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US4518675A Expired / Lapsed US ⏱️ 0.0 years remaining

Stripper for radiosensitive resist

Assignee: Toray Industries Inc
•
Filing: 1983-02-14
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Granted: 1985-05-21
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Expires: 2003-02-14
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Abstract

Abstract As a stripper for a radiosensitive resist formed of a poly(fluoroalkyl α-haloacrylate) or a copolymer thereof, there is used a solution which contains 0.1 to 40 wt. % of an alkali metal alkoxide, an alkali metal hydroxide or a tetraalkylammonium hydroxide in a substantially non-aqueous polar solvent of dimethyl sulfoxide.

Inventors

  • 👤 Mutsuo Kataoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:32
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/422; G03F7/425

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 65 words
A stripper for a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer, said stripper consisting essentially of a substantially non-aqueous polar solvent of dimethyl sulfoxide, and 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides and tetraalkylammonium hydroxides, said stripper further characterized as being used with a post-stripping water rinse and useful at room temperature.
Claim 2
Dependent Claim 65 words
A stripper for a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer, said stripper consisting essentially of a substantially non-aqueous polar solvent of dimethyl sulfoxide, and 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides and tetraalkylammonium hydroxides, said stripper further characterized as being used with a post-stripping water rinse and useful at room temperature.
Claim 3
Dependent Claim 13 words
The stripper of claim 1, wherein said compound is an alkali metal alkoxide.
Claim 4
Dependent Claim 20 words
The stripper of claim 2, wherein said alkali metal alkoxide is a sodium lower alkoxide or a potassium lower alkoxide.
Claim 5
Dependent Claim 12 words
The stripper of claim 1, wherein said compound is a tetraalkylammonium hydroxide.
Claim 6
Dependent Claim 13 words
The stripper of claim 4, wherein said tetraalkylammonium hydroxide is a tetraloweralkylammonium hydroxide.
Claim 7
Dependent Claim 73 words
A stripper for a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer, said stripper consisting essentially of a substantially non-aqueous polar solvent mixture of dimethyl sulfoxide and a lower alcohol, and 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and tetraalkylammonium hydroxides, said stripper further characterized as being used with a post-stripping water rinse and useful at room temperature.
Claim 8
Dependent Claim 73 words
A stripper for a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer, said stripper consisting essentially of a substantially non-aqueous polar solvent mixture of dimethyl sulfoxide and a lower alcohol, and 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and tetraalkylammonium hydroxides, said stripper further characterized as being used with a post-stripping water rinse and useful at room temperature.
Claim 9
Dependent Claim 20 words
The stripper of claim 6 wherein said alkali metal alkoxide is a sodium lower alkoxide or a potassium lower alkoxide.
Claim 10
Dependent Claim 12 words
The stripper of claim 6 wherein said tetraalkylammonium hydroxide is tetraloweralkylammonium hydroxide.
Claim 11
Dependent Claim 13 words
The stripper of claim 6, wherein said compound is an alkali metal hydroxide.
Claim 12
Dependent Claim 18 words
The stripper of claim 9, wherein said alkali metal hydroxide is lithium hydroxide, sodium hydroxide, or potassium hydroxide.
Claim 13
Dependent Claim 73 words
A process of stripping a radiosensitive resist formed of a fluoroalkyl α-haloacrylate polymer, which process comprises contacting a substrate having said radiosensitive resist formed thereon with a solution at room temperature, said solution containing 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides and tetraalkylammonium hydroxides in a substantially non-aqueous polar solvent of dimethyl sulfoxide, and subsequently washing said stripped substrate with water.
Claim 14
Dependent Claim 73 words
A process of stripping a radiosensitive resist formed of a fluoroalkyl α-haloacrylate polymer, which process comprises contacting a substrate having said radiosensitive resist formed thereon with a solution at room temperature, said solution containing 0.1 to 40 weight percent of at least one compound selected from the group consisting of alkali metal alkoxides and tetraalkylammonium hydroxides in a substantially non-aqueous polar solvent of dimethyl sulfoxide, and subsequently washing said stripped substrate with water.
Claim 15
Dependent Claim 19 words
The process of claim 11, wherein said substrate is pretreated with an organic solvent capable of dissolving said resist.
Claim 16
Dependent Claim 20 words
The process of claim 11 wherein said alkali metal alkoxide is a sodium lower alkoxide or a potassium lower alkoxide.
Claim 17
Dependent Claim 13 words
The process of claim 11 wherein said tetraalkylammonium hydroxide is a tetraloweralkylammonium hydroxide.
Claim 18
Dependent Claim 23 words
The process of claim 11 wherein said substantially non-aqueous polar solvent of dimethyl sulfoxide contains not more than 10 weight percent of water.
Claim 19
Dependent Claim 79 words
A process for stripping a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer which process comprises contacting a susbstrate having said radiosensitive resist formed thereon with a solution at room temperature, said solution containing 0.1 to 40 percent of at least one compound selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and tetraalkylammonium hydroxides in a substantially non-aqueous polar solvent mixture of dimethylsulfoxide and a lower alcohol, and subsequently washing said stripped substrate with water.
Claim 20
Dependent Claim 79 words
A process for stripping a radiosensitive resist formed of a fluoroalkyl alpha-haloacrylate polymer which process comprises contacting a susbstrate having said radiosensitive resist formed thereon with a solution at room temperature, said solution containing 0.1 to 40 percent of at least one compound selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and tetraalkylammonium hydroxides in a substantially non-aqueous polar solvent mixture of dimethylsulfoxide and a lower alcohol, and subsequently washing said stripped substrate with water.
Claim 21
Dependent Claim 19 words
The process of claim 16 wherein said substrate is pretreated with an organic solvent capable of dissolving said resist.
Claim 22
Dependent Claim 20 words
The process of claim 16 wherein said alkali metal alkoxide is a sodium lower alkoxide or a potassium lower alkoxide.
Claim 23
Dependent Claim 18 words
The process of claim 16 wherein said alkali metal hydroxide is lithium hydroxide, sodium hydroxide or potassium hydroxide.
Claim 24
Dependent Claim 13 words
The process of claim 16 wherein said tetraalkylammonium hydroxide is a tetraloweralkylammonium hydroxide.
Claim 25
Dependent Claim 28 words
The process of claim 16 wherein said substantially non-aqueous polar solvent mixture of dimethyl sulfoxide and a lower alcohol contains not more than 10 weight percent of water.

References Cited (Backward Citations)

US2694658A Cited
US2850411A Cited
US3679593A Cited
US3784477A Cited
US3980587A Cited
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US4202703A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-20 1988-11-19 1989-05-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-20 1992-11-19 1993-05-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-20 1996-11-19 1997-05-21 $7700.00 Window Closed / Lapsed

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