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Rubbery polymer composition

Assignee: Denka Co Ltd
•
Filing: 1983-07-18
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Granted: 1985-05-14
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Expires: 2003-07-18
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Abstract

Abstract A rubbery polymer composition comprises a crosslinked copolymer comprising the following components. Type I 15 to 40 wt. parts of a vinyl carboxylate having the formula (I); 60 to 85 wt. parts of an alkoxyalkyl acrylate having the formula (II); 0 to 15 wt. parts of ethylene; (100 wt. parts of a total of said three components); 0 to 5 wt. parts of the components having the formula (III), (IV) or (V): Type II 15 to 55 wt. parts of a vinyl carboxylate having the formula (I); 5 to 20 wt. parts of ethylene; an alkyl acrylate having the formula (II'); an alkoxyalkyl acrylate having the formula (II) (100 wt. parts of a total of said four components and more than 0.8 of a ratio of the alkoxyalkyl acrylate (II) to the alkyl acrylate (II') by weight); 0 to 5 wt. parts of the components having the formula (III), (IV) or (V): RCOO--CH═CH.sub.2 (I) wherein R represents a C 1-4 alkyl group. CH.sub.2 ═CHCOO--R.sub.1 --O--R.sub.2 (II) wherein R 1 represents a C 1-4 alkylene group; and R 2 represents a C 1-4 alkyl or alkoxyalkyl group. CH.sub.2 ═CHCOO--R.sub.6 (II') wherein R 6 represents a C 3-8 alkyl group. ##STR1## wherein R 3 represents hydrogen atom or methyl group. ##STR2## wherein R 4 represents vinyl, allyl or methallyl group. CH.sub.2 ═CH--O--R.sub.5 (V) wherein R 5 represents CH 2 Cl--CH 2 --or CH 2 Cl--CO--group.

Inventors

  • 👤 Kohki Takahashi
  • 👤 Takeo Kondoh
  • 👤 Masao Koga
  • 👤 Kenichiro Nishiwaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:18
CPC Classifications
C; C08; C08L; C08L31/00; C08L31/02; C08L33/00; C08L33/04; C08L33/14

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 175 words
A rubber polymer composition, consisting essentially of: a crosslinkable polymer having a Mooney viscosity (ML 1+4 ) of 35 to 50 at 100° C. prepared by copolymerizing (A) from 15 to 40 parts by weight of a vinyl carboxylate of the formula: RCOO--CH═CH 2 , wherein R is a C 1-4 alkyl group, (B) from 60 to 85 parts by weight of an alkoxyalkyl acrylate of the formula: CH 2 ═CHCOO--R 1 --O--R 2 , wherein R 1 is a C 1-4 alkylene group and R 2 is a C 1-4 alkyl or alkoxyalkyl group, (C) from 4 to 15 parts by weight of ethylene, with the total of components A, B and C constituting 100 parts by weight, and (D) from 0.3 to 5 parts by weight of a comonomer selected from the group consisting of ##STR5## wherein R 3 is hydrogen or methyl, ##STR6## wherein R 4 is a vinyl, allyl or methallyl group, and CH 2 ═CH--O--R 5 , wherein R 5 is CH 2 Cl--CH 2 -- or CH 2 Cl--CO--.
Claim 2
Dependent Claim 175 words
A rubber polymer composition, consisting essentially of: a crosslinkable polymer having a Mooney viscosity (ML 1+4 ) of 35 to 50 at 100° C. prepared by copolymerizing (A) from 15 to 40 parts by weight of a vinyl carboxylate of the formula: RCOO--CH═CH 2 , wherein R is a C 1-4 alkyl group, (B) from 60 to 85 parts by weight of an alkoxyalkyl acrylate of the formula: CH 2 ═CHCOO--R 1 --O--R 2 , wherein R 1 is a C 1-4 alkylene group and R 2 is a C 1-4 alkyl or alkoxyalkyl group, (C) from 4 to 15 parts by weight of ethylene, with the total of components A, B and C constituting 100 parts by weight, and (D) from 0.3 to 5 parts by weight of a comonomer selected from the group consisting of ##STR5## wherein R 3 is hydrogen or methyl, ##STR6## wherein R 4 is a vinyl, allyl or methallyl group, and CH 2 ═CH--O--R 5 , wherein R 5 is CH 2 Cl--CH 2 -- or CH 2 Cl--CO--.
Claim 3
Dependent Claim 17 words
The composition of claim 1, wherein said vinyl carboxylate is vinyl acetate, vinyl propionate or vinyl butyrate.
Claim 4
Dependent Claim 23 words
The composition of claim 1, wherein said alkoxyalkyl acrylate is methoxyethyl acrylate, methoxymethyl acrylate, ethoxyethyl acrylate, butoxyethyl acrylate, methoxyethoxyethyl acrylate or ethoxyethoxyethyl acrylate.
Claim 5
Dependent Claim 15 words
The composition of claim 1, wherein said monomer (D) is glycidyl acrylate or glycidyl methacrylate.
Claim 6
Dependent Claim 17 words
The composition of claim 1, wherein said monomer (D) is vinylglycidyl ether, allylglycidyl ether or methallylglycidyl ether.
Claim 7
Dependent Claim 15 words
The composition of claim 1, wherein said monomer (D) is vinyl chloroacetate or 2-chloroethylvinyl ether.

References Cited (Backward Citations)

US2565259A Cited
US3017396A Cited
US3035031A Cited
US3317483A Cited
US4214619A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-13 1988-11-12 1989-05-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-13 1992-11-12 1993-05-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-13 1996-11-12 1997-05-14 $7700.00 Window Closed / Lapsed

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