US4518689A
Expired / Lapsed
US
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Spectrally sensitized inner latent image type silver halide photographic emulsions
Assignee: Fujifilm Holdings Corp
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Filing: 1983-10-27
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Granted: 1985-05-21
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Expires: 2003-10-27
Abstract
Abstract An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one monomethine cyanine dye represented by general formula (II) to a direct positive inner latent image type silver halide photographic emulsion and thereafter adding additionally at least one monomethine cyanine dye represented by general formula (I) to said emulsion <IMAGE> (I) <IMAGE> (II) (the symbols are as defined in the appended claims). A remarkable increase of spectral sensitivity, an increase of maximum density and a decrease of minimum density can be obtained by this silver halide photographic emulsion.
Inventors
- 👤 Yasuhiro Noguchi
- 👤 Yuji Mihara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 07:37
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/485; G03C1/48538; G03C1/48584; G03C1/06; G03C1/08; G03C1/28; G03C1/29; Y; Y10; Y10S; Y10S430/00; Y10S430/141
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
213 words
An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one monomethine cyanine dye represented by general formula (II) to a direct positive inner latent image type silver halide photograhic emulsion and thereafter adding additionally at least one monomethine cyanine dye represented by general formula (I) to said emulsion ##STR9## wherein W and Y, which may be identical or different from each other, each represents an oxygen atom, a selenium atom, a sulfur atom or ##STR10## wherein R 5 represents a lower alkyl group which is unsubstituted or substituted by a halogen atom or a lower alkoxy group, or an allyl group, Z, Z 1 , Z 2 and Z 3 each represents an atomic group necessary to form a benzene ring or naphthalene ring, R 1 and R 2 each represents an unsubstituted alkyl group, a haloalkyl group, an alkoxyalkyl group, an aralkyl group, an aryloxyalkyl group or an allyl group, R 3 and R 4 each represents an alkyl group substituted with a carboxyl group or a sulfo group, but at least one of R 3 and R 4 represents an alkyl group substituted with a sulfo group, X 1 represents an anion, X 2 represents a cation, and n is 0 or 1.
Claim 2
Dependent Claim
213 words
An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one monomethine cyanine dye represented by general formula (II) to a direct positive inner latent image type silver halide photograhic emulsion and thereafter adding additionally at least one monomethine cyanine dye represented by general formula (I) to said emulsion ##STR9## wherein W and Y, which may be identical or different from each other, each represents an oxygen atom, a selenium atom, a sulfur atom or ##STR10## wherein R 5 represents a lower alkyl group which is unsubstituted or substituted by a halogen atom or a lower alkoxy group, or an allyl group, Z, Z 1 , Z 2 and Z 3 each represents an atomic group necessary to form a benzene ring or naphthalene ring, R 1 and R 2 each represents an unsubstituted alkyl group, a haloalkyl group, an alkoxyalkyl group, an aralkyl group, an aryloxyalkyl group or an allyl group, R 3 and R 4 each represents an alkyl group substituted with a carboxyl group or a sulfo group, but at least one of R 3 and R 4 represents an alkyl group substituted with a sulfo group, X 1 represents an anion, X 2 represents a cation, and n is 0 or 1.
Claim 3
Dependent Claim
22 words
The silver halide photographic emulsion of claim 1, wherein W and Y in formulae (I) and (II) each represents a sulfur atom.
Claim 4
Dependent Claim
55 words
The silver halide photographic emulsion of claim 1, wherein Z, Z 1 , Z 2 and Z 3 in formulae (I) and (II) each forms together with W, Y and the nitrogen atom a benzimidazole nucleus, a benzoxazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthoxazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus.
Claim 5
Dependent Claim
35 words
The silver halide photographic emulsion of claim 1, wherein R 3 and R 4 in formula (II) include an alkyl group connected with a carboxyl group or a sulfo group through another divalent organic group.
Claim 6
Dependent Claim
60 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of formulae (Ia-1) to (Ia-7), and the sensitizing dyes represented by general formula (II) are selected from the group consisting of formulae (IIa-1) to (IIa-8), the formulae are described at pages 10 to 27 of this specification.
Claim 7
Dependent Claim
60 words
The silver halide photographic emulsion of claim 1, wherein the sensitizing dyes represented by general formula (I) are selected from the group consisting of formulae (Ib-8) to (Ib-14), and the sensitizing dyes represented by general formula (II) are selected from the group consisting of formulae (IIb-9) to (IIb-17), the formulae are described at pages 10 to 27 of this specification.
Claim 8
Dependent Claim
39 words
The silver halide photographic emulsion of claim 1, wherein the molar ratio of the sensitizing dyes represented by general formula (I) to the sensitizing dyes represented by general formula (II) is selected from a range of 1/20 to 20/1.
Claim 9
Dependent Claim
39 words
The silver halide photographic emulsion of claim 1, wherein the amount of each of the sensitizing dyes represented by general formulae (I) and (II) is from about 1.0×10 -5 to about 1.0×10 -3 mol per mol of silver halide.
Claim 10
Dependent Claim
41 words
The silver halide photograhic emulsion of claim 1, wherein the time interval from the addition of the sensitizing dyes represented by general formula (II) to the addition of the sensitizing dyes represented by general formula (I) is at least 1 minute.
Claim 11
Dependent Claim
41 words
The silver halide photograhic emulsion of claim 1, wherein the time interval from the addition of the sensitizing dyes represented by general formula (II) to the addition of the sensitizing dyes represented by general formula (I) is at least 5 minutes.
Claim 12
Dependent Claim
44 words
A silver halide photographic material capable of providing direct positive images by surface development in the presence of a nucleus forming agent after imagewise exposure to light which has at least one inner latent image type silver halide emulsion layer according to claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-05-20 | 1988-11-19 | 1989-05-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-05-20 | 1992-11-19 | 1993-05-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-05-20 | 1996-11-19 | 1997-05-21 | $7700.00 | Window Closed / Lapsed |