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US4525216A Expired / Lapsed US ⏱️ 0.0 years remaining

Ink composition

Assignee: Sakura Color Products Corp
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Filing: 1982-10-26
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Granted: 1985-06-25
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Expires: 2002-10-26
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Abstract

Abstract An ink composition for a marking pen is disclosed which permits smooth writing even after a long period of standing of the pen with no cap. The ink composition comprises an organic solvent, a pigment, a resin and at least one additive selected from the group consisting of a glyceride of specified structure, and an alkylamide alcohol of specified structure and a sorbitan fatty acid ester. An erasable ink composition for writing on a writing surface such as one of resin is also disclosed, which further includes, in addition to the above, a separating agent which is a non-volatile or only slightly volatile liquid or semi-solid at normal temperatures and has a lower vapor pressure than the solvent, and is soluble in the solvent.

Inventors

  • 👤 Mikihiko Nakanishi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 08:21
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/16

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 190 words
An ink composition for a marking pen which consists essentially of: about 40-90% by weight of a volatile organic solvent; about 1-10% by weight of a pigment; about 0.5-30% by weight of a resin which is soluble in the solvent; and about 0.05-10% by weight of at least one anti-drying additive which is selected from the group consisting of (a) a glyceride of the general formula ##STR7## wherein R 1 represents a fatty acid residue of 7-23 carbons, R 2 represents a mono- or polybasic hydroxycarboxylic acid residue of 1-23 carbons, and n is an integer of 1 or 2, (b) an alkylamide alcohol of the general formula ##STR8## wherein R 1 is the same as above, R 3 represents an alkylene of 1-4 carbons, and R 4 represents hydrogen or a group of the general formula ##STR9## or an intramolecular condensate of the alkylamide alcohol of the formula ##STR10## wherein R 4 is hydrogen, or salts of said alkylamide alcohol or intramolecular condensate with fatty acids of 1-8 carbons, and (c) a sorbitan fatty acid ester of the general formula ##STR11## wherein R 1 is the same as above.
Claim 2
Dependent Claim 190 words
An ink composition for a marking pen which consists essentially of: about 40-90% by weight of a volatile organic solvent; about 1-10% by weight of a pigment; about 0.5-30% by weight of a resin which is soluble in the solvent; and about 0.05-10% by weight of at least one anti-drying additive which is selected from the group consisting of (a) a glyceride of the general formula ##STR7## wherein R 1 represents a fatty acid residue of 7-23 carbons, R 2 represents a mono- or polybasic hydroxycarboxylic acid residue of 1-23 carbons, and n is an integer of 1 or 2, (b) an alkylamide alcohol of the general formula ##STR8## wherein R 1 is the same as above, R 3 represents an alkylene of 1-4 carbons, and R 4 represents hydrogen or a group of the general formula ##STR9## or an intramolecular condensate of the alkylamide alcohol of the formula ##STR10## wherein R 4 is hydrogen, or salts of said alkylamide alcohol or intramolecular condensate with fatty acids of 1-8 carbons, and (c) a sorbitan fatty acid ester of the general formula ##STR11## wherein R 1 is the same as above.
Claim 3
Dependent Claim 29 words
The ink composition as claimed in claim 1 wherein R 1 is a fatty acid residue of 13-17 carbons, R 2 is malic acid residue, and n is 2.
Claim 4
Dependent Claim 48 words
The ink composition as claimed in claim 1 which further includes about 1-25% by weight of a separating agent which is a non-volatile or only slightly volatile liquid or semi-solid at normal temperatures and has a lower vapor pressure than the solvent, and is soluble in the solvent.
Claim 5
Dependent Claim 106 words
The ink composition as claimed in claim 3 which further includes up to about 10% by weight of a surfactant selected from the group consisting of a nonionic surfactant which is a higher alkyl ether, a higher alkylphenol ether, a higher fatty acid ester or a sorbitan ester of polyoxyethylene glycol, and an anionic surfactant which is a higher fatty acid salt, a higher aliphatic alcohol sulfonate, an alkylbenzene sulfonate, an alkylnaphthalene sulfonate, a dialkylsulfosuccinate, an alkylphosphate, a polyoxyethylene glycol sulfate or a polyoxyethylene phosphate, the total amount of the surfactant and the separating agent being up to 25% by weight based on the ink composition.
Claim 6
Dependent Claim 216 words
In a felt tip marking pen ink composition consisting essentially of a volatile organic solvent, a pigment and a resin soluble in said solvent, the improvement wherein there is additionally present an anti-drying additive in an amount effective to permit the formation of a thin solid film on the felt tip when a small amount of said solvent evaporates, which film is readily broken by writing pressure and dissolution of said film in said solvent, said anti-drying agent being selected from the group consisting of: (a) a glyceride of the general formula ##STR12## wherein R 1 represents a fatty acid residue of 7-23 carbons, R 2 represents a mono- or polybasic hydroxycarboxylic acid residue of 1-23 carbons, and n is an integer of 1 or 2, (b) an alkylamide alcohol of the general formula ##STR13## wherein R 1 is the same as above, R 3 represents an alkylene of 1-4 carbons, and R 4 represents hydrogen or a group of the general formula ##STR14## or an intramolecular condensate of the alkylamide alcohol of the formula ##STR15## wherein R 4 is hydrogen, or salts of said alkylamide alcohol or intramolecular condensate with fatty acids of 1-8 carbons, and (c) a sorbitan fatty acid ester of the general formula ##STR16## wherein R 1 is the same as above.
Claim 7
Dependent Claim 216 words
In a felt tip marking pen ink composition consisting essentially of a volatile organic solvent, a pigment and a resin soluble in said solvent, the improvement wherein there is additionally present an anti-drying additive in an amount effective to permit the formation of a thin solid film on the felt tip when a small amount of said solvent evaporates, which film is readily broken by writing pressure and dissolution of said film in said solvent, said anti-drying agent being selected from the group consisting of: (a) a glyceride of the general formula ##STR12## wherein R 1 represents a fatty acid residue of 7-23 carbons, R 2 represents a mono- or polybasic hydroxycarboxylic acid residue of 1-23 carbons, and n is an integer of 1 or 2, (b) an alkylamide alcohol of the general formula ##STR13## wherein R 1 is the same as above, R 3 represents an alkylene of 1-4 carbons, and R 4 represents hydrogen or a group of the general formula ##STR14## or an intramolecular condensate of the alkylamide alcohol of the formula ##STR15## wherein R 4 is hydrogen, or salts of said alkylamide alcohol or intramolecular condensate with fatty acids of 1-8 carbons, and (c) a sorbitan fatty acid ester of the general formula ##STR16## wherein R 1 is the same as above.
Claim 8
Dependent Claim 29 words
The ink composition as claimed in claim 5 wherein R 1 is a fatty acid residue of 13-17 carbons, R 2 is malic acid residue, and n is 2.
Claim 9
Dependent Claim 48 words
The ink composition as claimed in claim 5 which further includes about 1-25% by weight of a separating agent which is a non-volatile or only slightly volatile liquid or semi-solid at normal temperatures and has a lower vapor pressure than the solvent, and is soluble in the solvent.
Claim 10
Dependent Claim 105 words
The ink composition as claimed in claim 5 which further includes up to about 10% by weight of a surfactant selected from the group consisting of a nonionic surfactant which is higher alkyl ether, a higher alkylphenol ether, a higher fatty acid ester or a sorbitan ester of polyoxyethylene glycol, and an anionic surfactant which is a higher fatty acid salt, a higher aliphatic alcohol sulfonate, an alkylbenzene sulfonate, an alkylnaphthalene sulfonate, a dialkylsulfosuccinate, an alkylphosphate, a polyoxyethylene glycol sulfate or a polyoxyethylene phosphate, the total amount of the surfactant and the separating agent being up to 25% by weight based on the ink composition.

References Cited (Backward Citations)

US2602039A Cited
US3166421A Cited
US3475187A Cited
US4256494A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-24 1988-12-24 1989-06-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-24 1992-12-24 1993-06-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-24 1996-12-24 1997-06-25 $7700.00 Window Closed / Lapsed

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