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US4536296A Expired / Lapsed US ⏱️ 0.0 years remaining

Drilling and completion muds useful at elevated temperatures

Assignee: Societe National Elf Aquitaine
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Filing: 1983-03-10
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Granted: 1985-08-20
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Expires: 2003-03-10
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Abstract

Abstract The invention is clay based water drilling or completion muds with low viscosity and exceptional stability at elevated temperatures of up to 200° C. The muds are characterized by containing from 1 to 10 grams per liter of a low molecular weight polymer or copolymer having functional groups wherein from 2 to 95% of the functional groups consist independently of hydroxamic or thiohydroxamic groups. The mud composition comprises (a) fresh water, water containing electrolytes such as sodium chloride, potassium chloride, calcium chloride, magnesium chloride, or seawater; (b) clay, chosen to suit the saline concentration of the water and to provide the necessary properties; and (c) one or more viscosity increasing materials.

Inventors

  • 👤 Lino Vio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 05:08
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 193 words
A clay based aqueous drilling or completion mud comprising clay, density increasing material, viscosity increasing agent, and from 1 to 10 grams per liter of a hydrosoluble polymeric material having pendant groups and a weight average molecular weight not higher than about 40,000, wherein from about 2 to 95% of the pendant groups are independently hydroxamic or thiohydroxamic groups of the formula: ##STR7## wherein X 1 and X 2 are independently oxygen, or sulfur and R and R' are independently hydrogen, alkyl or cycloalkyl having from 1 to about 18 carbon atoms, alkylene and cycloalkylene having from about 2 to 18 carbon atoms, aryl, alkylaryl, arylalkyl, alkoxyaryl, and alkoxyalkyl, having up to two conjugated rings, and having up to about 18 carbon atoms and wherein said polymeric material before the introduction of the hydroxamic or thiohydroxamic groups, is a homopolymer of acrylamide, methacrylamide, alkylacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates, or copolymers of a monomer selected from acrylamide, methacrylamide, alklyacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates and a monomer selected from acrylic acid, alkylacrylic acid, salts of acrylic acid and alkylacrylic acid, esters of acrylic acid and alkylacrylic acid, maleicanhydride, vinylacetate, vinyl pyrrolidone, butadiene, styrene and acrylonitrile.
Claim 2
Dependent Claim 193 words
A clay based aqueous drilling or completion mud comprising clay, density increasing material, viscosity increasing agent, and from 1 to 10 grams per liter of a hydrosoluble polymeric material having pendant groups and a weight average molecular weight not higher than about 40,000, wherein from about 2 to 95% of the pendant groups are independently hydroxamic or thiohydroxamic groups of the formula: ##STR7## wherein X 1 and X 2 are independently oxygen, or sulfur and R and R' are independently hydrogen, alkyl or cycloalkyl having from 1 to about 18 carbon atoms, alkylene and cycloalkylene having from about 2 to 18 carbon atoms, aryl, alkylaryl, arylalkyl, alkoxyaryl, and alkoxyalkyl, having up to two conjugated rings, and having up to about 18 carbon atoms and wherein said polymeric material before the introduction of the hydroxamic or thiohydroxamic groups, is a homopolymer of acrylamide, methacrylamide, alkylacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates, or copolymers of a monomer selected from acrylamide, methacrylamide, alklyacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates and a monomer selected from acrylic acid, alkylacrylic acid, salts of acrylic acid and alkylacrylic acid, esters of acrylic acid and alkylacrylic acid, maleicanhydride, vinylacetate, vinyl pyrrolidone, butadiene, styrene and acrylonitrile.
Claim 3
Dependent Claim 17 words
The mud of claim 1 wherein the polymeric material has a molecular weight less than about 20,000.
Claim 4
Dependent Claim 18 words
The mud of claim 1 wherein the polymeric material has a molecular weight between about 1,000 and 20,000.
Claim 5
Dependent Claim 18 words
The mud of claim 1 wherein the polymeric material has a molecular weight between about 1200 and 6000.
Claim 6
Dependent Claim 41 words
Drilling muds as defined in claim 1, in which the dispersant is obtained by the reaction of hydroxylamine hydrochloride with an aqueous solution or inverse emulsion of polyacrylamide, with a molecular weight lower than 20,000 in the presence of sodium acetate.
Claim 7
Dependent Claim 65 words
Drilling muds as defined in claim 1, in which the dispersant is obtained by the reaction of an aqueous solution or inverse emulsion of a polyacrylamide, with a molecular weight lower than 20,000, with a hydroxylamine hydrochloride, at a temperature of 90° C., alkali metal or alkaline earth-metal hydroxide being used to adjust the pH value of the reaction mixture to between 5 and 7.5.
Claim 8
Dependent Claim 13 words
The mud of claim 1 wherein the pendant group is a hydroxamic group.
Claim 9
Dependent Claim 17 words
The mud of claim 7 wherein the polymeric material has a molecular weight less than about 20,000.
Claim 10
Dependent Claim 18 words
The mud of claim 7 wherein the polymeric material has a molecular weight between about 1,000 and 20,000.
Claim 11
Dependent Claim 18 words
The mud of claim 7 wherein the polymeric material has a molecular weight between about 1200 and 6000.
Claim 12
Dependent Claim 26 words
A mud of claim 7 wherein the polymeric material is a polyhydroxamic acid wherein from about 5 to 65% of the pendant groups are hydroxamic groups.
Claim 13
Dependent Claim 26 words
A mud of claim 8 wherein the polymeric material is a polyhydroxamic acid wherein from about 5 to 65% of the pendant groups are hydroxamic groups.
Claim 14
Dependent Claim 26 words
A mud of claim 9 wherein the polymeric material is a polyhydroxamic acid wherein from about 5 to 65% of the pendant groups are hydroxamic groups.
Claim 15
Dependent Claim 26 words
A mud of claim 10 wherein the polymeric material is a polyhydroxamic acid wherein from about 5 to 65% of the pendant groups are hydroxamic groups.
Claim 16
Dependent Claim 20 words
A mud of claim 10 wherein the polymeric material is a polyhydroxamic acid containing about 5 to 50% hydroxamic groups.

References Cited (Backward Citations)

CA543543A Cited
CA553011A Cited
US2718497A Cited
US2979454A Cited
US2959574A Cited
US3764530A Cited
US3730900A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-08-19 1989-02-18 1989-08-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-08-19 1993-02-18 1993-08-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-08-19 1997-02-18 1997-08-20 $7700.00 Window Closed / Lapsed

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