Patent US4537760A successfully refreshed from Google Patents.
US4537760A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the manufacture of ammonia
Assignee: Technion Research and Development Foundation Ltd
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Filing: 1984-08-14
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Granted: 1985-08-27
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Expires: 2004-08-14
Abstract
Abstract The present invention relates to an improved process for the manufacture of ammonia from a gaseous mixture containing hydrogen and nitrogen. According to the invention, the process comprises the steps of: (a) feeding a gaseous mixture of hydrogen and nitrogen, in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis; (b) conveying the reaction mixture from said converter through a water-free adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the water-free ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases, and (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia. The process has several advantages such as: reduced investments in equipment, substantial savings in mechanical energy, high yields of ammonia conversion per pass and less energy requirements per unit of ammonia produced.
Inventors
- 👤 Ram Lavie
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:40
CPC Classifications
C; C01; C01C; C01C1/00; C01C1/02; C01C1/04; C01C1/0405; C01C1/0458; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
153 words
A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions.
Claim 2
Dependent Claim
153 words
A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions.
Claim 3
Dependent Claim
35 words
A process according to claim 1, wherein two or more adsorbent beds are utilized to carry out, in parallel, said adsorption and desorption steps in said phased order, providing said continuous streams of controlled compositions.
Claim 4
Dependent Claim
41 words
A process according to claim 1, wherein heat is transferred from the hot regenerant stream to the adsorbent bed to be regenerated and subsequently heat is transferred from the adsorbent bed to the unreacted mixture of gases recycled into the converter.
Claim 5
Dependent Claim
23 words
A process according to claim 1, wherein the adsorbent bed separates simultaneously the ammonia and methane from the gas recycled to the converter.
Claim 6
Dependent Claim
27 words
A process according to claim 4, wherein the gases going out from the adsorbent bed and entering into the converter, comprises substantially pure synthesis gas including argon.
Claim 7
Dependent Claim
20 words
A process according to claim 1, carried out in an existing ammonia plant wherein solid adsorption beds are incorporated therein.
Claim 8
Dependent Claim
20 words
A process according to claim 1 wherein said desorption is carried out at substantially the same pressure as said adsorption.
Claim 9
Dependent Claim
166 words
A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising hot compressed ammonia refrigerant which is at least as concentrated with ammonia as the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions.
Claim 10
Dependent Claim
166 words
A process for the manufacture of ammonia, comprising the steps of (a) feeding a gaseous mixture of hydrogen and nitrogen, or generators thereof in the proportions of about 3 moles hydrogen to 1 mole nitrogen, together with inert gases, into a converter containing catalyst(s) for ammonia synthesis and thereby producing ammonia; (b) conveying the reaction mixture from said converter through an adsorbent to effect adsorption of the formed ammonia together with some inert gases, whereby the adsorbed gases are separated from the unreacted mixture of gases, the latter being recycled to the converter; (c) effecting desorption of ammonia from the ammonia-loaded adsorbent by direct contact of said adsorbent with a concentrated hot stream of ammonia-containing gases comprising hot compressed ammonia refrigerant which is at least as concentrated with ammonia as the hot effluent from the converter; (d) condensing the ammonia eliberated from the adsorbent to liquid ammonia; and wherein the adsorption and desorption steps are carried out in phased order, providing continuous streams of controlled compositions.
Claim 11
Dependent Claim
37 words
A process according to claim 8, wherein a liquid ammonia barrier is used to separate the circulated reactant mixture of gases from the ammonia refrigerant gas, thus substantially eliminating losses of unreacted gases into the refrigeration cycle.
Claim 12
Dependent Claim
35 words
A process according to claim 8, wherein two or more adsorbent beds are utilized to carry out, in parallel, said adsorption and desorption steps in said phased order, providing said continuous streams of controlled compositions.
Claim 13
Dependent Claim
41 words
A process according to claim 8, wherein heat is transferred from the hot regenerant stream to the adsorbent bed to be regenerated and subsequently heat is transferred from the adsorbent bed to the unreacted mixture of gases recycled into the converter.
Claim 14
Dependent Claim
23 words
A process according to claim 8, wherein the adsorbent bed separates simultaneously the ammonia and methane from the gas recycled to the converter.
Claim 15
Dependent Claim
27 words
A process according to claim 12, wherein the gases going out from the adsorbent bed and entering into the converter, comprises substantially pure synthesis gas including argon.
Claim 16
Dependent Claim
20 words
A process according to claim 8, carried out in an existing ammonia plant wherein solid adsorption beds are incorporated therein.
Claim 17
Dependent Claim
20 words
A process according to claim 8 wherein said desorption is carried out at substantially the same pressure as said adsorption.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-26 | 1989-02-25 | 1989-08-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-26 | 1993-02-25 | 1993-08-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-26 | 1997-02-25 | 1997-08-27 | $7700.00 | Window Closed / Lapsed |