Patent US4528108A successfully refreshed from Google Patents.
US4528108A
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Method for cooling internal combustion engine with an oleaginous coolant fluid composition
Assignee: Lubrizol Corp
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Filing: 1983-04-20
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Granted: 1985-07-09
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Expires: 2003-04-20
Abstract
Abstract Disclosed is a method for cooling an internal combustion engine which comprises circulating within the cooling system of said engine an oleaginous coolant fluid composition which comprises (A) a major amount of a lubricating oil having a kinematic viscosity of from about 3.5 up to about 5 cSt at 100° C. and from about 18 up to about 30 cSt at 40° C.; and (B) a minor amount of one or more of the following compositions: (1) one or more basic metal salts of organic acids; (2) one or more phosphorus-containing metal salts; (3) one or more phenol antioxidants.
Inventors
- 👤 Kent B. Grover
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 08:00
CPC Classifications
C; C10; C10M; C10M167/00; C10M129/00; C10M129/02; C10M129/16; C10M129/18; C10M129/26; C10M137/00; C10M145/00; C10M145/02; C10M145/10; C10M149/00; C10M149/02; C10M149/06; C10M159/00; C10M159/12; C10M2205/00; C10M2205/22; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/024; C10M2207/026; C10M2207/04; C10M2207/042; C10M2207/10; C10M2207/12; C10M2207/121; C10M2207/122; C10M2207/123; C10M2207/124; C10M2207/125; C10M2207/128; C10M2207/129; C10M2207/14; C10M2207/141; C10M2207/142; C10M2207/144; C10M2207/146; C10M2207/22; C10M2207/24; C10M2207/26; C10M2207/262; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/086; C10M2217/00; C10M2217/02; C10M2217/024; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/046; C10M2219/08; C10M2219/082; C10M2219/087; C10M2219/088; C10M2219/089; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2223/045; C10M2223/06; C10M2223/061; C10M2223/065; C10M2227/00; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2010/06; C10N2010/08; C10N2010/10; C10N2010/12; C10N2010/14; C10N2010/16
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
122 words
A method for cooling a conventional water-cooled internal combustion engine which comprises circulating within the water coolant system of said engine an oleaginous coolant fluid composition essentially free from water and comprising: (A) a major amount of a lubricating oil having a kinematic viscosity of from about 3.5 up to about 5 cSt at 100° C. and from about 18 up to about 30 cSt at 40° C.; (B) a minor amount of a composition selected from the group consisting of (1) one or more basic metal salts of organic acids; (2) one or more phosphorus containing metal salts; (3) one or more phenolic antioxidants; (4) one or more pour point depressants; and mixtures of two or more of (B)(1) through (B)(4).
Claim 2
Independent Claim
122 words
A method for cooling a conventional water-cooled internal combustion engine which comprises circulating within the water coolant system of said engine an oleaginous coolant fluid composition essentially free from water and comprising: (A) a major amount of a lubricating oil having a kinematic viscosity of from about 3.5 up to about 5 cSt at 100° C. and from about 18 up to about 30 cSt at 40° C.; (B) a minor amount of a composition selected from the group consisting of (1) one or more basic metal salts of organic acids; (2) one or more phosphorus containing metal salts; (3) one or more phenolic antioxidants; (4) one or more pour point depressants; and mixtures of two or more of (B)(1) through (B)(4).
Claim 3
Dependent Claim
236 words
A method according to claim 1 wherein component (B) is a composition comprising (1) one or more basic metal salts of organic acids; (2) one or more phosphorus-containing metal salts selected from the group consisting of (a) metal salts of one or more phosphorus-containing acids of the formula ##STR18## wherein each X and X' is independently oxygen or divalent sulfur with the proviso that each n may be zero or one, each R is independently the same or a different hydrocarbon-based radical; (b) metal salts of the mixture of (i) one or more phosphorus-containing acids of the formula ##STR19## wherein X, X', R and n are defined in (B)(2)(a); and (ii) one or more aliphatic or alicyclic carboxylic acids; and (c) one or more compositions which are phosphite post-treatments of (B)(2)(a) or (B)(2)(b); and (3) one or more phenolic antioxidants selected from the group consisting of hindered phenols and hindered phenols corresponding to the formulae: ##STR20## wherein said R 1 groups are each independently hydrogen or aliphatic hydrocarbon radicals containing from 1 to about 8 carbon atoms; q can be 1, 2 or 3 with the proviso that at least one of said R 1 groups is an aliphatic hydrocarbon radical in a position ortho to the phenolic hydroxyl group and Y is a radical selected from the group consisting of alkylidene radicals containing from 1 to about 4 carbon atoms, thio radicals and dithio radicals.
Claim 4
Dependent Claim
17 words
A method according to claim 2 wherein the organic acid of (B)(1) is an organic sulfur acid.
Claim 5
Dependent Claim
26 words
A method according to claim 3 wherein the basic metal salts of (B)(1) are alkali and alkaline earth metal salts of carbocyclic or aliphatic sulfonic acids.
Claim 6
Dependent Claim
30 words
A method according to claim 3 wherein at least one X of (B)(2) is divalent sulfur, at least one X' of (B)(2) is oxygen and n of (B)(2) is one.
Claim 7
Dependent Claim
18 words
A method according to claim 5 wherein the phosphorus-containing metal salts of (B)(2) are Group II metal salts.
Claim 8
Dependent Claim
34 words
A method according to claim 6 wherein the phenolic antioxidant of (B)(3) corresponds to the formula ##STR21## wherein R 1 is an alkyl radical containing 1-4 carbon atoms and q is 2 or 3.
Claim 9
Dependent Claim
18 words
A method according to claim 6 wherein X' is oxygen, X is divalent sulfur and n is 1.
Claim 10
Dependent Claim
15 words
A method according to claim 8 wherein the Group II metal is zinc or cadmium.
Claim 11
Dependent Claim
21 words
A method according to claim 9 wherein each R is an alkyl radical having from 3 to about 50 carbon atoms.
Claim 12
Dependent Claim
18 words
A method according to claim 10 wherein each R contains from about 3 to about 18 carbon atoms.
Claim 13
Dependent Claim
24 words
A method according to claim 11 wherein the carboxylic acid has the formula R 2 COOH, wherein R 2 is an aliphatic hydrocarbon-based radical.
Claim 14
Dependent Claim
18 words
A method according to claim 12 wherein the carboxylic acid contains from 3 to about 40 carbon atoms.
Claim 15
Dependent Claim
22 words
A method according to claim 13 wherein R 2 is a branched alkyl radical containing about 4 to about 20 carbon atoms.
Claim 16
Dependent Claim
26 words
A method according to claim 6 wherein the phosphite is of the formula (R 4 O) 3 P, wherein each R 4 is a hydrocarbon-based radical.
Claim 17
Dependent Claim
19 words
A method according to claim 14 wherein each R 4 contains from about 3 to about 18 carbon atoms.
Claim 18
Independent Claim
264 words
A method for cooling a conventional water-cooled internal combustion engine which comprises circulating within the water coolant system of said engine an oleaginous coolant fluid composition essentially free from water and comprising: (A) a major amount of a lubricating oil having a kinematic viscosity of about 4.0-4.3 cSt at 100° C. and about 19-22 cSt at 40° C.; (B)(1) a minor amount of one or more basic alkali or alkaline earth metal salts of organic sulfonic acids, carboxylic acids or mixtures thereof; (B)(2) a minor amount of one or more phosphite post-treatment compositions of zinc or cadmium metal salts of the mixture of (i) one or more phosphorus-containing acids of the formula ##STR22## wherein each X is independently oxygen or divalent sulfur, each R is independently an alkyl radical containing from about 3 to about 18 carbon atoms; and (ii) one or more carboxylic acids having the formula R 2 COOH, wherein R 2 is an aliphatic hydrocarbon-based radical; (B)(3) a minor amount of one or more phenolic antioxidants having the formula ##STR23## wherein each R 1 is independently an alkyl radical containing 1-4 carbon atoms; q is 2 or 3 with the proviso that said R 1 radicals are in both positions ortho to the phenolic hydroxyl group; (B)(4) a minor amount of one or more pour point depressants; (B)(5) a minor amount of one or more demulsifier compositions; and (B)(6) a minor amount of one or more antifoam compositions; with the proviso that components (B)(1) through (B)(6) constitute from about 0.05 up to about 2.5% by weight of said coolant fluid composition.
Claim 19
Independent Claim
264 words
A method for cooling a conventional water-cooled internal combustion engine which comprises circulating within the water coolant system of said engine an oleaginous coolant fluid composition essentially free from water and comprising: (A) a major amount of a lubricating oil having a kinematic viscosity of about 4.0-4.3 cSt at 100° C. and about 19-22 cSt at 40° C.; (B)(1) a minor amount of one or more basic alkali or alkaline earth metal salts of organic sulfonic acids, carboxylic acids or mixtures thereof; (B)(2) a minor amount of one or more phosphite post-treatment compositions of zinc or cadmium metal salts of the mixture of (i) one or more phosphorus-containing acids of the formula ##STR22## wherein each X is independently oxygen or divalent sulfur, each R is independently an alkyl radical containing from about 3 to about 18 carbon atoms; and (ii) one or more carboxylic acids having the formula R 2 COOH, wherein R 2 is an aliphatic hydrocarbon-based radical; (B)(3) a minor amount of one or more phenolic antioxidants having the formula ##STR23## wherein each R 1 is independently an alkyl radical containing 1-4 carbon atoms; q is 2 or 3 with the proviso that said R 1 radicals are in both positions ortho to the phenolic hydroxyl group; (B)(4) a minor amount of one or more pour point depressants; (B)(5) a minor amount of one or more demulsifier compositions; and (B)(6) a minor amount of one or more antifoam compositions; with the proviso that components (B)(1) through (B)(6) constitute from about 0.05 up to about 2.5% by weight of said coolant fluid composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-08 | 1989-01-07 | 1989-07-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-08 | 1993-01-07 | 1993-07-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-08 | 1997-01-07 | 1997-07-09 | $7700.00 | Window Closed / Lapsed |