Abstract The instant invention relates to a membrane solvent extraction and reaction system. More particularly it pertains to an improvement in the membrane solvent extraction system wherein a solute is extracted through a polymeric membrane from one solvent liquid phase to an extracting solvent liquid without direct contact between the liquid phases which are separated by the membrane and in which the extracting solvent has no greater solubility and usually substantially less solubility for the solute than the feed solvent. The impovement comprises converting the solute permeating across the membrane to a different chemical compound, whereby a high concentration gradient for the solute across the membrane is maintained to improve the separation of the solute from the feed solvent liquid phase. This improved process is particularly useful for the separation of partially oxygenated hydrocarbons from admixture with hydrocarbons and conversion of the permeating oxygenated hydrocarbons by oxidation in an extracting aqueous solvent containing an oxidizing agent, and in which extracting solvent the oxygenated hydrocarbon solute is less soluble than in the hydrocarbon solvent. This process is especially useful for the separation of the oxidation products of cyclohexane, e.g., cyclohexanol and cyclohexanone, by permeation through a hydrophilic membrane, e.g., fluorocarbon polymers containing pendant sulfonic acid and/or carboxylic acid groups and the salts thereof, into an aqueous solvent comprising an oxidant, e.g., nitric acid. In this embodiment, the oxidation products of cyclohexane may be continuously separated from unoxidized cyclohexane and converted into adipic acid.
In a process for membrane solvent extraction wherein a solute permeates through a polymeric membrane from a feed solvent liquid phase containing said solute to an extracting solvent liquid without direct contact betweeen the liquid phases which are separated by said membrane, the improvement which comprises maintaining a high concentration gradient for said solute across said membrane with an extracting solvent which has no greater solubility for the solute than said feed solvent by converting said solute permeating through said membrane to a different chemical compound by reacting the permeated solute with a reactant which is reactive with said solute but which is essentially non-reactive with said membrane and said solvents, thereby improving the separation of said solute from said feed solvent liquid phase.
Claim 2
Dependent Claim
124 words
In a process for membrane solvent extraction wherein a solute permeates through a polymeric membrane from a feed solvent liquid phase containing said solute to an extracting solvent liquid without direct contact betweeen the liquid phases which are separated by said membrane, the improvement which comprises maintaining a high concentration gradient for said solute across said membrane with an extracting solvent which has no greater solubility for the solute than said feed solvent by converting said solute permeating through said membrane to a different chemical compound by reacting the permeated solute with a reactant which is reactive with said solute but which is essentially non-reactive with said membrane and said solvents, thereby improving the separation of said solute from said feed solvent liquid phase.
Claim 3
Dependent Claim
24 words
The process of claim 1 wherein said extracting solvent liquid phase has substantially less solubility for said solute than said feed solvent liquid phase.
Claim 4
Dependent Claim
48 words
The process of claim 1 wherein said solute and feed solvent are partially oxygenated hydrocarbon and hydrocarbon, respectively, said extracting solvent is an aqueous solvent and in said conversion said permeated partially oxygenated hydrocarbon is oxidized to a higher oxygenated state by an oxidant in said extracting solvent.
Claim 5
Dependent Claim
34 words
The process of claim 3 wherein said partially oxygenated hydrocarbons are selected from the group consisting of alcohols, ketones and mixtures thereof and said more highly oxygenated hydrocarbons are carboxylic acids and mixtures thereof.
Claim 6
Dependent Claim
27 words
The process of claim 3 wherein the product of said oxidation is more soluble in said aqueous solvent than said partially oxidized hydrocarbon in said aqueous solvent.
Claim 7
Dependent Claim
26 words
The process of claim 3 wherein said solute and feed solvent together form a liquid phase admixture obtained from liquid phase air oxidation of aliphatic hydrocarbon.
Claim 8
Dependent Claim
16 words
The process of claim 6 wherein said admixture consists essentially of cyclohexanone and cyclohexanol in cyclohexane.
Claim 9
Dependent Claim
23 words
The process of claim 7 wherein said extracting solvent is an aqueous solvent containing an oxidant selected from nitric acid and chromic acid.
Claim 10
Dependent Claim
11 words
The process of claim 7, wherein said oxidant is nitric acid.
Claim 11
Dependent Claim
16 words
The process of claim 7 wherein said extracting solvent is an aqueous solution of chromic acid.