Patent US4523912A successfully refreshed from Google Patents.
US4523912A
Expired / Lapsed
US
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Mineral tooth with silane-coupled adhesive plastic part
Assignee: VEB KOMBINAT MEDIZIN- und LABORTECHNIK LEIPZIG A GERMAN CORP
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Filing: 1983-03-10
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Granted: 1985-06-18
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Expires: 2003-03-10
Abstract
Abstract The invention concerns a mineral tooth having a silane-coupled adhesive plastic part which enables chemical bonding with base materials being common in dental prosthetics as well as a process for its industrial manufacture. The ground masses of the individual layers of the mineral tooth have grain sizes with a fractionation from about 60 μm to about 100 μm and the adhesive plastic part consists of a multiple component mixture of suitable viscosity and consistency and with 1% to 5% of mineral filler material. With fritting of the ground masses, a defined guidance of both time and temperature is carried out in the range from 600° C. to 900° C., the mineral teeth are silanized for several times in the silane solution and the multiple component mixture is applied without pressure on the mineral tooth and is polymerized-on without pressure by means of a source of heat rays.
Inventors
- 👤 Alfred Breustedt
- 👤 Heinz Taschner
- 👤 Rainer Korf
- 👤 Renate Lorenz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:55
CPC Classifications
A; A61; A61C; A61C13/00; A61C13/08; A61C13/09; A61K; A61K6/00; A61K6/15; A61K6/17; A61K6/70; A61K6/71; A61K6/76; A61K6/78; A61K6/80; A61K6/802
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
170 words
A process for producing an artificial tooth which comprises: (a) providing a base mineral portion; (b) fritting said base mineral portion at a temperature in the range of between 600° C. and 900° C., to produce a base mineral portion having grain sizes with a fractionation of from about 60 μm to about 100 μm; (c) applying a silane layer to at least one surface of the base mineral portion, said silane layer being selected from the group consisting of ν-amino-propyltriethoxysilane, ν-glycidyloxypropyltri-methoxysilane, ν-methacryloxypropyltrimethoxysilane, and ν-aminopropyltrimethoxysilane; (d) applying a plastic adhesive layer onto said silane layer, said plastic adhesive layer comprising 30% to 33% polymethacrylic acid methyl ester, 3% to 6% dioxane, 63% to 66% methacrylic acid methyl ester, 1% to 2% of a sensitizer, and 0.3% to 1% of a vapor pressure reducing substance; and (e) polymerizing said plastic adhesive layer with a quartz lamp radiating heat source using UV-rays for 3 to 6 minutes at a temperature of from 20° C. to 50° C., and under normal atmospheric pressure.
Claim 2
Dependent Claim
170 words
A process for producing an artificial tooth which comprises: (a) providing a base mineral portion; (b) fritting said base mineral portion at a temperature in the range of between 600° C. and 900° C., to produce a base mineral portion having grain sizes with a fractionation of from about 60 μm to about 100 μm; (c) applying a silane layer to at least one surface of the base mineral portion, said silane layer being selected from the group consisting of ν-amino-propyltriethoxysilane, ν-glycidyloxypropyltri-methoxysilane, ν-methacryloxypropyltrimethoxysilane, and ν-aminopropyltrimethoxysilane; (d) applying a plastic adhesive layer onto said silane layer, said plastic adhesive layer comprising 30% to 33% polymethacrylic acid methyl ester, 3% to 6% dioxane, 63% to 66% methacrylic acid methyl ester, 1% to 2% of a sensitizer, and 0.3% to 1% of a vapor pressure reducing substance; and (e) polymerizing said plastic adhesive layer with a quartz lamp radiating heat source using UV-rays for 3 to 6 minutes at a temperature of from 20° C. to 50° C., and under normal atmospheric pressure.
Claim 3
Dependent Claim
42 words
The process for producing an artificial tooth of claim 1, in which said base mineral portion is washed and degreased in an ultrasonic bath using a degreasing component selected from the group consisting of xylol and 1, 1,2-trifluorotrichlorethane, prior to step (c).
Claim 4
Dependent Claim
43 words
The process for producing an artificial tooth of claim 2, in which the washing and degreasing takes place in the ultrasonic bath for about 10 minutes, after which the degreased base mineral portion is dried in an air stream for about 5 minutes.
Claim 5
Dependent Claim
64 words
The process for producing an artificial tooth of claim 1, in which the silane layer is applied according to step (c) by silanizing the base mineral portion in a silane solution comprising an about 1% water solution in an about 0.3% acetic acid solution, the silane solution being produced by mixing the silanes and the 0.3% acetic acid in a ratio of about 1:99.
Claim 6
Dependent Claim
16 words
The process for producing an artificial tooth of claim 4, in which the silane is ν-methacryloxypropyl-trimethoxysilane.
Claim 7
Dependent Claim
74 words
The process for producing an artificial tooth of claim 4, in which the base mineral portion is inserted into the silane solution and joggled at least twice, each period of insertion and joggling being for about 5 minutes, with the base mineral portion being removed from the silane solution and dried at a temperature of about 110° C. for about 10 minutes, after each time period of insertion and joggling in the silane solution.
Claim 8
Dependent Claim
32 words
The process for producing an artificial tooth of claim 4, in which the silane solution is utilized for silanizing within 120 hours after preparation, to control the viscosity of the silanizing solution.
Claim 9
Dependent Claim
52 words
The process for producing an artificial tooth of claim 1, in which the plastic adhesive layer of step (d) is a multiple component mixture containing from 1% to 5% of a component selected from the group consisting of mineral filler material, previously silanized mineral fillers, silicate bonded color pigments, and mixtures thereof.
Claim 10
Dependent Claim
38 words
The process for producing an artificial tooth of claim 8, in which the previously silanized mineral fillers are selected from the group consisting of quartz and aluminum oxide, and mixtures thereof, with grain sizes of about 60 μm.
Claim 11
Dependent Claim
24 words
The process for producing an artificial tooth of claim 8, in which the silicate bonded color pigments have grain sizes of about 60 μm.
Claim 12
Dependent Claim
47 words
The process for producing an artificial tooth of claim 1, in which the plastic adhesive layer of step (d) comprises about 30.5% polymethacrylic acid methyl ester, about 63.9% methacrylic acid methyl ester, about 4.0% dioxane, about 1.3% UV sensitizer, and 0.3% of a vapor pressure reducing substance.
Claim 13
Dependent Claim
26 words
The process for producing an artificial tooth of claim 1, in which the plastic adhesive layer is polymerized according to step (e) for about 4 minutes.
Claim 14
Dependent Claim
45 words
The process for producing an artificial tooth of claim 1, in which the sensitizer is a compound of the formula ##STR2## where R represents an alkylene group, an alkylene ether group, or polyalkylene ether groups, and X represents hydrogen, a hydroxy group, or a halogen.
Claim 15
Dependent Claim
162 words
An artificial tooth comprising a base mineral portion, said base mineral portion having grain sizes with a fractionation of from about 60 μm to about 100 μm and produced by fritting said base mineral portion at a temperature in the range of between 600° C. and 900° C., a silane layer on at least one surface of said base mineral portion, said silane layer being selected from the group consisting of γ-aminopropyltriethoxysilane, γ-glycidyloxypropyltrimethoxysilane, γ-methacryloxypropyltrimethoxysilane, and γ-aminopropyltrimethoxysilane, and a plastic adhesive layer on said silane layer, said plastic adhesive layer comprising 30% to 33% polymethacrylic acid methylester, 3% to 6% dioxane, 63% to 66% methacrylic acid methylester, 1% to 2% of a sensitizer, and 0.3% to 1% of a vapor pressure reducing substance, said plastic adhesive layer being a polymerized layer produced by polymerization with a quartz lamp radiating heat source using UV-rays for 3 to 6 minutes at a temperature of from 20° C. to 50° C., and under normal atmospheric pressure.
Claim 16
Dependent Claim
162 words
An artificial tooth comprising a base mineral portion, said base mineral portion having grain sizes with a fractionation of from about 60 μm to about 100 μm and produced by fritting said base mineral portion at a temperature in the range of between 600° C. and 900° C., a silane layer on at least one surface of said base mineral portion, said silane layer being selected from the group consisting of γ-aminopropyltriethoxysilane, γ-glycidyloxypropyltrimethoxysilane, γ-methacryloxypropyltrimethoxysilane, and γ-aminopropyltrimethoxysilane, and a plastic adhesive layer on said silane layer, said plastic adhesive layer comprising 30% to 33% polymethacrylic acid methylester, 3% to 6% dioxane, 63% to 66% methacrylic acid methylester, 1% to 2% of a sensitizer, and 0.3% to 1% of a vapor pressure reducing substance, said plastic adhesive layer being a polymerized layer produced by polymerization with a quartz lamp radiating heat source using UV-rays for 3 to 6 minutes at a temperature of from 20° C. to 50° C., and under normal atmospheric pressure.
Claim 17
Dependent Claim
45 words
The artificial tooth of claim 14, in which the plastic adhesive layer is a multiple component mixture containing from 1% to 5% of a component selected from the group consisting of mineral filler material, previously silanized mineral fillers, silicate bonded color pigments, and mixtures thereof.
Claim 18
Dependent Claim
34 words
The artificial tooth of claim 15, in which the previously silanized mineral fillers are selected from the group consisting of quartz and aluminum oxide, and mixtures thereof, with grain sizes of about 60 μm.
Claim 19
Dependent Claim
20 words
The artificial tooth of claim 15, in which the silicate bonded color pigments have grain sizes of about 60 μm.
Claim 20
Dependent Claim
39 words
The artificial tooth of claim 14, in which the plastic adhesive layer comprises about 30.5% polymethacrylic acid methyl ester, about 63.9% methacrylic acid methylester, about 4.0% dioxane, about 1.3% UV sensitizer, and 0.3% of a vapor pressure reducing substance.
Claim 21
Dependent Claim
41 words
The artificial tooth of claim 14, in which the sensitizer is a compound of the formula ##STR3## where R represents an alkylene group, an alkylene ether group, or polyalkylene ether groups, and X represents hydrogen, a hydroxy group, or a halogen.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-17 | 1988-12-17 | 1989-06-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-17 | 1992-12-17 | 1993-06-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-17 | 1996-12-17 | 1997-06-18 | $7700.00 | Window Closed / Lapsed |