US4525503A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Piperidine derivatives which are stabilizers for synthetic polymers
Assignee: Novartis Corp
•
Filing: 1982-09-08
•
Granted: 1985-06-25
•
Expires: 2002-09-08
Abstract
Abstract The invention relates to new piperidine compounds which act as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers, in particular for hydrocarbon polymers. The compounds are piperidinol carbamates of the formula: ##STR1## in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and A have the meanings defined in the description and y is an integer from 1 to 4. In particular, A represents a monovalent to tetravalent radical, always bonded to the carboxy-piperidine radicals via nitrogen atoms.
Inventors
- 👤 Giuseppe Cantatore
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 05:53
CPC Classifications
C; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/56; C07D211/58; C07D211/40; C07D211/44; C07D211/46; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
300 words
A compound of the formula ##STR37## or an acid addition salt thereof, in which R 1 represents (a) hydrogen, (b) C 1 -C 12 -alkyl, (c) --CH 2 CN (d) C 3 -C 12 -alkenyl, (e) C 3 -C 12 -alkinyl, (f) benzyl, (g) benzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (h) hydroxybenzyl, (i) hydroxybenzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (j) a --COR 8 , --COOR 8 , --CH 2 COOR 8 or --CONR 8 R 9 radical in which R 8 and R 9 , which may be identical or different, represent (1) linear or branched C 1 -C 12 -alkyl, (2) C 3 -C 12 -alkenyl, (3) C 5 -C 12 -cycloalkyl, (4) phenyl, (5) phenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (6) hydroxyphenyl, (7) hydroxyphenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (8) C 7 -C 12 -aralkyl, or (9) 2,2,6,6-tetramethyl-piperidin-4-yl, (k) a ##STR38## radical, in which R 10 is hydrogen methyl or phenyl and R 11 is hydrogen, --R 8 , --COR 8 or --CONR 8 R 9 , in which R 8 and R 9 are as defined above, or (1) a ##STR39## radical; and A is a radical of the formula ##STR40## in which R 17 and R 18 may be identical or different and represent C 1 -C 12 alkyl, C 5 -C 12 cycloalkyl or a radical of the formula ##STR41## in which R 1 is as defined above, and m and n, which may be identical or different, are integers from 2 to 6, or A is a trivalent radical of a 6-7-membered heterocyclic compound containing 3 nitrogen atoms in the ring, with the free valencies on the three nitrogen atoms.
Claim 2
Dependent Claim
300 words
A compound of the formula ##STR37## or an acid addition salt thereof, in which R 1 represents (a) hydrogen, (b) C 1 -C 12 -alkyl, (c) --CH 2 CN (d) C 3 -C 12 -alkenyl, (e) C 3 -C 12 -alkinyl, (f) benzyl, (g) benzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (h) hydroxybenzyl, (i) hydroxybenzyl substituted by 1 to 3 C 1 -C 4 -alkyl radicals, (j) a --COR 8 , --COOR 8 , --CH 2 COOR 8 or --CONR 8 R 9 radical in which R 8 and R 9 , which may be identical or different, represent (1) linear or branched C 1 -C 12 -alkyl, (2) C 3 -C 12 -alkenyl, (3) C 5 -C 12 -cycloalkyl, (4) phenyl, (5) phenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (6) hydroxyphenyl, (7) hydroxyphenyl substituted by 1 to 3 C 1 -C 8 -alkyl radicals, (8) C 7 -C 12 -aralkyl, or (9) 2,2,6,6-tetramethyl-piperidin-4-yl, (k) a ##STR38## radical, in which R 10 is hydrogen methyl or phenyl and R 11 is hydrogen, --R 8 , --COR 8 or --CONR 8 R 9 , in which R 8 and R 9 are as defined above, or (1) a ##STR39## radical; and A is a radical of the formula ##STR40## in which R 17 and R 18 may be identical or different and represent C 1 -C 12 alkyl, C 5 -C 12 cycloalkyl or a radical of the formula ##STR41## in which R 1 is as defined above, and m and n, which may be identical or different, are integers from 2 to 6, or A is a trivalent radical of a 6-7-membered heterocyclic compound containing 3 nitrogen atoms in the ring, with the free valencies on the three nitrogen atoms.
Claim 3
Dependent Claim
69 words
A compound according to claim 1, in which R 1 represents hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl, benzyl or C 1 -C 6 -alkanoyl; A is member of the group of (a) ##STR42## wherein R 17 and R 18 represent C 1 -C 8 -alkyl, C 6 -C 12 -cycloalkyl, 2,2,6,6-tetramethylpiperidine-4-yl or 1,2,2,6,6-pentamethylpiperidin-4-yl and m and n are 2 or 3 and (b) hexahydro-1,3,5-triazin-1,3,5-triyl.
Claim 4
Dependent Claim
28 words
A compound according to claim 2, in which R 1 is hydrogen, methyl, allyl, benzyl or acetyl and R 17 and R 18 are cyclohexyl, 2,2,6,6-tetramethylpiperidin-4-yl or 1,2,2,6,6-pentamethylpiperidin-4-yl.
Claim 5
Dependent Claim
12 words
A compound according to claim 1, of one of the formulae: ##STR43##
Claim 6
Dependent Claim
44 words
A light-stabilised, heat-stabilised and oxidation-stabilised polymer composition which consists of a synthetic polymer and a stabiliser compound according to claim 1 in an amount of between 0.01 and 5%, preferably between 0.1 and 1%, by weight relative to the weight of the synthetic polymer.
Claim 7
Dependent Claim
20 words
A composition according to claim 5, which, in addition to the novel stabiliser, contains other, conventional additives for synthetic polymers.
Claim 8
Dependent Claim
15 words
A composition according to claim 5, in which the synthetic polymer is polyethylene or polypropylene.
Claim 9
Dependent Claim
11 words
Articles obtained from the stabilised polymer composition according to claim 5.
References Cited (Backward Citations)
US3640928A
Cited
DE2126954A1
Cited
FR2183293A1
Cited
FR2183294A1
Cited
FR2256159A1
Cited
US4075165A
Cited
FR2333794A1
Cited
FR2349574A1
Cited
FR2357561A1
Cited
US4102858A
Cited
FR2405247A1
Cited
FR2409985A1
Cited
US4315859A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-24 | 1988-12-24 | 1989-06-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-24 | 1992-12-24 | 1993-06-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-24 | 1996-12-24 | 1997-06-25 | $7700.00 | Window Closed / Lapsed |