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US4536562A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystalline polyesters

Assignee: Solutia Inc
•
Filing: 1985-01-04
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Granted: 1985-08-20
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Expires: 2005-01-04
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Abstract

Abstract Disclosed are liquid crystal copolyesters prepared from p-hydroxybenzoic acid, isophthalic and/or terephthalic acid, hydroquinone, and a mono-substituted hydroquinone wherein the substituent is selected from the group consisting of alkyls of 1 to 6 carbon atoms, phenyl and phenyl substituted with an alkyl of 1 to 6 carbon atoms, chloro, bromo, cyano, formyl, acetyl, and trifluoromethyl, wherein, when a specific amount of the hydroquinone is replaced by a specific substituted hydroquinone, the copolyester not only becomes more tractable but also unexpectedly more crystalline when compared to the unsubstituted copolyester.

Inventors

  • 👤 Oliver D. Deex

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 08:53
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/605; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3804; C09K19/3809

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 223 words
A copolyester capable of forming a thermotropic melt phase and having an inherent viscosity of at least about 0.3 measured at 30° C. with a solution of 0.5 gm of copolyester per 100 m/ of a solvent composed of 60 weight % phenol and 40% tetrachloroethane, consisting essentially of the following divalent radicals: ##STR2## wherein the placements of the carbonyl groups of the B radicals are meta or para or a mixture of meta and para; wherein R is selected from the group consisting of alkyls of 1 to 6 carbon atoms, phenyl and phenyl substituted with an alkyl of 1 to 6 carbon atoms, chloro, bromo, cyano, formyl, acetyl, and trifluoromethyl; wherein the amount of radical A is in the range from about 10 mole % to about 60 mole % of the copolyester and wherein the amount of radical D is selected in the range from about 1 mole % up to about 50 mole % of the total amount of radicals C and D to provide a ratio of storage moduli of said copolyester determined at T g -50° C. and T g +50° C. less than the ratio of the storage moduli determined at T g -50° C. and T g +50° C. of a copolyester of identical composition except that the D radicals are replaced with C radicals.
Claim 2
Dependent Claim 223 words
A copolyester capable of forming a thermotropic melt phase and having an inherent viscosity of at least about 0.3 measured at 30° C. with a solution of 0.5 gm of copolyester per 100 m/ of a solvent composed of 60 weight % phenol and 40% tetrachloroethane, consisting essentially of the following divalent radicals: ##STR2## wherein the placements of the carbonyl groups of the B radicals are meta or para or a mixture of meta and para; wherein R is selected from the group consisting of alkyls of 1 to 6 carbon atoms, phenyl and phenyl substituted with an alkyl of 1 to 6 carbon atoms, chloro, bromo, cyano, formyl, acetyl, and trifluoromethyl; wherein the amount of radical A is in the range from about 10 mole % to about 60 mole % of the copolyester and wherein the amount of radical D is selected in the range from about 1 mole % up to about 50 mole % of the total amount of radicals C and D to provide a ratio of storage moduli of said copolyester determined at T g -50° C. and T g +50° C. less than the ratio of the storage moduli determined at T g -50° C. and T g +50° C. of a copolyester of identical composition except that the D radicals are replaced with C radicals.
Claim 3
Dependent Claim 26 words
The copolyester of claim 1 wherein radical R is selected from the group consisting of alkyls of 1 to 4 carbon atoms, phenyl, methyl, and chloro.
Claim 4
Dependent Claim 18 words
The copolyester of claim 1 wherein radical R is selected from the group consisting of methyl and chloro.
Claim 5
Dependent Claim 34 words
The copolyester of claim 1 wherein the amount of radical D is in the range from about 1 mole % to about 25 mole % of the total amount of radicals C and D.
Claim 6
Dependent Claim 34 words
The copolyester of claim 1 wherein the amount of radical D is in the range from about 5 mole % to about 20 mole % of the total amount of radicals C and D.
Claim 7
Dependent Claim 9 words
The copolyester of claim 1 wherein R is methyl.
Claim 8
Dependent Claim 28 words
The copolyester of claim 1 wherein the amount of radical A is in the range from about 15 mole % to about 40 mole % of the polyester.
Claim 9
Dependent Claim 25 words
The copolyester of claim 1 wherein the amount of radical A is in the range from about 20 mole % to about 35 mole %.
Claim 10
Dependent Claim 14 words
The copolyester of claim 1 wherein the inherent viscosity is at least about 0.5.
Claim 11
Dependent Claim 41 words
The copolyester of claim 1 wherein the ratio of storage moduli of said copolyester is less than 60% of the ratio of the storage moduli of a copolyester of identical composition except that the D radicals are replaced with C radicals.
Claim 12
Dependent Claim 42 words
The copolyester of claim 1 wherein the ratio of the storage moduli of said copolyester is less than 30% of the ratio of the storage moduli of a copolyester of identical composition except that the D radicals are replaced with C radicals.
Claim 13
Dependent Claim 18 words
The copolyester of claim 1 wherein the placements of the carbonyl groups of the B radicals are meta.
Claim 14
Dependent Claim 39 words
The copolyester of claim 12 wherein R is methyl and wherein the amount of radical D is in the range from about 5 mole % to about 20 mole % of the total amount of radicals C and D.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-08-19 1989-02-18 1989-08-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-08-19 1993-02-18 1993-08-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-08-19 1997-02-18 1997-08-20 $7700.00 Window Closed / Lapsed

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