US4534879A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Synthetic surfactant flakes and process for making them
Assignee: Procter and Gamble Co
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Filing: 1984-06-27
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Granted: 1985-08-13
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Expires: 2004-06-27
Abstract
Abstract A process for making improved synthetic surfactant flakes from a water-wet paste which is dried on a heated roll drum dryer. Hot surfactant flakes are made from drum drying a water-wet paste containing sodium alkyl sulfate (AS), sodium alkyl benzene sulfonate (LAS), and water-soluble inorganic salts, preferably sodium chloride and magnesium chloride blends. The hot flakes are cooled in a low moisture environment having a dewpoint of up to 10 DEG C., e.g., under a dry nitrogen or dry air blanket. The low moisture environment prevents undesirable, insidious hydration and stabilizes the AS/LAS flakes. The stable AS/LAS surfactant flakes can be used to make more economical, more processable, firmer improved surfactant cakes. One advantage is that cakes made with the flakes of this invention can contain larger amounts of perfume than cakes made with comparable AS/LAS flakes cooled above said dewpoint.
Inventors
- 👤 Stephen H. Iding
- 👤 Robert H. Callicott
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:20
CPC Classifications
C; C11; C11D; C11D11/00; C11D11/0082; C11D1/00; C11D1/02; C11D1/37; C11D17/00; C11D17/06; C11D3/00; C11D3/50; C11D1/12; C11D1/14; C11D1/22; Y; Y10; Y10S; Y10S159/00; Y10S159/14
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
187 words
A process for making improved surfactant flakes from a water-wet paste which is dried on a heated roll drum dryer comprising the steps of: A. Forming a 25° C. to 95° C. water-wet paste containing: (a) From 20% to 30% of an alkali metal C 9 -C 15 alkyl sulfate; (b) From 20% to 30% of an alkali metal C 9 -C 15 alkyl benzene sulfonate, wherein said (a) and (b) have a weight ratio of 1:1.5 to 1.5:1; (c) From 0.5% to 10% of a water-soluble inorganic salt; and (d) The balance water; B. Forming heat dried flakes from said paste on said heated roll drum dryer, said flakes having a thickness of 0.1 mm to 1.3 mm and a moisture content of up to about 1.2%; C. Cooling the flakes to about ambient temperature in a controlled environment having a dewpoint of less than about 10° C.; wherein said improved surfactant flakes can carry a larger amount of perfume in a firm cake than a comparable cake made from flakes cooled above said dewpoint; and wherein said firm cake contains from 5% to 20% perfume.
Claim 2
Dependent Claim
187 words
A process for making improved surfactant flakes from a water-wet paste which is dried on a heated roll drum dryer comprising the steps of: A. Forming a 25° C. to 95° C. water-wet paste containing: (a) From 20% to 30% of an alkali metal C 9 -C 15 alkyl sulfate; (b) From 20% to 30% of an alkali metal C 9 -C 15 alkyl benzene sulfonate, wherein said (a) and (b) have a weight ratio of 1:1.5 to 1.5:1; (c) From 0.5% to 10% of a water-soluble inorganic salt; and (d) The balance water; B. Forming heat dried flakes from said paste on said heated roll drum dryer, said flakes having a thickness of 0.1 mm to 1.3 mm and a moisture content of up to about 1.2%; C. Cooling the flakes to about ambient temperature in a controlled environment having a dewpoint of less than about 10° C.; wherein said improved surfactant flakes can carry a larger amount of perfume in a firm cake than a comparable cake made from flakes cooled above said dewpoint; and wherein said firm cake contains from 5% to 20% perfume.
Claim 3
Dependent Claim
29 words
The invention of claim 1 wherein said paste contains a buffer to maintain a paste pH of from 7 to 9.5 in a 1% solids solution at ambient temperature.
Claim 4
Dependent Claim
29 words
The invention of claim 1 wherein said roll drum dryer has a temperature of 140° C. to 190° C. and wherein said dewpoint is from 0° to 4° C.
Claim 5
Dependent Claim
17 words
The invention of claim 1 wherein heat dried flakes are cooled under a blanket of dry nitrogen.
Claim 6
Dependent Claim
28 words
The invention of claim 1 wherein said heat dried flakes are cooled under a blanket of dry air and wherein the dewpoint is from 0° to 4° C.
Claim 7
Dependent Claim
23 words
The invention of claim 1 wherein said wet paste of step (A) is concentrated to 50% to 70% solids for ease of handling.
Claim 8
Dependent Claim
20 words
The invention of claim 1 wherein said alkyl sulfate and said alkyl benzene sulfonate have a ratio of about 1:1.
Claim 9
Dependent Claim
29 words
The invention of claim 1 wherein said inorganic salt includes sodium chloride which is present in the dried flakes at a level of from about 6% to about 8%.
Claim 10
Dependent Claim
30 words
The invention of claim 1 wherein said wet paste is heated to a temperature of 38° C. to 66° C. and concentrated to a moisture level of 30% to 40%.
Claim 11
Dependent Claim
33 words
The invention of claim 1 wherein said heated roll drum dryer has a temperature of 150° C. to 175° C. and said flakes have a moisture content of from about 0.5 to 0.8.
Claim 12
Dependent Claim
26 words
The invention of claim 1 wherein the flakes have a thickness of 0.2 mm to 0.6 mm, and a moisture content of about 0.5% to 0.8%.
Claim 13
Dependent Claim
44 words
The invention of claim 1 wherein said flakes are mixed with from 5% to 20% perfume, 0.5% to 12% dye, and from 0% to 30% water-soluble inorganic salts, plodded, extruded, and formed into cakes having a hardness penetrometer value of from 40 to 100.
Claim 14
Dependent Claim
24 words
The invention of claim 12 wherein cake has 9% to 20% perfume and a total inorganic salt content of about 15% to about 30%.
Claim 15
Dependent Claim
26 words
The invention of claim 1 wherein said paste is passed through a pre-dryer to reduce the moisture content of the paste to about 30% to 50%.
Claim 16
Dependent Claim
176 words
Improved surfactant flakes comprising on a weight percentage basis of from about 38% to about 52% sodium C 9 -C 15 alkyl sulfate (AS), from 33% to 47% sodium C 9 -C 15 alkyl benzene sulfonate (LAS), from about 0.5% to about 10% water-soluble inorganic salt and less than about 1.2% moisture, said surfactant flakes being made by: A. Forming a 26° C. to 93° C. water-wet paste of said AS, LAS and said salt, said paste having a water content of from 40% to 60%; B. Forming heat dried flakes from said water-wet paste on a heated roll drum dryer, said flakes having a thickness of from 0.1 mm to 1.3 mm; C. Cooling the heat dried flakes to about ambient temperature in a controlled environment having a dewpoint of less than about 10° C.; wherein said improved surfactant flakes can carry a larger amount of perfume when in a firm cake form than a comparable cake made from flakes cooled above said dewpoint; and wherein said firm cake contains from 5% to 20% perfume.
Claim 17
Dependent Claim
176 words
Improved surfactant flakes comprising on a weight percentage basis of from about 38% to about 52% sodium C 9 -C 15 alkyl sulfate (AS), from 33% to 47% sodium C 9 -C 15 alkyl benzene sulfonate (LAS), from about 0.5% to about 10% water-soluble inorganic salt and less than about 1.2% moisture, said surfactant flakes being made by: A. Forming a 26° C. to 93° C. water-wet paste of said AS, LAS and said salt, said paste having a water content of from 40% to 60%; B. Forming heat dried flakes from said water-wet paste on a heated roll drum dryer, said flakes having a thickness of from 0.1 mm to 1.3 mm; C. Cooling the heat dried flakes to about ambient temperature in a controlled environment having a dewpoint of less than about 10° C.; wherein said improved surfactant flakes can carry a larger amount of perfume when in a firm cake form than a comparable cake made from flakes cooled above said dewpoint; and wherein said firm cake contains from 5% to 20% perfume.
Claim 18
Dependent Claim
19 words
The invention of claim 15 wherein said AS and LAS have a weight ratio of from 0.8:1 to 1:0.8.
Claim 19
Dependent Claim
11 words
The invention of claim 16 wherein said ratio is about 1:1.
Claim 20
Dependent Claim
27 words
The invention of claim 15 wherein said water-soluble inorganic salt is present in said flake at a level of from about 6% to about 10% by weight.
Claim 21
Dependent Claim
16 words
The invention of claim 15 wherein said flake thickness is from 0.2 mm to 0.6 mm.
Claim 22
Dependent Claim
26 words
The invention of claim 15 wherein said flakes are made on a roll drum dryer which has a temperature of from 140° C. to 190° C.
Claim 23
Dependent Claim
17 words
The invention of claim 20 wherein said roll drum dryer temperature is 150° C. to 175° C.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-12 | 1989-02-11 | 1989-08-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-12 | 1993-02-11 | 1993-08-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-12 | 1997-02-11 | 1997-08-13 | $7700.00 | Window Closed / Lapsed |