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US4528341A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester and its use in powder coating

Assignee: Covestro Resins BV
•
Filing: 1984-08-08
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Granted: 1985-07-09
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Expires: 2004-08-08
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Abstract

Abstract An improved carboxyl-group-containing polyester resin composition as described of an aromatic carboxylic acid and an aliphatic diol having the following combination of properties: (a) an acid number between 10 and 26 mg KOH/g, (b) a hydroxyl number that is smaller than 15 mg KOH/g, (c) a theoretical number-average molecular weight between 4,500 and 12,500 and (d) a glass transistion temperature between 40° and 85° C.

Inventors

  • 👤 Eimbert G. Belder
  • 👤 Robert van der Linde
  • 👤 Jan Schippers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:44
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/20; C09; C09D; C09D167/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 104 words
A powder coating wherein the binding agent is composed of a homogeneous mixture of a tri-epoxy compound and a polyester containing carboxyl groups, wherein said mixture contains between 1.4 and 5.3 wt. % of a tri-epoxy compound, and from 94.7 to 98.6 wt. % of a polyester of an aromatic dicarboxylic acid and an aliphatic diol having the following combination of properties: (a) an acid number between 10 and 26 mg KOH/g, (b) a hydroxyl number that is smaller than 15 mg KOH/g, (c) a theoretical number-average molecular weight between 4,500 and 12,500 and (d) a glass transition temperature between 40° and 85° C.
Claim 2
Dependent Claim 104 words
A powder coating wherein the binding agent is composed of a homogeneous mixture of a tri-epoxy compound and a polyester containing carboxyl groups, wherein said mixture contains between 1.4 and 5.3 wt. % of a tri-epoxy compound, and from 94.7 to 98.6 wt. % of a polyester of an aromatic dicarboxylic acid and an aliphatic diol having the following combination of properties: (a) an acid number between 10 and 26 mg KOH/g, (b) a hydroxyl number that is smaller than 15 mg KOH/g, (c) a theoretical number-average molecular weight between 4,500 and 12,500 and (d) a glass transition temperature between 40° and 85° C.
Claim 3
Dependent Claim 17 words
A polyester according to claim 1, wherein said acid number is between 12 and 24 mg KOH/g.
Claim 4
Dependent Claim 17 words
A polyester according to claim 1 wherein said hydroxyl number is 5 mg KOH/g at a maximum.
Claim 5
Dependent Claim 17 words
A polyester according to claim 1, wherein said theoretical number-average molecular weight is between 5,000 and 10,000.
Claim 6
Dependent Claim 20 words
A polyester according to claim 1, wherein said glass transition temperature of the polyester is between 50° and 70° C.
Claim 7
Dependent Claim 19 words
A polyester according to claim 1, wherein said average carboxyl functionality of the polyester is between 2 and 3.
Claim 8
Dependent Claim 19 words
A polyester according to claim 1, wherein said average carboxyl functionality of the polyester is between 2.2 and 2.8.
Claim 9
Dependent Claim 24 words
A polyester according to claim 1, wherein said dicarboxylic acid mixture consists of at least 50 wt. % of isophthalic acid and/or terephthalic acid.
Claim 10
Dependent Claim 24 words
A polyester according to claim 1, wherein said dicarboxylic acid mixture consists of at least 70 mol. % of isophthalic acid and/or terephthalic acid.
Claim 11
Dependent Claim 24 words
A polyester according to claim 1, wherein said aliphatic diol mixture consists of at least 50 mol. % of neopentyl glycol and propylene glycol.
Claim 12
Dependent Claim 28 words
A polyester according to claim 1, wherein said polyester contains a compound which has at least 4 methylene groups in an amount of up to 15 mol. %.
Claim 13
Dependent Claim 20 words
A powder coating according to claim 10, wherein the weight percentage of said tri-epoxy compound is between 1.6 and 4.9.
Claim 14
Dependent Claim 14 words
A powder coating according to claim 10 wherein said tri-epoxy compound is triglycidyl isocyanurate.
Claim 15
Dependent Claim 63 words
A polyester according to claim 1 wherein said acid number is between 12 and 24 mg KOH/g, said hydroxyl number is 5 mg KOH/g at a maximum, said theoretical number-average molecular weight is between 5,000 and 10,000, said glass transition temperature of the polyester is between 50° and 70° C. and said average carboxyl functionality of the polyester is between 2 and 3.
Claim 16
Dependent Claim 24 words
A polyester according to claim 14 wherein said dicarboxylic acid mixture consists of at least 50 wt. % of isophthalic acid and/or terephthalic acid.
Claim 17
Dependent Claim 24 words
A polyester according to claim 14 wherein said dicarboxylic acid mixture consists of at least 70 mol. % of isophthalic acid and/or terephthalic acid.
Claim 18
Dependent Claim 24 words
A polyester according to claim 14 wherein said aliphatic diol mixture consists of at least 50 mol. % of neopentyl glycol and propylene glycol.

References Cited (Backward Citations)

US4147737A Cited
US3988288A Cited
US4085159A Cited
US4087479A Cited
US4288569A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-08 1989-01-07 1989-07-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-08 1993-01-07 1993-07-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-08 1997-01-07 1997-07-09 $7700.00 Window Closed / Lapsed

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