Patent US4536189A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4536189A Expired / Lapsed US ⏱️ 0.0 years remaining

Corrosion inhibitor and motor fuel composition containing the same

Assignee: Texaco Inc
•
Filing: 1984-04-27
•
Granted: 1985-08-20
•
Expires: 2004-04-27
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract An anti-corrosion additive composition for motor fuels containing a minor amount (i.e., from 1 to 10%) of a short chain aliphatic alcohol that is prepared by reacting substantially equal molar amounts of maleic anhydride and a hydrocarbon-substituted mono primary amine or hydrocarbon-substituted mono primary ether amine to produce a maleamic acid intermediate reaction product followed by (b) reacting said intermediate product of (a) with a substantially equal molar amount of a heterocyclic selected from the group consisting of 5-amino-1,3,4-thiadiazole-2-thiol or benzotriazole, said hydrocarbon-substituted mono primary amine being represented by the formula: R--NH.sub.2 in which R is a monovalent hydrocarbyl radical having from about 6 to about 20 carbon atoms or a hydrocarbyl aminoalkylene radical in which the hydrocarbyl group has from 6 to about 20 carbon atoms and in which the divalent alkylene group has from 2 to 3 carbon atoms, and said hydrocarbon-substituted mono primary ether amine being represented by the formula: ##STR1## in which R is a hydrocarbyl radical having from about 6 to about 20 carbon atoms and when y is 0, x is 1 and n is an integer from 1 to 4 and when x is 0, y has a value of 1 to 10.

Inventors

  • 👤 Rodney L. Sung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:49
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/24; C10L1/2443; C10L1/2456; C10L1/18; C10L1/182; C10L1/1822; C10L1/1824

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 199 words
A novel composition prepared by (a) reacting substantially equal molar amounts of maleic anhydride and a hydrocarbon-substituted mono primary amine or a hydrocarbon-substituted mono primary ether amine at a temperature ranging from 75 to 150 C. to produce a maleamic acid intermediate reaction product, and (b) reacting said intermediate product of (a) with a substantially equal molar amount of a heterocyclic compound selected from the group consisting of 5-amino-1,3,4,-thiadiazole-2-thiol and benzotriazole at an elevated temperature to produce said composition, said hydrocarbon-substituted mono primary amine being represented by a formula: R--NH.sub.2 in which R is a monovalent hydrocarbyl radical having from about 6 to about 20 carbon atoms or a hydrocarbyl aminoalkylene radical in which the hydrocarbyl group has from 6 to about 20 carbon atoms and in which the divalent alkylene group has from about 2 to 3 carbon atoms, and said hydrocarbon-substituted mono primary ether amine being represented by the formula: ##STR4## in which R is a hydrocarbyl radical having from about 6 to about 20 carbon atoms and when y is 0, x is 1 and n is an integer from 1 to 4 and when x is 0, y has a value of 1 to 10.
Claim 2
Dependent Claim 199 words
A novel composition prepared by (a) reacting substantially equal molar amounts of maleic anhydride and a hydrocarbon-substituted mono primary amine or a hydrocarbon-substituted mono primary ether amine at a temperature ranging from 75 to 150 C. to produce a maleamic acid intermediate reaction product, and (b) reacting said intermediate product of (a) with a substantially equal molar amount of a heterocyclic compound selected from the group consisting of 5-amino-1,3,4,-thiadiazole-2-thiol and benzotriazole at an elevated temperature to produce said composition, said hydrocarbon-substituted mono primary amine being represented by a formula: R--NH.sub.2 in which R is a monovalent hydrocarbyl radical having from about 6 to about 20 carbon atoms or a hydrocarbyl aminoalkylene radical in which the hydrocarbyl group has from 6 to about 20 carbon atoms and in which the divalent alkylene group has from about 2 to 3 carbon atoms, and said hydrocarbon-substituted mono primary ether amine being represented by the formula: ##STR4## in which R is a hydrocarbyl radical having from about 6 to about 20 carbon atoms and when y is 0, x is 1 and n is an integer from 1 to 4 and when x is 0, y has a value of 1 to 10.
Claim 3
Dependent Claim 24 words
The composition of claim 1 wherein R in said hydrocarbon-substituted mono primary amine is an aliphatic radical having from 10 to 18 carbon atoms.
Claim 4
Dependent Claim 27 words
A motor fuel composition containing a major amount of hydrocarbons boiling in the gasoline boiling range and an effective amount of the anti-corrosion additive of claim 1.
Claim 5
Dependent Claim 16 words
A fuel composition as claimed in claim 3, wherein said fuel consists essentially of a gasoline.
Claim 6
Dependent Claim 22 words
A fuel composition as claimed in claim 3, wherein said fuel additionally contains from 1 to 10% of a short chain alcohol.
Claim 7
Dependent Claim 24 words
A fuel composition as claimed in claim 5, wherein the alcohols are selected from the group consisting of methanol, ethanol, propanol, butanol, and t-butanol.
Claim 8
Dependent Claim 29 words
The composition of claim 3, wherein said anti-corrosion reaction product is present in an amount ranging from about 5 to about 50 lbs. per thousand barrels of fuel mixture.

References Cited (Backward Citations)

US3791803A Cited
US4348210A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-08-19 1989-02-18 1989-08-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-08-19 1993-02-18 1993-08-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-08-19 1997-02-18 1997-08-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag