Patent US4524010A successfully refreshed from Google Patents.
US4524010A
Expired / Lapsed
US
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High-sudsing, granular detergent composition with greater granulate stability and process for its preparation
Assignee: Henkel AG and Co KGaA
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Filing: 1982-11-16
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Granted: 1985-06-18
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Expires: 2002-11-16
Abstract
Abstract A spray-dried, high-sudsing detergent granulate is disclosed having a bulk density of not more than 450 gm/l and a high content of anionic tensides, which is characterized by a granule structure resistant to mechanical and climatic influences. The detergent granulate contains a tenside component of alkylbenzene sulfonates and, possibly, fatty alcohol sulfates, a builder component of sodium tripolyphosphate, finely crystalline sodium aluminosilicate (zeolite NaA) and sodium silicate. For the preparation, an aqueous slurry is sprayed in spray-drying equipment. The obtained spray-dried product has a porous granule structure with a mean granule size of 0.4 to 0.8 mm. The bulk density is preferably in the range from 250 to 400 gm/l.
Inventors
- 👤 Herbert Reuter
- 👤 Wolfgang Seiter
- 👤 Ingo Wegener
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 10:25
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0094; C11D11/00; C11D11/02; C11D3/02; C11D3/04; C11D3/08; C11D3/12; C11D3/124; C11D3/1246; C11D3/128
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
192 words
A high sudsing, granular, spray-dried detergent composition with excellent granule stability comprised of anionic surface-active compounds, sodium tripolyphosphate, sodium aluminosilicate and sodium silicate, having a bulk density of from 300 to 400 gm per liter and a mean granule size of 0.4 to 0.8 mm where the amount of granules with a granule size of less than 0.1 mm is less than 10% by weight and the amount of granules with a granule size of more than 1.2 mm is less than 5% by weight, and having the composition of: (A) from 35% to 45% by weight of a sodium linear alkylbenzene sulfonate having from 10 to 14 carbons atoms in the alkyl, (B) from 3% to 10% by weight of sodium fatty alcohol sulfate where said fatty alcohol has from 10 to 20 carbon atoms and is selected from the group consisting of alkanols and alkenols, where the sum of the of the components (A) and (B) is from 40% to 48% by weight, (C) from 8% to 20% by weight of sodium tripolyphosphate, (D) from 8% to 18% by weight of finely crystalline, bound water-containing sodium aluminosilicate having the formula:
Claim 2
Dependent Claim
192 words
A high sudsing, granular, spray-dried detergent composition with excellent granule stability comprised of anionic surface-active compounds, sodium tripolyphosphate, sodium aluminosilicate and sodium silicate, having a bulk density of from 300 to 400 gm per liter and a mean granule size of 0.4 to 0.8 mm where the amount of granules with a granule size of less than 0.1 mm is less than 10% by weight and the amount of granules with a granule size of more than 1.2 mm is less than 5% by weight, and having the composition of: (A) from 35% to 45% by weight of a sodium linear alkylbenzene sulfonate having from 10 to 14 carbons atoms in the alkyl, (B) from 3% to 10% by weight of sodium fatty alcohol sulfate where said fatty alcohol has from 10 to 20 carbon atoms and is selected from the group consisting of alkanols and alkenols, where the sum of the of the components (A) and (B) is from 40% to 48% by weight, (C) from 8% to 20% by weight of sodium tripolyphosphate, (D) from 8% to 18% by weight of finely crystalline, bound water-containing sodium aluminosilicate having the formula:
Claim 3
Dependent Claim
158 words
7-1.5 Na 2 O.Al 2 O 3 .1.3-4 SiO 2 and having a calcium binding power of at least 100 mg CaO/gm of active substance (AS) and a particle size of less than 25μ, with at least 80% by weight of the particles having a size of less than 10μ, (E) from 8% to 18% by weight of sodium silicate of the composition: Na.sub.2 O:SiO.sub.2 =1:2 to 1:3.5, (F) from 0 to 10% by weight of sodium sulfate and/or sodium carbonate, and (G) from 8% to 15% by weight of water, including bound water and water of crystallization contained in components (C) to (F), the amount of water removable at a drying temperature of 140° C. being from 4% to 8% by weight, where the sum of the components (C) to (G) is from 52% to 60% by weight, produced by spray-drying an aqueous slurry of the constituents at drying gas outlet temperature of up to 95° C.
Claim 4
Dependent Claim
158 words
7-1.5 Na 2 O.Al 2 O 3 .1.3-4 SiO 2 and having a calcium binding power of at least 100 mg CaO/gm of active substance (AS) and a particle size of less than 25μ, with at least 80% by weight of the particles having a size of less than 10μ, (E) from 8% to 18% by weight of sodium silicate of the composition: Na.sub.2 O:SiO.sub.2 =1:2 to 1:3.5, (F) from 0 to 10% by weight of sodium sulfate and/or sodium carbonate, and (G) from 8% to 15% by weight of water, including bound water and water of crystallization contained in components (C) to (F), the amount of water removable at a drying temperature of 140° C. being from 4% to 8% by weight, where the sum of the components (C) to (G) is from 52% to 60% by weight, produced by spray-drying an aqueous slurry of the constituents at drying gas outlet temperature of up to 95° C.
Claim 5
Dependent Claim
59 words
The detergent composition of claim 1 further containing from 0 to 5% by weight, being from 0 to about 2% by weight of the individual components, of other customary ingredients of spray-dried washing powders of an organic nature selected from the group consisting of organic complexing agents, optical brighteners, anti-redepositing agents and organic tensides employed as aluminosilicate suspending agents.
Claim 6
Dependent Claim
25 words
The detergent composition of claim 1 wherein component (F) is sodium sulfate and is present in an amount of from 0.2% to 5% by weight.
Claim 7
Dependent Claim
70 words
A process for the production of the detergent composition of claim 1 comprising spray-drying a mixture of the the components (A) to (F) in an aqueous slurry containing from 30% to 45% by weight of water through a nozzle into a spray-drying area having a drying gases intake temperature of 150° C. to 350° C. and an outlet temperature of 65° C. to 95° C., and recovering said detergent composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-17 | 1988-12-17 | 1989-06-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-17 | 1992-12-17 | 1993-06-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-17 | 1996-12-17 | 1997-06-18 | $7700.00 | Window Closed / Lapsed |