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Piperidine derivatives which are stabilizers for synthetic polymers

Assignee: Novartis Corp
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Filing: 1982-09-08
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Granted: 1985-06-25
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Expires: 2002-09-08
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Abstract

Abstract The invention relates to new piperidine compounds which act as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers, in particular for hydrocarbon polymers. The compounds are piperidinol carbamates of the formula: ##STR1## in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and A have the meanings defined in the description and y is an integer from 1 to 4. In particular, A represents a monovalent to tetravalent radical, always bonded to the carboxy-piperidine radicals via nitrogen atoms.

Inventors

  • 👤 Giuseppe Cantatore

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:39
CPC Classifications
C; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/56; C07D211/58; C07D211/40; C07D211/44; C07D211/46; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 300 words
A compound of the formula ##STR37## or an acid addition salt thereof, in which R 1 represents (a) hydrogen, (b) C 1 -C 12 -alkyl, (c) --CH 2 CN (d) C 3 -C 12 -alkenyl, (e) C 3 -C 12 -alkinyl, (f) benzyl, (g) benzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (h) hydroxybenzyl, (i) hydroxybenzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (j) a --COR 8 , --COOR 8 , --CH 2 COOR 8 or --CONR 8 R 9 radical in which R 8 and R 9 , which may be identical or different, represent (1) linear or branched C 1 -C 12 -alkyl, (2) C 3 -C 12 -alkenyl, (3) C 5 -C 12 -cycloalkyl, (4) phenyl, (5) phenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (6) hydroxyphenyl, (7) hydroxyphenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (8) C 7 -C 12 -aralkyl, or (9) 2,2,6,6-tetramethyl-piperidin-4-yl, (k) a ##STR38## radical, in which R 10 is hydrogen methyl or phenyl and R 11 is hydrogen, --R 8 , --COR 8 or --CONR 8 R 9 , in which R 8 and R 9 are as defined above, or (1) a ##STR39## radical; and A is a radical of the formula ##STR40## in which R 17 and R 18 may be identical or different and represent C 1 -C 12 alkyl, C 5 -C 12 cycloalkyl or a radical of the formula ##STR41## in which R 1 is as defined above, and m and n, which may be identical or different, are integers from 2 to 6, or A is a trivalent radical of a 6-7-membered heterocyclic compound containing 3 nitrogen atoms in the ring, with the free valencies on the three nitrogen atoms.
Claim 2
Dependent Claim 300 words
A compound of the formula ##STR37## or an acid addition salt thereof, in which R 1 represents (a) hydrogen, (b) C 1 -C 12 -alkyl, (c) --CH 2 CN (d) C 3 -C 12 -alkenyl, (e) C 3 -C 12 -alkinyl, (f) benzyl, (g) benzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (h) hydroxybenzyl, (i) hydroxybenzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (j) a --COR 8 , --COOR 8 , --CH 2 COOR 8 or --CONR 8 R 9 radical in which R 8 and R 9 , which may be identical or different, represent (1) linear or branched C 1 -C 12 -alkyl, (2) C 3 -C 12 -alkenyl, (3) C 5 -C 12 -cycloalkyl, (4) phenyl, (5) phenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (6) hydroxyphenyl, (7) hydroxyphenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (8) C 7 -C 12 -aralkyl, or (9) 2,2,6,6-tetramethyl-piperidin-4-yl, (k) a ##STR38## radical, in which R 10 is hydrogen methyl or phenyl and R 11 is hydrogen, --R 8 , --COR 8 or --CONR 8 R 9 , in which R 8 and R 9 are as defined above, or (1) a ##STR39## radical; and A is a radical of the formula ##STR40## in which R 17 and R 18 may be identical or different and represent C 1 -C 12 alkyl, C 5 -C 12 cycloalkyl or a radical of the formula ##STR41## in which R 1 is as defined above, and m and n, which may be identical or different, are integers from 2 to 6, or A is a trivalent radical of a 6-7-membered heterocyclic compound containing 3 nitrogen atoms in the ring, with the free valencies on the three nitrogen atoms.
Claim 3
Dependent Claim 69 words
A compound according to claim 1, in which R 1 represents hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl, benzyl or C 1 -C 6 -alkanoyl; A is member of the group of (a) ##STR42## wherein R 17 and R 18 represent C 1 -C 8 -alkyl, C 6 -C 12 -cycloalkyl, 2,2,6,6-tetramethylpiperidine-4-yl or 1,2,2,6,6-pentamethylpiperidin-4-yl and m and n are 2 or 3 and (b) hexahydro-1,3,5-triazin-1,3,5-triyl.
Claim 4
Dependent Claim 28 words
A compound according to claim 2, in which R 1 is hydrogen, methyl, allyl, benzyl or acetyl and R 17 and R 18 are cyclohexyl, 2,2,6,6-tetramethylpiperidin-4-yl or 1,2,2,6,6-pentamethylpiperidin-4-yl.
Claim 5
Dependent Claim 12 words
A compound according to claim 1, of one of the formulae: ##STR43##
Claim 6
Dependent Claim 44 words
A light-stabilised, heat-stabilised and oxidation-stabilised polymer composition which consists of a synthetic polymer and a stabiliser compound according to claim 1 in an amount of between 0.01 and 5%, preferably between 0.1 and 1%, by weight relative to the weight of the synthetic polymer.
Claim 7
Dependent Claim 20 words
A composition according to claim 5, which, in addition to the novel stabiliser, contains other, conventional additives for synthetic polymers.
Claim 8
Dependent Claim 15 words
A composition according to claim 5, in which the synthetic polymer is polyethylene or polypropylene.
Claim 9
Dependent Claim 11 words
Articles obtained from the stabilised polymer composition according to claim 5.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-24 1988-12-24 1989-06-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-24 1992-12-24 1993-06-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-24 1996-12-24 1997-06-25 $7700.00 Window Closed / Lapsed

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