Patent US622487A successfully refreshed from Google Patents.
Patent US4535056A successfully refreshed from Google Patents.
US4535056A
Expired / Lapsed
US
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Yellow color formers for use in color photothermographic system
Assignee: Eastman Kodak Co
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Filing: 1984-03-15
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Granted: 1985-08-13
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Expires: 2004-03-15
Abstract
Abstract A photographic construction comprises at least one spectrally-sensitized polymeric binder layer containing photographic silver halide and, in association therewith a. a non-light sensitive organic silver salt oxidizing agent, b. at least one biphenol color-forming reducing agent having the formula ##STR1## wherein each R is independently selected from a straight chain or branched alkyl or alkoxy group having 1 to 6 carbon atoms, and phenyl, and R 1 is hydrogen or an alkalilabile protecting group, and c. at least one aliphatic or aromatic carboxylic acid of a specific class, which preferably is p-aminobenzoic acid, as development modifier, and d. optionally, at least one toner.
Inventors
- 👤 Robert A. Frenchik
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 18:53
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/494; G03C1/498; G03C1/49827
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
205 words
A photographic construction comprising at least one polymeric binder layer containing spectrally-sensitized photographic silver halide and, in association therewith a. a non-light sensitive organic silver salt oxidizing agent, b. at least one biphenol color-forming reducing agent having the formula ##STR11## wherein each R is independently selected from a straight chain or branched alkyl or alkoxy group having 1 to 6 carbon atoms, and phenyl, and R 1 is hydrogen or an alkali-labile protecting group, and c. at least one aliphatic or aromatic carboxylic acid as development modifier, the acid having the formula R(COOH).sub.x wherein x is an integer having the value 1 or 2, R is a group which is unsubstituted or substituted by at least one group selected from amino, hydroxyl, lower alkyl (C 1 to C 4 ), nitro, and one or two chloro atoms, wherein when x is 1, R is selected from the group consisting of alkenyl, aryl, and phenylalkyl, having up to 10 carbon atoms, and when x is 2, R is selected from the group consisting of alkenylene, alkylene, and arylene, having up to 14 carbon atoms; and d. optionally, at least one toner; said polymeric binder layer being capable of providing a yellow to gold color upon development.
Claim 2
Dependent Claim
205 words
A photographic construction comprising at least one polymeric binder layer containing spectrally-sensitized photographic silver halide and, in association therewith a. a non-light sensitive organic silver salt oxidizing agent, b. at least one biphenol color-forming reducing agent having the formula ##STR11## wherein each R is independently selected from a straight chain or branched alkyl or alkoxy group having 1 to 6 carbon atoms, and phenyl, and R 1 is hydrogen or an alkali-labile protecting group, and c. at least one aliphatic or aromatic carboxylic acid as development modifier, the acid having the formula R(COOH).sub.x wherein x is an integer having the value 1 or 2, R is a group which is unsubstituted or substituted by at least one group selected from amino, hydroxyl, lower alkyl (C 1 to C 4 ), nitro, and one or two chloro atoms, wherein when x is 1, R is selected from the group consisting of alkenyl, aryl, and phenylalkyl, having up to 10 carbon atoms, and when x is 2, R is selected from the group consisting of alkenylene, alkylene, and arylene, having up to 14 carbon atoms; and d. optionally, at least one toner; said polymeric binder layer being capable of providing a yellow to gold color upon development.
Claim 3
Dependent Claim
12 words
The photographic construction according to claim 1 wherein R 1 is hydrogen.
Claim 4
Dependent Claim
19 words
The photographic construction according to claim 1 wherein R is selected from the group consisting of methyl and tert-butyl.
Claim 5
Dependent Claim
20 words
The photographic construction according to claim 1 wherein said biphenol is selected from the group consisting of 2,2,6,6'-tetramethylbiphenol and 2,2'-dimethyl-6,6'-di(tert-butyl)-4,4'-biphenol.
Claim 6
Dependent Claim
15 words
The photographic construction according to claim 1 wherein said development modifier is an aromatic acid.
Claim 7
Dependent Claim
23 words
The photographic construction according to claim 1 wherein said development modifier is selected from the group consisting of amino- and nitro-substituted aromatic acids.
Claim 8
Dependent Claim
52 words
The photographic construction according to claim 1 wherein said development modifier is selected from the group consisting of p-aminobenzoic acid, phthalic acid, 3- or 4-nitrophthalic acid, benzoic acid, maleic acid, dichlormaleic acid, succinic acid, suberic acid, cinnamic acid, nitrocinnamic acid, 3- or 4-methylphthalic acid, 3,5-diaminobenzoic acid, and 4-aminosalicylic acid, and 2,3-naphthalenedicarboxylic acid.
Claim 9
Dependent Claim
14 words
The photographic construction according to claim 7 wherein said development modifier is p-aminobenzoic acid.
Claim 10
Dependent Claim
26 words
The photographic construction according to claim 1 wherein said reducing agent is present in the range of 0.5 to 5 weight percent of the coating solution.
Claim 11
Dependent Claim
21 words
The photographic construction according to claim 1 wherein said construction has a Δ density in the range of 0.3 to 1.8.
Claim 12
Dependent Claim
26 words
The photographic construction according to claim 1 wherein said development modifier is present in the range of 0.01 to 2.0 weight percent of the coating solution.
Claim 13
Dependent Claim
26 words
The photographic construction according to claim 11 wherein said development modifier is present in the range of 0.2 to 1.0 weight percent of the coating solution.
Claim 14
Dependent Claim
23 words
The photographic construction according to claim 1 wherein said toner is selected from the group consisting of phthalazine, phthalazinone, imidazole, phthalimide, and N-aminophthalimide.
Claim 15
Dependent Claim
12 words
The photographic construction according to claim 12 wherein said toner is phthalazine.
Claim 16
Dependent Claim
26 words
The photographic construction according to claim 1 wherein said toner is present in the range of 5.0 to 50 mg per 100 g of coating solution.
Claim 17
Dependent Claim
41 words
The photographic construction according to claim 1 wherein the combination of said toner and development modifier are selected from the group consisting of (1) phthalazine and phthalic acid, (2) phthalazine and p-aminobenzoic acid, and (3) phthalazine, phthalic acid, and p-aminobenzoic acid.
References Cited (Backward Citations)
US4021250A
Cited
US3985565A
Cited
US4021240A
Cited
US4260677A
Cited
GB2075496A
Cited
US4374921A
Cited
US4531286A
Cited
US4460681A
Cited
US4452883A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-12 | 1989-02-11 | 1989-08-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-12 | 1993-02-11 | 1993-08-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-12 | 1997-02-11 | 1997-08-13 | $7700.00 | Window Closed / Lapsed |