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US4530924A
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Phthalocyanine compounds and anti-microbial use
Assignee: BASF Corp
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Filing: 1981-10-30
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Granted: 1985-07-23
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Expires: 2001-10-30
Abstract
Abstract A process for combating micro-organisms in or on organic or inorganic substrates and for protecting the said substrates against attack by micro-organisms, which comprises treating the substrates with a water-soluble phthalocyanine derivative, in the presence of oxygen and water and while irradiating with light in the infra-red and/or visible range, antimicrobical agents containing water-soluble phthalocyanine compounds as well as new phthalocyanine compounds are described.
Inventors
- 👤 Rudolf Polony
- 👤 Gerhard Reinert
- 👤 Gerd Holzle
- 👤 Andre Pugin
- 👤 Rodolphe Vonderwahl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 21:58
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/48; A; A01; A01N; A01N43/00; A01N43/90; A01N47/00; A01N47/08; A01N47/28; A01N47/40; A01N47/42; A61; A61P; A61P31/00; A61P31/04; A61P31/12; C09; C09B; C09B47/00; C09B47/04; C09B47/045; C09B47/08; C09B47/24; C09B47/26; C11D3/0005; C11D3/0063; D; D06; D06M; D06M16/00; Y; Y02; Y02W; Y02W10/00; Y02W10/30; Y02W10/37
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
240 words
A phthalocyanine compound of the formula Me'(PC--(R).sub.v in which PC is the phthalocyanine ring system, v has any desired value between 1 and 4, Me' is Na, K, Ca, or AlX, in which X is an anion and R is a group of the formula ##STR41## in which Y is hydrogen or an alkali metal, ammonium or amine ion, R 7 ' is a hydrogen or alkyl having 1 to 4 carbon atoms, n' is an integer from 2 to 6, R 1 and R 2 independently of one another are hydrogen, a sulpho group and salts thereof, a carboxyl group and salts thereof or a hydroxyl group and at least one of the radicals R 1 and R 2 is a sulpho or carboxyl group or a salt thereof, and R 3 and R 4 independently of one another are hydrogen, alkyl, hydroxyalkyl, cyanoalkyl, sulphoalkyol, carboxyalkyl or halogenalkyl, having, in each case, 1 to 6 carbon atoms, or unsubstituted phen or phenyl substituted by halogen, alkyl or alkoxy having 1 to 4 carbon atoms, sulpho or carboxyl or R 3 and R 4 together with the nitrogen atom to which they are bonded are a saturated 5-membered or 6-membered heterocyclic ring which additionally can also contain a nitrogen atom or oxygen atom as a ring member, and the radicals R are bonded to the phenyl nuclei of the phthalocyanine ring system and can be identical or different, when v>1.
Claim 2
Dependent Claim
240 words
A phthalocyanine compound of the formula Me'(PC--(R).sub.v in which PC is the phthalocyanine ring system, v has any desired value between 1 and 4, Me' is Na, K, Ca, or AlX, in which X is an anion and R is a group of the formula ##STR41## in which Y is hydrogen or an alkali metal, ammonium or amine ion, R 7 ' is a hydrogen or alkyl having 1 to 4 carbon atoms, n' is an integer from 2 to 6, R 1 and R 2 independently of one another are hydrogen, a sulpho group and salts thereof, a carboxyl group and salts thereof or a hydroxyl group and at least one of the radicals R 1 and R 2 is a sulpho or carboxyl group or a salt thereof, and R 3 and R 4 independently of one another are hydrogen, alkyl, hydroxyalkyl, cyanoalkyl, sulphoalkyol, carboxyalkyl or halogenalkyl, having, in each case, 1 to 6 carbon atoms, or unsubstituted phen or phenyl substituted by halogen, alkyl or alkoxy having 1 to 4 carbon atoms, sulpho or carboxyl or R 3 and R 4 together with the nitrogen atom to which they are bonded are a saturated 5-membered or 6-membered heterocyclic ring which additionally can also contain a nitrogen atom or oxygen atom as a ring member, and the radicals R are bonded to the phenyl nuclei of the phthalocyanine ring system and can be identical or different, when v>1.
Claim 3
Dependent Claim
56 words
A phthalocyanine compound according to claim 1, of the formula ##STR42## in which R 3 ' and R 4 ' independently of one another are hydrogen, phenyl, sulphophenyl, carboxyphenyl or alkyl, hydroxyalkyl, cyanoalkyl, sulphoalkyl, carboxyalkyl or halogenoalkyl having, in each case, 1 to 6 carbon atoms, or together with the nitrogen atom are the morpholine ring.
Claim 4
Dependent Claim
19 words
A phthalocyanine compound of the formula defined in either of claims 1 and 2, in which Me is Al(X).
Claim 5
Dependent Claim
20 words
A phthalocyanine compound according to claim 1, of the formula Me'(PC--(SO.sub.3 Y).sub.v' in which v' is between 1.5 and 4.
Claim 6
Dependent Claim
41 words
A phthalocyanine compound according to claim 4, of the formula AlX'(PC--(SO.sub.3 Y).sub.v' in which X' is an anion from the group consisting of OH - , SO 4 2- , Cl - , Br - and CH 3 COO - .
Claim 7
Dependent Claim
20 words
A phthalocyanine compound according to claim 5, of the formula AlCl(PC--(SO.sub.3 Y").sub.v' in which Y" is hydrogen, sodium or potassium.
Claim 8
Dependent Claim
16 words
A composition comprising an antimicrobial amount of a phthalocyanine compound of claim 1 and a carrier.
Claim 9
Dependent Claim
17 words
A composition of claim 7, which contains a detergent as carrier or which further contains a detergent.
Claim 10
Dependent Claim
26 words
A composition of claim 8, wherein the phthalocyanine compound is 0.0005 to 1.5% by weight of the total composition, and wherein R is --SO 3 Y.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-22 | 1989-01-21 | 1989-07-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-22 | 1993-01-21 | 1993-07-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-22 | 1997-01-21 | 1997-07-23 | $7700.00 | Window Closed / Lapsed |