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US4537945A
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Polyether derivative and a poly(urethane)ureamide obtained therefrom
Assignee: Toyo Tire Corp
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Filing: 1984-09-17
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Granted: 1985-08-27
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Expires: 2004-09-17
Abstract
Abstract A poly(urethane)ureamide which comprises a polymer obtained by a reaction of (a) a polyether derivative of the general formula [I] and (b) a polyisocyanate exhibits an excellent wear resistance and heat resistance due to the presence of the aromatic amido groups ##STR1## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1.
Inventors
- 👤 Kozo Otani
- 👤 Yoshio Yamada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 15:02
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/50; C08G18/5021; C08G18/5036; C08G18/5039; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C08G65/333; C08G65/33303; C08G65/3331; C08G65/33313
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
60 words
A polyether derivative of the formula ##STR5## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1.
Claim 2
Dependent Claim
60 words
A polyether derivative of the formula ##STR5## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1.
Claim 3
Dependent Claim
103 words
A process for preparing a polyether derivative of the formula ##STR6## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1, which process comprises reacting one mole of an n-valent polyoxyalkylene polyol having a molecular weight of 400 to 10,000 with 0.125n to 2n moles of aminobenzoic acid in the presence of 0.125n to 30n equivalents of an aliphatic alcohol.
Claim 4
Dependent Claim
103 words
A process for preparing a polyether derivative of the formula ##STR6## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1, which process comprises reacting one mole of an n-valent polyoxyalkylene polyol having a molecular weight of 400 to 10,000 with 0.125n to 2n moles of aminobenzoic acid in the presence of 0.125n to 30n equivalents of an aliphatic alcohol.
Claim 5
Dependent Claim
11 words
A polyether derivative prepared according to the process of claim 2.
Claim 6
Dependent Claim
76 words
A poly(urethane)ureamide which comprises a polymer obtained by a reaction of (a) a polyether derivative of the formula ##STR7## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1, and (b) a polyisocyanate.
Claim 7
Dependent Claim
76 words
A poly(urethane)ureamide which comprises a polymer obtained by a reaction of (a) a polyether derivative of the formula ##STR7## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1, and (b) a polyisocyanate.
Claim 8
Dependent Claim
23 words
A poly(urethane)ureamide as claimed in claim 4 which is obtained by further reacting a chain extender having a molecular weight up to 400.
Claim 9
Dependent Claim
120 words
A process for preparing a poly(urethane)ureamide as defined in claim 4, which process comprises reacting one mole of an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000 with 0.125n to 2n moles of aminobenzoic acid in the presence of 0.125n to 30n equivalents of an aliphatic alcohol to obtain a polyether derivative of the general formula ##STR8## wherein A is an n-valent radical obtained by removal of hydroxyl groups from an n-valent polyoxyalkylenepolyol having a molecular weight of 400 to 10,000, n is an integer of 2 to 8, x is an average value and a number of 0≦x<(n-1) and y is an average value and a number of 0.05≦y<1, and reacting said polyether derivative with a polyisocyanate.
Claim 10
Dependent Claim
21 words
A process as claimed in claim 6 wherein a chain extender having a molecular weight up to 400 is further reacted.
Claim 11
Dependent Claim
10 words
A poly(urethane)ureamide prepared according to the process of claim 6.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-26 | 1989-02-25 | 1989-08-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-26 | 1993-02-25 | 1993-08-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-26 | 1997-02-25 | 1997-08-27 | $7700.00 | Window Closed / Lapsed |