7
Dependent Claim 53 words
The electrophotographic photosensitive element according to claim 1, wherein in the formula (I), R 1 , R 2 , R 3 and R 4 independently represent ethyl or benzyl, R 5 , R 8 and R 10 independently represent hydrogen R 6 represents phenyl, and R 7 and R 9 independently represent methyl.
Claim 8
Dependent Claim 78 words
The electrophotographic photosensitive element according to claim 1, wherein said polycarbonate is a polymer having repeating units of the formula ##STR6## in which R represents an unsubstituted phenylene group, a halogen-substituted phenylene group or an alkyl-substituted phenylene group, and R 11 and R 12 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, or jointly form a saturated or unsaturated hydrocarbon ring having from 3 to 19 carbon atoms.
Claim 9
Dependent Claim 17 words
The electrophotographic photosensitive element as recited in claim 1 wherein the compound of formula (I) is 1,1-bis(4-N,N-diethylamino-2-methylphenyl)-1-(4-N,N-diethylaminophenyl)methane.
Claim 10
Dependent Claim 16 words
The electrophotographic element as recited in claim 1 wherein the compound of formula (I) is 1,1-bis(4-N,N-diethylamino-2-methylphenyl)-1-phenylmethane.

References Cited (Backward Citations)

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JPS5560953A Cited
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JPS5665141A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-09-02 1989-03-04 1989-09-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-09-02 1993-03-04 1993-09-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-09-02 1997-03-04 1997-09-03 $7700.00 Window Closed / Lapsed

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