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US4525469A
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Catalyst composition for polymerizing olefins
Assignee: Mitsui Chemicals Inc
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Filing: 1983-10-25
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Granted: 1985-06-25
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Expires: 2003-10-25
Abstract
Abstract A catalyst composition for the polymerization or copolymerization of olefins composed of (A) a titanium component (a-1) or (a-2), (a-1) a highly active titanium component containing titanium, magnesium and halogen as essential ingredients, or (a-2) a highly active titanium catalyst component obtained by treating component (a-1) with an organic compound containing active hydrogen bonded to oxygen, and (B) an organoaluminum compound component, wherein (i) when component (A) is the component (a-1), component (b) is an organoaluminum compound component obtained by treating a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2 with a compound selected from the group consisting of water and organic compounds having active hydrogen bonded to oxygen, and (ii) when component (A) is the component (a-2), the component (B) is a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2, and the ratio of the amount (x) of the organic compound having active hydrogen atom bonded to oxygen and/or an oxygen-containing group derived from said organic compound to the amount (y) of titanium, x:y, is 4-100:1.
Inventors
- 👤 Takashi Ueda
- 👤 Norio Kashiwa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:04
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F10/00
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
183 words
A catalyst composition for the polymerization or copolymerization of olefins composed of (A) a titanium component (a-1) or (a-2), (a-1) a highly active titanium component containing titanium, magnesium and halogen as essential ingredients, or (a-2) a highly active titanium catalyst component obtained by treating component (a-1) with an organic compound containing active hydrogen bonded to oxygen, and (B) an organoaluminum compound component, wherein (i) when component (A) is the component (a-1), component (B) is an organoaluminum compound component obtained by treating a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2 with a compound selected from the group consisting of water and organic compounds having active hydrogen bonded to oxygen, and (ii) when component (A) is the component (a-2), the component (B) is a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2, and the ratio of the amount (x) of the organic compound having active hydrogen atom bonded to oxygen and/or an oxygen-containing group derived from said organic compound to the amount (y) of titanium, x:y, is 4-100:1.
Claim 2
Dependent Claim
183 words
A catalyst composition for the polymerization or copolymerization of olefins composed of (A) a titanium component (a-1) or (a-2), (a-1) a highly active titanium component containing titanium, magnesium and halogen as essential ingredients, or (a-2) a highly active titanium catalyst component obtained by treating component (a-1) with an organic compound containing active hydrogen bonded to oxygen, and (B) an organoaluminum compound component, wherein (i) when component (A) is the component (a-1), component (B) is an organoaluminum compound component obtained by treating a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2 with a compound selected from the group consisting of water and organic compounds having active hydrogen bonded to oxygen, and (ii) when component (A) is the component (a-2), the component (B) is a halogen-containing organoaluminum compound having a halogen/Al atomic ratio of at least 1 but less than 2, and the ratio of the amount (x) of the organic compound having active hydrogen atom bonded to oxygen and/or an oxygen-containing group derived from said organic compound to the amount (y) of titanium, x:y, is 4-100:1.
Claim 3
Dependent Claim
46 words
The catalyst composition of claim 1 wherein the organic compound having active hydrogen bonded to oxygen is a compound selected from the group consisting of alcohols, phenols, carboxylic acids and adducts and complexes of said alcohols, phenols or carboxylic acids with magnesium chloride or aluminum chloride.
Claim 4
Dependent Claim
96 words
The catalyst composition of claim 2 wherein the active hydrogen-containing organic compound is a compound selected from the group consisting of aliphatic alchols having 1 to 18 carbon atoms, alicyclic alcohols having 5 to 12 carbon atoms, aromatic alcohols having 7 to 15 carbon atoms, phenols having 6 to 16 carbon atoms, aliphatic carboxylic acids having 1 to 18 carbon atoms, alicyclic carboxylic acids having 6 to 12 carbon atoms, aromatic carboxylic acids having 7 to 15 carbon atoms, and adducts and complexes of said alcohols, carboxylic acids or phenols with magnesium chloride or aluminum chloride.
Claim 5
Dependent Claim
29 words
The catalyst composition of claim 1 wherein in component (a-1), the magnesium/titanium atomic ratio is from 2 to 100, and the halogen/titanium atomic ratio is from 4 to 100.
Claim 6
Dependent Claim
17 words
The catalyst composition of claim 1 wherein the titanium component (a-1) is used for the component (A).
Claim 7
Dependent Claim
17 words
The catalyst composition of claim 1 wherein the titanium component (a-1) is used as the component (A).
Claim 8
Dependent Claim
12 words
The catalyst composition of claim 6 wherein the ratio x:y is 6-50:1.
Claim 9
Dependent Claim
32 words
The catalyst composition of claim 6 wherein the amount of the organic compound containing active hydrogen bonded to oxygen is from 1 to 50 moles per titanium atom in the component (a-1).
Claim 10
Dependent Claim
16 words
The catalyst composition of claim 6 wherein the halogen-Al atomic ratio is from 1.25 to 1.75.
Claim 11
Dependent Claim
16 words
The catalyst composition of claim 5 wherein the halogen-Al atomic ratio is from 1.25 to 1.75.
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