Patent US4521594A successfully refreshed from Google Patents.
US4521594A
Expired / Lapsed
US
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Process for producing sodium carboxymethylcellulose
Assignee: Daicel Corp
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Filing: 1984-06-20
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Granted: 1985-06-04
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Expires: 2004-06-20
Abstract
Abstract A process for producing sodium carboxymethylcellulose having an excellent dispersibility in water by heat-treating sodium carboxymethylcellulose to crosslink the same. The starting sodium carboxymethylcellulose has an equivalent ratio of the free carboxylic acid group to the sodium carboxylate of at least 0.01 to 100 and a viscosity of at least 100 cP (as a 1% aqueous solution).
Inventors
- 👤 Tetuo Kanematu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 22:18
CPC Classifications
C; C08; C08B; C08B11/00; C08B11/20; C08B15/00; C08B15/005
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
159 words
A method of treating a starting sodium carboxymethylcellulose to improve its dispersibility in water, said starting sodium carboxymethylcellulose having a ratio of equivalents of free carboxyl groups/sodium carboxylate of at least 0.01/100, and a 1% aqueous solution of said starting sodium carboxymethylcellulose having a pH in the range from 6.0 to 7.5 and a viscosity of at least 100 cPs, which comprises the steps of: heating said starting sodium carboxymethylcellulose at a temperature in the range of from 100° to 170° C., for a period of time effective to partially react the free carboxyl groups of said sodium carboxymethylcellulose with hydroxyl groups of said sodium carboxymethylcellulose to obtain a modified, cross-linked sodium carboxymethylcellulose which is water-soluble, does not form lumps when it is placed in water and exhibits improved dispersibility when it is placed in water, and wherein an aqueous solution of said modified sodium carboxymethylcellulose has a lower viscosity than an aqueous solution of said starting sodium carboxymethylcellulose.
Claim 2
Independent Claim
159 words
A method of treating a starting sodium carboxymethylcellulose to improve its dispersibility in water, said starting sodium carboxymethylcellulose having a ratio of equivalents of free carboxyl groups/sodium carboxylate of at least 0.01/100, and a 1% aqueous solution of said starting sodium carboxymethylcellulose having a pH in the range from 6.0 to 7.5 and a viscosity of at least 100 cPs, which comprises the steps of: heating said starting sodium carboxymethylcellulose at a temperature in the range of from 100° to 170° C., for a period of time effective to partially react the free carboxyl groups of said sodium carboxymethylcellulose with hydroxyl groups of said sodium carboxymethylcellulose to obtain a modified, cross-linked sodium carboxymethylcellulose which is water-soluble, does not form lumps when it is placed in water and exhibits improved dispersibility when it is placed in water, and wherein an aqueous solution of said modified sodium carboxymethylcellulose has a lower viscosity than an aqueous solution of said starting sodium carboxymethylcellulose.
Claim 3
Dependent Claim
17 words
A method as claimed in claim 1 in which said temperature is from 120° to 160° C.
Claim 4
Dependent Claim
41 words
A method as claimed in claim 1 in which a 1% aqueous solution of said starting sodium carboxymethylcellulose has a viscosity of from 100 to 1000 cPs, said temperature is 140° C. or higher and the heating time is several hours.
Claim 5
Dependent Claim
42 words
A method as claimed in claim 1 in which a 1% aqueous solution of said starting sodium carboxymethylcellulose has a viscosity of from 1000 to 3000 cPs, said temperature is about 140° C. and the heating time is 1 to 2 hours.
Claim 6
Dependent Claim
43 words
A method as claimed in claim 1 in which a 1% aqueous solution of said starting sodium carboxymethylcellulose has a viscosity of higher than 3000 cPs, said temperature is from 100° to 130° C. and the heating time is several tens of minutes.
Claim 7
Dependent Claim
65 words
A method as claimed in claim 1 in which the treatment time and temperature conditions are on or within the quadrilateral plane figure defined by lines joining the coordinates 120° C., 0.5 hour 120° C., 2.5 hours 150° C., 2.0 hours 170° C., 0.5 hour in a rectangular coordinate graph of time as one axis of reference and temperature as the other axis of reference.
Claim 8
Dependent Claim
48 words
A method as claimed in claim 1 in which the ratio of free carboxyl groups to sodium carboxylate groups in the starting sodium carboxymethylcellulose is from 0.1 to 2.0, the temperature is from 140° to 150° C. and said period of time is from 0.5 to 2.0 hours.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-03 | 1988-12-03 | 1989-06-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-03 | 1992-12-03 | 1993-06-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-03 | 1996-12-03 | 1997-06-04 | $7700.00 | Window Closed / Lapsed |