Liquid smoke treated cellulosic food casings

Claim 2

A shirred tubular cellulosic food casing having incorporated in the external surface thereof a substantially tar-free admixture of smoke coloring and flavoring constituents derived from natural wood and including acids and neutralized acids, phenols and carbonyls in an amount of at least about 0.8 mg. per square inch of casing surface, such that the casing external surface is darker then the casing interior surface, said casing being suitable without other smoking procedures for imparting smoke color and flavor to food products processed therein with said smoke color resulting from reactions of said coloring constituents with proteins in the food products.

Claim 3

The casing of claim 1 wherein said casing has incorporated therein at least about 0.1 mg. of acids and neutralized acids expressed as acetic acid, per square inch of casing surface.

Claim 4

The casing of claim 1 wherein said casing has incorporated therein at least about 0.003 mg. of phenols expressed as 2,6-dimethoxyphenol, per square inch of casing surface.

Claim 5

The casing of claim 1 wherein said casing has incorporated therein at least about 1.2 mg. of carbonyls expressed as 2-butanone, per square inch of casing surface.

Claim 6

The casing of claim 1 wherein said casing has incorporated therein at least about 0.3 mg. acids and neutralized acids expressed as acetic acid, per square inch of casing surface.

Claim 7

The casing of claim 1 wherein said casing has incorporated therein at least about 0.008 mg. phenols expressed as 2,6-dimethoxyphenol, per square inch of casing surface.

Claim 8

The casing of claim 1 wherein said casing has incorporated therein at least about 1.6 mg. carbonyls expressed as 2-butanone, per square inch of casing surface.

Claim 9

The casing of claim 1 wherein said casing has at least a smear resistant inner surface when rubbed with a dry cloth.

Claim 10

The casing of claim 1 wherein said casing has incorporated therein a salt of an alkaline neutralizing agent and an acid.

Claim 11

The casing of claim 1 wherein said casing is a nonfibrous casing.

Claim 12

The casing of claim 1 wherein said casing is a fibrous casing.

Claim 13

The casing of claim 1 wherein said casing has coated on its interior surface an agent for improving the peelability of the casing from food products processed therein.

Claim 14

The casing of claim 12 wherein said peeling agent comprises a water soluble cellulose ether composition.

Claim 15

The casing of claim 13 wherein said water soluble cellulose ehter composition comprises a carboxymethyl cellulose composition.

Claim 16

The casing of claim 14 wherein said carboxymethyl cellulose composition contains an alkaline buffering agent.

Claim 17

The casing of claim 1 wherein said casing has coated on its interior surface an agent for improving the adhesion of the casing to food products processed therein.

Claim 18

A shirred tubular cellulosic food casing prepared by the steps of: providing a cellulosic casing selected from the group consisting of a non-fibrous gel stock casing and a fibrous gel stock casing; treating the external surface of said casing with a substantially tar-free aqueous liquid smoke composition having a pH greater than about 4 comprising a mixture of smoke coloring and flavoring constituents derived as said mixture from natural wood, until said casing has incorporated therein said mixture of smoke coloring and flavoring constituents including acids and neutralized acids, pheonls and carbonyls, in an amount of at least about 0.8 mg. per square inch of casing surface, such that the so-treated casing has an exterior surface which is darker than the interior surface of the casing; and thereafter drying and shirring the so-treated casing with the smoke coloring and flavoring constituents incorporated therein being suitable without other smoking procedures for imparting smoke color and flavor to food products processed therein and with said smoke color resulting from reaction of said coloring constituents with proteins in the food products.

Claim 19

A shirred tubular cellulosic food casing prepared by the steps of: providing a cellulosic casing selected from the group consisting of a non-fibrous gel stock casing and a fibrous gel stock casing; treating the external surface of said casing with a substantially tar-free aqueous liquid smoke composition having a pH greater than about 4 comprising a mixture of smoke coloring and flavoring constituents derived as said mixture from natural wood, until said casing has incorporated therein said mixture of smoke coloring and flavoring constituents including acids and neutralized acids, pheonls and carbonyls, in an amount of at least about 0.8 mg. per square inch of casing surface, such that the so-treated casing has an exterior surface which is darker than the interior surface of the casing; and thereafter drying and shirring the so-treated casing with the smoke coloring and flavoring constituents incorporated therein being suitable without other smoking procedures for imparting smoke color and flavor to food products processed therein and with said smoke color resulting from reaction of said coloring constituents with proteins in the food products.

Claim 20

The casing of claim 1 wherein the substantially tar-free liquid smoke is prepared by removing tar from natural wood-derived tar-containing liquid smoke.

Claim 21

The casing of claim 1 wherein the substantially tar-free liquid smoke is prepared by neutralizing natural wood-derived tar-containing liquid smoke and filtering to remove the precipitated tar.

Claim 22

The casing of claim 17 wherein the substantially tar-free liquid smoke is prepared by providing natural wood-derived tar-containing liquid smoke and removing the tar therefrom.

Claim 23

The casing of claim 17 wherein the substantially tar-free liquid smoke is prepared by providing natural wood-derived tar-containing liquid smoke, neutralizing said tar-containing liquid smoke thereby precipitating tar, and removing the precipitated tar.